trimethylsilyl 3-methylbut-2-enoate

Modify Date: 2024-01-09 18:54:28

trimethylsilyl 3-methylbut-2-enoate Structure
trimethylsilyl 3-methylbut-2-enoate structure
Common Name trimethylsilyl 3-methylbut-2-enoate
CAS Number 25436-25-3 Molecular Weight 172.29700
Density N/A Boiling Point 63ºC (13 mmHg)
Molecular Formula C8H16O2Si Melting Point N/A
MSDS N/A Flash Point N/A

 Names

Name trimethylsilyl 3-methylbut-2-enoate
Synonym More Synonyms

 Chemical & Physical Properties

Boiling Point 63ºC (13 mmHg)
Molecular Formula C8H16O2Si
Molecular Weight 172.29700
Exact Mass 172.09200
PSA 26.30000
LogP 2.33070

 MSDS

Name: TRIMETHYLSILYL 3 3-DIMETHYLACRYLATE Material Safety Data Sheet
Synonym:
CAS: 25436-25-3
Section 1 - Chemical Product MSDS Name:TRIMETHYLSILYL 3 3-DIMETHYLACRYLATE Material Safety Data Sheet
Synonym:

Section 2 - COMPOSITION, INFORMATION ON INGREDIENTS
CAS# Chemical Name content EINECS#
25436-25-3 TRIMETHYLSILYL 3,3-DIMETHYLACRYLATE unlisted
Hazard Symbols: None Listed.
Risk Phrases: None Listed.

Section 3 - HAZARDS IDENTIFICATION
EMERGENCY OVERVIEW
Not available.
Potential Health Effects
Eye:
May cause eye irritation.
Skin:
May cause skin irritation.
Ingestion:
May cause irritation of the digestive tract. The toxicological properties of this substance have not been fully investigated.
Inhalation:
May cause respiratory tract irritation.
Chronic:
Not available.

Section 4 - FIRST AID MEASURES
Eyes: Flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid.
Skin:
Get medical aid. Flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes.
Ingestion:
Get medical aid. Wash mouth out with water.
Inhalation:
Remove from exposure and move to fresh air immediately. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical aid.
Notes to Physician:

Section 5 - FIRE FIGHTING MEASURES
General Information:
As in any fire, wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear.
Extinguishing Media:
Use extinguishing media most appropriate for the surrounding fire.

Section 6 - ACCIDENTAL RELEASE MEASURES
General Information: Use proper personal protective equipment as indicated in Section 8.
Spills/Leaks:
Absorb spill with inert material (e.g. vermiculite, sand or earth), then place in suitable container.

Section 7 - HANDLING and STORAGE
Handling:
Avoid breathing dust, vapor, mist, or gas. Avoid contact with skin and eyes.
Storage:
Store in a tightly closed container. Keep refrigerated. (Store below 4C/39F.)

Section 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION
Engineering Controls:
Use adequate ventilation to keep airborne concentrations low.
Exposure Limits CAS# 25436-25-3: Personal Protective Equipment Eyes: Not available.
Skin:
Wear appropriate protective gloves to prevent skin exposure.
Clothing:
Wear appropriate protective clothing to prevent skin exposure.
Respirators:
Follow the OSHA respirator regulations found in 29 CFR 1910.134 or European Standard EN 149. Use a NIOSH/MSHA or European Standard EN 149 approved respirator if exposure limits are exceeded or if irritation or other symptoms are experienced.

Section 9 - PHYSICAL AND CHEMICAL PROPERTIES

Physical State: Liquid
Color: colorless
Odor: Not available.
pH: Not available.
Vapor Pressure: Not available.
Viscosity: Not available.
Boiling Point: 63 deg C @ 13.00mm
Freezing/Melting Point: Not available.
Autoignition Temperature: Not available.
Flash Point: Not available.
Explosion Limits, lower: Not available.
Explosion Limits, upper: Not available.
Decomposition Temperature:
Solubility in water:
Specific Gravity/Density:
Molecular Formula:
Molecular Weight: 172.30

Section 10 - STABILITY AND REACTIVITY
Chemical Stability:
Not available.
Conditions to Avoid:
Incompatible materials.
Incompatibilities with Other Materials:
Strong oxidizing agents.
Hazardous Decomposition Products:
Carbon monoxide, carbon dioxide.
Hazardous Polymerization: Has not been reported

Section 11 - TOXICOLOGICAL INFORMATION
RTECS#:
CAS# 25436-25-3 unlisted.
LD50/LC50:
Not available.
Carcinogenicity:
TRIMETHYLSILYL 3,3-DIMETHYLACRYLATE - Not listed by ACGIH, IARC, or NTP.

Section 12 - ECOLOGICAL INFORMATION


Section 13 - DISPOSAL CONSIDERATIONS
Dispose of in a manner consistent with federal, state, and local regulations.

Section 14 - TRANSPORT INFORMATION

IATA
No information available.
IMO
No information available.
RID/ADR
No information available.

Section 15 - REGULATORY INFORMATION

European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: Not available.
Risk Phrases:
Safety Phrases:
S 24/25 Avoid contact with skin and eyes.
WGK (Water Danger/Protection)
CAS# 25436-25-3: No information available.
Canada
None of the chemicals in this product are listed on the DSL/NDSL list.
CAS# 25436-25-3 is not listed on Canada's Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 25436-25-3 is not listed on the TSCA inventory.
It is for research and development use only.


SECTION 16 - ADDITIONAL INFORMATION
N/A

 Safety Information

Safety Phrases S24/25

 Synthetic Route

~88%

trimethylsilyl 3-methylbut-2-enoate Structure

trimethylsilyl ...

CAS#:25436-25-3

Literature: Bellassoued, M.; Habbachi, F.; Gaudemar, M. Synthesis, 1983 , # 9 p. 745 - 746

~%

trimethylsilyl 3-methylbut-2-enoate Structure

trimethylsilyl ...

CAS#:25436-25-3

Literature: Synthesis, , # 8 p. 684 - 686

~87%

trimethylsilyl 3-methylbut-2-enoate Structure

trimethylsilyl ...

CAS#:25436-25-3

Literature: Khan; Blessing; Schmidt Synthesis, 1994 , # 3 p. 255 - 257

~%

trimethylsilyl 3-methylbut-2-enoate Structure

trimethylsilyl ...

CAS#:25436-25-3

Literature: J. Gen. Chem. USSR (Engl. Transl.), , vol. 48, # 6 p. 1363 - 1368,1249 - 1253

 Synonyms

2-Butenoic acid,3-methyl-,trimethylsilyl ester
trimethylsilyl 3,3-dimethylacrylate
Crotonic acid,3-methyl-,trimethylsilyl ester
crotonate de trimethylsilyle
Trimethylsilyl 3-methyl-2-butenoate
3-Butenoic acid,3-methyl-,trimethylsilyl ester
MFCD01632556