trimethylsilyl 3-methylbut-2-enoate structure
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Common Name | trimethylsilyl 3-methylbut-2-enoate | ||
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CAS Number | 25436-25-3 | Molecular Weight | 172.29700 | |
Density | N/A | Boiling Point | 63ºC (13 mmHg) | |
Molecular Formula | C8H16O2Si | Melting Point | N/A | |
MSDS | N/A | Flash Point | N/A |
Name | trimethylsilyl 3-methylbut-2-enoate |
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Synonym | More Synonyms |
Boiling Point | 63ºC (13 mmHg) |
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Molecular Formula | C8H16O2Si |
Molecular Weight | 172.29700 |
Exact Mass | 172.09200 |
PSA | 26.30000 |
LogP | 2.33070 |
Synonym: Section 2 - COMPOSITION, INFORMATION ON INGREDIENTS
Risk Phrases: None Listed. Section 3 - HAZARDS IDENTIFICATION EMERGENCY OVERVIEW
Not available. Potential Health Effects Eye: May cause eye irritation. Skin: May cause skin irritation. Ingestion: May cause irritation of the digestive tract. The toxicological properties of this substance have not been fully investigated. Inhalation: May cause respiratory tract irritation. Chronic: Not available. Section 4 - FIRST AID MEASURES Eyes: Flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid. Skin: Get medical aid. Flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes. Ingestion: Get medical aid. Wash mouth out with water. Inhalation: Remove from exposure and move to fresh air immediately. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical aid. Notes to Physician: Section 5 - FIRE FIGHTING MEASURES General Information: As in any fire, wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. Extinguishing Media: Use extinguishing media most appropriate for the surrounding fire. Section 6 - ACCIDENTAL RELEASE MEASURES General Information: Use proper personal protective equipment as indicated in Section 8. Spills/Leaks: Absorb spill with inert material (e.g. vermiculite, sand or earth), then place in suitable container. Section 7 - HANDLING and STORAGE Handling: Avoid breathing dust, vapor, mist, or gas. Avoid contact with skin and eyes. Storage: Store in a tightly closed container. Keep refrigerated. (Store below 4C/39F.) Section 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION Engineering Controls: Use adequate ventilation to keep airborne concentrations low. Exposure Limits CAS# 25436-25-3: Personal Protective Equipment Eyes: Not available. Skin: Wear appropriate protective gloves to prevent skin exposure. Clothing: Wear appropriate protective clothing to prevent skin exposure. Respirators: Follow the OSHA respirator regulations found in 29 CFR 1910.134 or European Standard EN 149. Use a NIOSH/MSHA or European Standard EN 149 approved respirator if exposure limits are exceeded or if irritation or other symptoms are experienced. Section 9 - PHYSICAL AND CHEMICAL PROPERTIES Physical State: Liquid Color: colorless Odor: Not available. pH: Not available. Vapor Pressure: Not available. Viscosity: Not available. Boiling Point: 63 deg C @ 13.00mm Freezing/Melting Point: Not available. Autoignition Temperature: Not available. Flash Point: Not available. Explosion Limits, lower: Not available. Explosion Limits, upper: Not available. Decomposition Temperature: Solubility in water: Specific Gravity/Density: Molecular Formula: Molecular Weight: 172.30 Section 10 - STABILITY AND REACTIVITY Chemical Stability: Not available. Conditions to Avoid: Incompatible materials. Incompatibilities with Other Materials: Strong oxidizing agents. Hazardous Decomposition Products: Carbon monoxide, carbon dioxide. Hazardous Polymerization: Has not been reported Section 11 - TOXICOLOGICAL INFORMATION RTECS#: CAS# 25436-25-3 unlisted. LD50/LC50: Not available. Carcinogenicity: TRIMETHYLSILYL 3,3-DIMETHYLACRYLATE - Not listed by ACGIH, IARC, or NTP. Section 12 - ECOLOGICAL INFORMATION Section 13 - DISPOSAL CONSIDERATIONS Dispose of in a manner consistent with federal, state, and local regulations. Section 14 - TRANSPORT INFORMATION IATA No information available. IMO No information available. RID/ADR No information available. Section 15 - REGULATORY INFORMATION European/International Regulations European Labeling in Accordance with EC Directives Hazard Symbols: Not available. Risk Phrases: Safety Phrases: S 24/25 Avoid contact with skin and eyes. WGK (Water Danger/Protection) CAS# 25436-25-3: No information available. Canada None of the chemicals in this product are listed on the DSL/NDSL list. CAS# 25436-25-3 is not listed on Canada's Ingredient Disclosure List. US FEDERAL TSCA CAS# 25436-25-3 is not listed on the TSCA inventory. It is for research and development use only. SECTION 16 - ADDITIONAL INFORMATION N/A |
Safety Phrases | S24/25 |
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~88% trimethylsilyl ... CAS#:25436-25-3 |
Literature: Bellassoued, M.; Habbachi, F.; Gaudemar, M. Synthesis, 1983 , # 9 p. 745 - 746 |
~% trimethylsilyl ... CAS#:25436-25-3 |
Literature: Synthesis, , # 8 p. 684 - 686 |
~87% trimethylsilyl ... CAS#:25436-25-3 |
Literature: Khan; Blessing; Schmidt Synthesis, 1994 , # 3 p. 255 - 257 |
~% trimethylsilyl ... CAS#:25436-25-3 |
Literature: J. Gen. Chem. USSR (Engl. Transl.), , vol. 48, # 6 p. 1363 - 1368,1249 - 1253 |
Precursor 6 | |
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DownStream 8 | |
2-Butenoic acid,3-methyl-,trimethylsilyl ester |
trimethylsilyl 3,3-dimethylacrylate |
Crotonic acid,3-methyl-,trimethylsilyl ester |
crotonate de trimethylsilyle |
Trimethylsilyl 3-methyl-2-butenoate |
3-Butenoic acid,3-methyl-,trimethylsilyl ester |
MFCD01632556 |