2-(Dicyclohexylphosphino)-2'-methylbiphenyl

Modify Date: 2024-01-02 10:12:01

2-(Dicyclohexylphosphino)-2'-methylbiphenyl Structure
2-(Dicyclohexylphosphino)-2'-methylbiphenyl structure
 Common Name 2-(Dicyclohexylphosphino)-2'-methylbiphenyl
CAS Number 251320-86-2 Molecular Weight 364.50
Density N/A Boiling Point 499.3±24.0 °C at 760 mmHg
Molecular Formula C25H33P Melting Point 107-111 °C
MSDS USA Flash Point 271.5±29.2 °C

 Use of 2-(Dicyclohexylphosphino)-2'-methylbiphenyl


MePhos is a biochemical reagent that can be used as a biological material or organic compound for life science related research.

 Names

Name dicyclohexyl-[2-(2-methylphenyl)phenyl]phosphane
Synonym More Synonyms

  Biological Activity

Description MePhos is a biochemical reagent that can be used as a biological material or organic compound for life science related research.
Related Catalog

 Chemical & Physical Properties

Boiling Point 499.3±24.0 °C at 760 mmHg
Melting Point 107-111 °C
Molecular Formula C25H33P
Molecular Weight 364.50
Flash Point 271.5±29.2 °C
Exact Mass 364.231995
PSA 13.59000
LogP 8.91
Vapour Pressure 0.0±1.2 mmHg at 25°C

 Safety Information

Hazard Codes Xi:Irritant;
Risk Phrases R36/37/38
Safety Phrases 37/39-26
RIDADR NONH for all modes of transport
WGK Germany 3
HS Code 2902909090

 Synthetic Route

2-bromo-2'-methylbiphenyl structure

2-bromo-2'-meth...

CAS#:251320-87-3

Dicyclohexylphosphinous chloride structure

Dicyclohexylpho...

CAS#:16523-54-9

~65%

2-(Dicyclohexylphosphino)-2'-methylbiphenyl Structure

2-(Dicyclohexyl...

CAS#:251320-86-2

Literature: Wolfe, John P.; Singer, Robert A.; Yang, Bryant H.; Buchwald, Stephen L. Journal of the American Chemical Society, 1999 , vol. 121, # 41 p. 9550 - 9561
2-Bromochlorobenzene structure

2-Bromochlorobenzene

CAS#:694-80-4

O-TOLYLMAGNESIUM CHLORIDE structure

O-TOLYLMAGNESIU...

CAS#:33872-80-9

Dicyclohexylphosphinous chloride structure

Dicyclohexylpho...

CAS#:16523-54-9

~49%

2-(Dicyclohexylphosphino)-2'-methylbiphenyl Structure

2-(Dicyclohexyl...

CAS#:251320-86-2

Literature: Kaye, Steven; Fox, Joseph M.; Hicks, Frederick A.; Buchwald, Stephen L. Advanced Synthesis and Catalysis, 2001 , vol. 343, # 8 p. 789 - 794
2-chloro-2'-methylbiphenyl structure

2-chloro-2'-met...

CAS#:19493-31-3

Dicyclohexylphosphinous chloride structure

Dicyclohexylpho...

CAS#:16523-54-9

~53%

2-(Dicyclohexylphosphino)-2'-methylbiphenyl Structure

2-(Dicyclohexyl...

CAS#:251320-86-2

Literature: Ullah, Ehsan; McNulty, James; Robertson, Al European Journal of Organic Chemistry, 2012 , # 11 p. 2127 - 2131
tolylboronic acid structure

tolylboronic acid

CAS#:16419-60-6

~%

2-(Dicyclohexylphosphino)-2'-methylbiphenyl Structure

2-(Dicyclohexyl...

CAS#:251320-86-2

Literature: Journal of the American Chemical Society, , vol. 121, # 41 p. 9550 - 9561
1-Bromo-2-iodobenzene structure

1-Bromo-2-iodob...

CAS#:583-55-1

~%

2-(Dicyclohexylphosphino)-2'-methylbiphenyl Structure

2-(Dicyclohexyl...

CAS#:251320-86-2

Literature: Journal of the American Chemical Society, , vol. 121, # 41 p. 9550 - 9561
chlorocyclohexylmagnesium structure

chlorocyclohexy...

CAS#:931-51-1

~%

2-(Dicyclohexylphosphino)-2'-methylbiphenyl Structure

2-(Dicyclohexyl...

CAS#:251320-86-2

Literature: Advanced Synthesis and Catalysis, , vol. 343, # 8 p. 789 - 794
1,2-Dichlorobenzene structure

1,2-Dichlorobenzene

CAS#:95-50-1

~%

2-(Dicyclohexylphosphino)-2'-methylbiphenyl Structure

2-(Dicyclohexyl...

CAS#:251320-86-2

Literature: European Journal of Organic Chemistry, , # 11 p. 2127 - 2131
2-Bromochlorobenzene structure

2-Bromochlorobenzene

CAS#:694-80-4

2-Bromotoluene structure

2-Bromotoluene

CAS#:95-46-5

Dicyclohexylphosphinous chloride structure

Dicyclohexylpho...

CAS#:16523-54-9

~55%

2-(Dicyclohexylphosphino)-2'-methylbiphenyl Structure

2-(Dicyclohexyl...

CAS#:251320-86-2

Literature: Mauger, Christelle C.; Mignani, Gerard A. Organic Process Research and Development, 2004 , vol. 8, # 6 p. 1065 - 1071
2-Bromochlorobenzene structure

2-Bromochlorobenzene

CAS#:694-80-4

2-Chlorotoluene structure

2-Chlorotoluene

CAS#:95-49-8

chlorocyclohexylmagnesium structure

chlorocyclohexy...

CAS#:931-51-1

~58%

2-(Dicyclohexylphosphino)-2'-methylbiphenyl Structure

2-(Dicyclohexyl...

CAS#:251320-86-2

Literature: Tomori, Hiroshi; Fox, Joseph M.; Buchwald, Stephen L. Journal of Organic Chemistry, 2000 , vol. 65, # 17 p. 5334 - 5341

 Customs

HS Code 2902909090
Summary 2902909090 other aromatic hydrocarbons。Supervision conditions:None。VAT:17.0%。Tax rebate rate:9.0%。MFN tariff:2.0%。General tariff:30.0%

 Articles3

More Articles
Palladium-catalyzed Suzuki-Miyaura cross-coupling reactions employing dialkylbiaryl phosphine ligands.

Acc. Chem. Res. 41 , 1461, (2008)

The cores of many types of polymers, ligands, natural products, and pharmaceuticals contain biaryl or substituted aromatic structures, and efficient methods of synthesizing these structures are crucia...

Biaryl phosphane ligands in palladium-catalyzed amination.

Angew. Chem. Int. Ed. Engl. 47 , 6338, (2008)

Palladium-catalyzed amination reactions of aryl halides have undergone rapid development in the last 12 years, largely driven by the implementation of new classes of ligands. Biaryl phosphanes have pr...

Dialkylbiaryl Phosphines in Pd-Catalyzed Amination: A User's Guide.

Chem. Sci. 2 , 27, (2011)

Dialkylbiaryl phosphines are a valuable class of ligand for Pd-catalyzed amination reactions and have been applied in a range of contexts. This review attempts to aid the reader in the selection of th...

 Synonyms

Dicyclohexyl(2'-methylbiphenyl-2-yl)phosphine
2-Dicyclohexylphosphino-2′-methylbiphenyl
2-Methyl-2‘-dicyclohexylphosphinobiphenyl
MebiphPCy2
2-Methyl-2′-dicyclohexylphosphinobiphenyl
Dicyclohexyl(2'-methyl-2-biphenylyl)phosphine
2-Dicyclohexylphosphino-2'-methylbiphenyl
2-(Dicyclohexylphosphino)-2‘-methylbiphenyl
Phosphine, dicyclohexyl(2'-methyl[1,1'-biphenyl]-2-yl)-
MePhos
MFCD03094577
2-(Dicyclohexylphosphino)-2'-methylbiphenyl
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Chemsrc provides CAS#:251320-86-2 MSDS, density, melting point, boiling point, structure, etc. Its name is 2-(Dicyclohexylphosphino)-2'-methylbiphenyl>> amp version: 2-(Dicyclohexylphosphino)-2'-methylbiphenyl

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