(tert-Butylimido)osmium trioxide

Modify Date: 2024-01-09 15:52:59

(tert-Butylimido)osmium trioxide Structure
(tert-Butylimido)osmium trioxide structure
Common Name (tert-Butylimido)osmium trioxide
CAS Number 50381-48-1 Molecular Weight 309.34900
Density N/A Boiling Point N/A
Molecular Formula C4H9NO3Os Melting Point N/A
MSDS N/A Flash Point N/A

 Names

Name (tert-Butylimido)osmium trioxide
Synonym More Synonyms

 Chemical & Physical Properties

Molecular Formula C4H9NO3Os
Molecular Weight 309.34900
Exact Mass 311.02000
PSA 63.57000
LogP 1.16140

 MSDS

Name: (tert-Butylimido)osmium trioxide Material Safety Data Sheet
Synonym:
CAS: 50381-48-1
Section 1 - Chemical Product MSDS Name:(tert-Butylimido)osmium trioxide Material Safety Data Sheet
Synonym:

Section 2 - COMPOSITION, INFORMATION ON INGREDIENTS
CAS# Chemical Name content EINECS#
50381-48-1 (tert-Butylimido)osmium trioxide unlisted
Hazard Symbols: T
Risk Phrases: 23/24/25

Section 3 - HAZARDS IDENTIFICATION
EMERGENCY OVERVIEW
Toxic by inhalation, in contact with skin and if swallowed.
Potential Health Effects
Eye:
May cause eye irritation.
Skin:
May cause skin irritation. Toxic in contact with skin.
Ingestion:
May cause irritation of the digestive tract. Toxic if swallowed.
Inhalation:
May cause respiratory tract irritation. Toxic if inhaled.
Chronic:
Not available.

Section 4 - FIRST AID MEASURES
Eyes: Immediately flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid immediately.
Skin:
Get medical aid immediately. Immediately flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes.
Ingestion:
Get medical aid immediately. Wash mouth out with water.
Inhalation:
Get medical aid immediately. Remove from exposure and move to fresh air immediately. If not breathing, give artificial respiration. If breathing is difficult, give oxygen.
Notes to Physician:

Section 5 - FIRE FIGHTING MEASURES
General Information:
As in any fire, wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear.
Extinguishing Media:
Use water spray, dry chemical, carbon dioxide, or chemical foam.

Section 6 - ACCIDENTAL RELEASE MEASURES
General Information: Use proper personal protective equipment as indicated in Section 8.
Spills/Leaks:
Vacuum or sweep up material and place into a suitable disposal container.

Section 7 - HANDLING and STORAGE
Handling:
Do not breathe dust, vapor, mist, or gas. Do not get in eyes, on skin, or on clothing. Use only in a chemical fume hood.
Storage:
Do not store in direct sunlight. Keep refrigerated. (Store below 4C/39F.) Store in a tightly closed container. Store in a dry area.
Store under nitrogen.

Section 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION
Engineering Controls:
Use adequate ventilation to keep airborne concentrations low.
Exposure Limits CAS# 50381-48-1: Personal Protective Equipment Eyes: Not available.
Skin:
Wear appropriate protective gloves to prevent skin exposure.
Clothing:
Wear appropriate protective clothing to prevent skin exposure.
Respirators:
Follow the OSHA respirator regulations found in 29 CFR 1910.134 or European Standard EN 149. Use a NIOSH/MSHA or European Standard EN 149 approved respirator if exposure limits are exceeded or if irritation or other symptoms are experienced.

Section 9 - PHYSICAL AND CHEMICAL PROPERTIES

Physical State: Solid
Color: yellow to yellow-green
Odor: Not available.
pH: Not available.
Vapor Pressure: Not available.
Viscosity: Not available.
Boiling Point: Not available.
Freezing/Melting Point: 110 deg C(dec.)
Autoignition Temperature: Not available.
Flash Point: Not available.
Explosion Limits, lower: Not available.
Explosion Limits, upper: Not available.
Decomposition Temperature:
Solubility in water:
Specific Gravity/Density:
Molecular Formula: C4H9NO3Os
Molecular Weight: 309.32

Section 10 - STABILITY AND REACTIVITY
Chemical Stability:
Light sensitive.
Conditions to Avoid:
Incompatible materials, light.
Incompatibilities with Other Materials:
Strong oxidizing agents.
Hazardous Decomposition Products:
Nitrogen oxides, carbon monoxide, carbon dioxide.
Hazardous Polymerization: Has not been reported

Section 11 - TOXICOLOGICAL INFORMATION
RTECS#:
CAS# 50381-48-1 unlisted.
LD50/LC50:
Not available.
Carcinogenicity:
(tert-Butylimido)osmium trioxide - Not listed by ACGIH, IARC, or NTP.

Section 12 - ECOLOGICAL INFORMATION


Section 13 - DISPOSAL CONSIDERATIONS
Dispose of in a manner consistent with federal, state, and local regulations.

Section 14 - TRANSPORT INFORMATION

IATA
Shipping Name: TOXIC SOLID, ORGANIC, N.O.S.*
Hazard Class: 6.1
UN Number: 2811
Packing Group: II
IMO
Shipping Name: TOXIC SOLID, ORGANIC, N.O.S.
Hazard Class: 6.1
UN Number: 2811
Packing Group: II
RID/ADR
Shipping Name: TOXIC SOLID, ORGANIC, N.O.S.
Hazard Class: 6.1
UN Number: 2811
Packing group: II

Section 15 - REGULATORY INFORMATION

European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: T
Risk Phrases:
R 23/24/25 Toxic by inhalation, in contact with skin
and if swallowed.
Safety Phrases:
S 22 Do not breathe dust.
S 28A After contact with skin, wash immediately with
plenty of water.
S 36/37/39 Wear suitable protective clothing, gloves
and eye/face protection.
S 45 In case of accident or if you feel unwell, seek
medical advice immediately (show the label where
possible).
WGK (Water Danger/Protection)
CAS# 50381-48-1: No information available.
Canada
None of the chemicals in this product are listed on the DSL/NDSL list.
CAS# 50381-48-1 is not listed on Canada's Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 50381-48-1 is not listed on the TSCA inventory.
It is for research and development use only.


SECTION 16 - ADDITIONAL INFORMATION
N/A

 Safety Information

Hazard Codes T
Risk Phrases R23/24/25
Safety Phrases S22;S28;S45;S36/S37/S39
HS Code 2925290090

 Synthetic Route

~%

(tert-Butylimido)osmium trioxide Structure

(tert-Butylimid...

CAS#:50381-48-1

Literature: Patrick,D.W. et al. Journal of Organic Chemistry, 1978 , vol. 43, p. 2628 - 2638 Full Text View citing articles Show Details Milas; Iliopulos Journal of the American Chemical Society, 1959 , vol. 81, p. 6089 Full Text View citing articles Show Details Clifford, A. F.; Kobayashi, C. S. Inorganic Syntheses, 1960 , vol. 6, p. 204 - 208

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(tert-Butylimido)osmium trioxide Structure

(tert-Butylimid...

CAS#:50381-48-1

Detail
Literature: Chong,A.O. et al. Journal of the American Chemical Society, 1977 , vol. 99, p. 3420 - 3426 Full Text View citing articles Show Details Gmelin Handbook: Os: SVol.1, 3.2.1.6.7.3, page 92 - 92

 Customs

HS Code 2925290090
Summary 2925290090 other imines and their derivatives; salts thereof。Supervision conditions:None。VAT:17.0%。Tax rebate rate:9.0%。MFN tariff:6.5%。General tariff:30.0%

 Synonyms

Chlorates
chloric acid anion
n.o.s.,wet
tert.-Butylimido-Osmiumtrioxid
(TERT-BUTYLIMIDO)OSMIUM TRIOXIDE
chlorate anion
chlorine trioxide anion
Chlorine oxide
Chlorate ion
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