p-trifluoromethylphenylhydrazine

Modify Date: 2024-01-02 11:28:18

p-trifluoromethylphenylhydrazine Structure
p-trifluoromethylphenylhydrazine structure
Common Name p-trifluoromethylphenylhydrazine
CAS Number 368-90-1 Molecular Weight 176.139
Density 1.4±0.1 g/cm3 Boiling Point 230.0±40.0 °C at 760 mmHg
Molecular Formula C7H7F3N2 Melting Point 63-65 °C(lit.)
MSDS Chinese USA Flash Point 92.9±27.3 °C
Symbol GHS07
GHS07
Signal Word Warning

 Names

Name 4-(Trifluoromethyl)phenylhydrazine
Synonym More Synonyms

 Chemical & Physical Properties

Density 1.4±0.1 g/cm3
Boiling Point 230.0±40.0 °C at 760 mmHg
Melting Point 63-65 °C(lit.)
Molecular Formula C7H7F3N2
Molecular Weight 176.139
Flash Point 92.9±27.3 °C
Exact Mass 176.056137
PSA 38.05000
LogP 2.26
Vapour Pressure 0.1±0.5 mmHg at 25°C
Index of Refraction 1.526
Storage condition 2-8°C

 Safety Information

Symbol GHS07
GHS07
Signal Word Warning
Hazard Statements H315-H319-H335
Precautionary Statements P261-P305 + P351 + P338
Personal Protective Equipment dust mask type N95 (US);Eyeshields;Gloves
Hazard Codes Xi:Irritant;
Risk Phrases R36/37/38
Safety Phrases S26-S36
RIDADR 2811
WGK Germany 3
Packaging Group III
HS Code 2928000090

 Synthetic Route

~40%

p-trifluoromethylphenylhydrazine Structure

p-trifluorometh...

CAS#:368-90-1

Literature: Aventis CropScience, S.A. Patent: US6410737 B1, 2002 ; Location in patent: Page column 7 ;

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p-trifluoromethylphenylhydrazine Structure

p-trifluorometh...

CAS#:368-90-1

Literature: May and Baker Limited Patent: US4496390 A1, 1985 ;

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p-trifluoromethylphenylhydrazine Structure

p-trifluorometh...

CAS#:368-90-1

Literature: Zhu, Mingzhao; Zheng, Nan Synthesis, 2011 , # 14 art. no. C01611SS, p. 2223 - 2236

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p-trifluoromethylphenylhydrazine Structure

p-trifluorometh...

CAS#:368-90-1

Literature: Nagarajan, K.; Talwalker, P.K.; Kulkarni, C.L.; Venkateswarlu, A.; Prabhu, S.S.; Nayak, G.V. Indian Journal of Chemistry, Section B: Organic Chemistry Including Medicinal Chemistry, 1984 , vol. 23, # 12 p. 1243 - 1257

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p-trifluoromethylphenylhydrazine Structure

p-trifluorometh...

CAS#:368-90-1

Literature: Safraoui, Adil; Calmon, Michelle; Calmon, Jean-Pierre Journal of the Chemical Society, Perkin Transactions 2: Physical Organic Chemistry (1972-1999), 1991 , # 9 p. 1349 - 1352

 Customs

HS Code 2928000090
Summary 2928000090 other organic derivatives of hydrazine or of hydroxylamine VAT:17.0% Tax rebate rate:9.0% Supervision conditions:none MFN tariff:6.5% General tariff:20.0%

 Articles2

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Nanoscale 6(13) , 7183-7, (2014)

A one-step reduction and functionalization of graphene oxide (FrGO) was easily achieved using a novel phenylhydrazine-based reductant containing fluorine atoms, which can induce p-type doping due to i...

2-Substituted paullones: CDK1/cyclin B-inhibiting property and in vitro antiproliferative activity.

Bioorg. Med. Chem. Lett. 10(6) , 567-9, (2000)

9-Trifluoromethyl-paullones with a carbon chain in the 2-position were synthesized by palladium-catalyzed coupling reactions of a 2-iodoprecursor with terminal alkenes or alkynes, respectively. The in...

 Synonyms

Hydrazine, [4-(trifluoromethyl)phenyl]-
(4-(Trifluoromethyl)phenyl)hydrazine
p-trifluoromethylphenylhydrazine
[4-(Trifluoromethyl)phenyl]hydrazine
MFCD00042508
4-(Trifluoromethyl)phenylhydrazine
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