2,3,5-Tri-O-benzyl-D-arabinofuranose 1-(4-nitrobenzoate)

Modify Date: 2024-01-09 23:36:34

2,3,5-Tri-O-benzyl-D-arabinofuranose 1-(4-nitrobenzoate) Structure
2,3,5-Tri-O-benzyl-D-arabinofuranose 1-(4-nitrobenzoate) structure
Common Name 2,3,5-Tri-O-benzyl-D-arabinofuranose 1-(4-nitrobenzoate)
CAS Number 52522-49-3 Molecular Weight 569.601
Density 1.3±0.1 g/cm3 Boiling Point 706.2±60.0 °C at 760 mmHg
Molecular Formula C33H31NO8 Melting Point 69-72ºC
MSDS N/A Flash Point 246.8±34.9 °C

 Names

Name 2,3,5-tri-O-benzyl-1,0-(4-nitrobenzoyl)-D-arabinofuranose
Synonym More Synonyms

 Chemical & Physical Properties

Density 1.3±0.1 g/cm3
Boiling Point 706.2±60.0 °C at 760 mmHg
Melting Point 69-72ºC
Molecular Formula C33H31NO8
Molecular Weight 569.601
Flash Point 246.8±34.9 °C
Exact Mass 569.204956
PSA 109.04000
LogP 8.36
Vapour Pressure 0.0±2.2 mmHg at 25°C
Index of Refraction 1.631
Storage condition −20°C

 MSDS

Name: 2 3 5-Tri-O-benzyl-1-O-(4-Nitrobenzoyl)-D-Arabinofuranose 97% Material Safety Data Sheet
Synonym: None
CAS: 52522-49-3
Section 1 - Chemical Product MSDS Name:2 3 5-Tri-O-benzyl-1-O-(4-Nitrobenzoyl)-D-Arabinofuranose 97% Material Safety Data Sheet
Synonym:None

Section 2 - COMPOSITION, INFORMATION ON INGREDIENTS
CAS# Chemical Name content EINECS#
52522-49-3 2,3,5-Tri-O-benzyl-1-O-(4-Nitrobenzoyl 97% 257-992-5
Hazard Symbols: None Listed.
Risk Phrases: None Listed.

Section 3 - HAZARDS IDENTIFICATION
EMERGENCY OVERVIEW
The toxicological properties of this material have not been fully investigated.
Potential Health Effects
Eye:
May cause eye irritation.
Skin:
May cause skin irritation.
Ingestion:
May cause irritation of the digestive tract. The toxicological properties of this substance have not been fully investigated.
Inhalation:
May cause respiratory tract irritation. The toxicological properties of this substance have not been fully investigated.
Chronic:
No information found.

Section 4 - FIRST AID MEASURES
Eyes: Flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid.
Skin:
Get medical aid. Flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes. Wash clothing before reuse.
Ingestion:
Never give anything by mouth to an unconscious person. Get medical aid. Do NOT induce vomiting. If conscious and alert, rinse mouth and drink 2-4 cupfuls of milk or water. Wash mouth out with water.
Inhalation:
Remove from exposure and move to fresh air immediately. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical aid.
Notes to Physician:

Section 5 - FIRE FIGHTING MEASURES
General Information:
As in any fire, wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. During a fire, irritating and highly toxic gases may be generated by thermal decomposition or combustion.
Extinguishing Media:
Use agent most appropriate to extinguish fire. Use water spray, dry chemical, carbon dioxide, or appropriate foam.

Section 6 - ACCIDENTAL RELEASE MEASURES
General Information: Use proper personal protective equipment as indicated in Section 8.
Spills/Leaks:
Vacuum or sweep up material and place into a suitable disposal container. Clean up spills immediately, observing precautions in the Protective Equipment section. Avoid generating dusty conditions.
Provide ventilation.

Section 7 - HANDLING and STORAGE
Handling:
Wash thoroughly after handling. Use with adequate ventilation.
Minimize dust generation and accumulation. Avoid contact with eyes, skin, and clothing. Keep container tightly closed. Avoid ingestion and inhalation.
Storage:
Store in a tightly closed container. Store in a cool, dry, well-ventilated area away from incompatible substances.

Section 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION
Engineering Controls:
Facilities storing or utilizing this material should be equipped with an eyewash facility and a safety shower. Use adequate ventilation to keep airborne concentrations low.
Exposure Limits CAS# 52522-49-3: Personal Protective Equipment Eyes: Wear appropriate protective eyeglasses or chemical safety goggles as described by OSHA's eye and face protection regulations in 29 CFR 1910.133 or European Standard EN166.
Skin:
Wear appropriate protective gloves to prevent skin exposure.
Clothing:
Wear appropriate protective clothing to prevent skin exposure.
Respirators:
A respiratory protection program that meets OSHA's 29 CFR 1910.134 and ANSI Z88.2 requirements or European Standard EN 149 must be followed whenever workplace conditions warrant respirator use.

Section 9 - PHYSICAL AND CHEMICAL PROPERTIES

Physical State: Powder
Color: off-white powder
Odor: odorless
pH: Not available.
Vapor Pressure: Not available.
Viscosity: Not available.
Boiling Point: Not available.
Freezing/Melting Point: 69-72C
Autoignition Temperature: Not applicable.
Flash Point: Not applicable.
Explosion Limits, lower: Not available.
Explosion Limits, upper: Not available.
Decomposition Temperature:
Solubility in water:
Specific Gravity/Density:
Molecular Formula: C33H31NO8
Molecular Weight: 569.2189

Section 10 - STABILITY AND REACTIVITY
Chemical Stability:
Stable under normal temperatures and pressures.
Conditions to Avoid:
Incompatible materials, dust generation, excess heat.
Incompatibilities with Other Materials:
Oxidizing agents.
Hazardous Decomposition Products:
Carbon monoxide, irritating and toxic fumes and gases, carbon dioxide.
Hazardous Polymerization: Will not occur.

Section 11 - TOXICOLOGICAL INFORMATION
RTECS#:
CAS# 52522-49-3 unlisted.
LD50/LC50:
Not available.
Carcinogenicity:
2,3,5-Tri-O-benzyl-1-O-(4-Nitrobenzoyl)-D-Arabinofuranose - Not listed by ACGIH, IARC, or NTP.

Section 12 - ECOLOGICAL INFORMATION


Section 13 - DISPOSAL CONSIDERATIONS
Dispose of in a manner consistent with federal, state, and local regulations.

Section 14 - TRANSPORT INFORMATION

IATA
Not regulated as a hazardous material.
IMO
Not regulated as a hazardous material.
RID/ADR
Not regulated as a hazardous material.

Section 15 - REGULATORY INFORMATION

European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: Not available.
Risk Phrases:
Safety Phrases:
S 24/25 Avoid contact with skin and eyes.
S 28A After contact with skin, wash immediately with
plenty of water.
S 37 Wear suitable gloves.
S 45 In case of accident or if you feel unwell, seek
medical advice immediately (show the label where
possible).
WGK (Water Danger/Protection)
CAS# 52522-49-3: No information available.
Canada
None of the chemicals in this product are listed on the DSL/NDSL list.
CAS# 52522-49-3 is not listed on Canada's Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 52522-49-3 is not listed on the TSCA inventory.
It is for research and development use only.


SECTION 16 - ADDITIONAL INFORMATION
N/A

 Safety Information

Hazard Codes Xi
Safety Phrases 24/25
WGK Germany 3

 Synthetic Route

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2,3,5-Tri-O-benzyl-D-arabinofuranose 1-(4-nitrobenzoate) Structure

2,3,5-Tri-O-ben...

CAS#:52522-49-3

Literature: Kadir, Kamaliah; Mackenzie, Grahame; Shaw, Gordon Journal of the Chemical Society, Perkin Transactions 1: Organic and Bio-Organic Chemistry (1972-1999), 1980 , p. 2304 - 2309

 Synonyms

2,3,5-tri-O-benzyl-1-O-(p-nitrobenzoyl)-D-arabinofuranose
2,3,5-TRI-O-BENZYL-D-ARABINOFURANOSE-1
2,3,5-Tri-O-benzyl-D-arabinofuranose 1-(4-nitrobenzoate)
2,3,5-Tri-O-benzyl-1-O-(4-nitrobenzoyl)-D-arabinofuranose
D-Arabinofuranose, 2,3,5-tris-O-(phenylmethyl)-, 4-nitrobenzoate
1-O-(4-nitrobenzoyl)-2,3,5-tri-O-benzyl-D-arabinofuranose
MFCD00038477
2,3,5-tri-O -benzyl-1-O-p-nitrobenzoyl-D-arabinofuranose
2,3,5-tri-O-benzyl-1-(4-nitrobenzoyloxy)-D-arabinofuranose
4-nitrobenzoate 2,3,5-tris-O-benzyl-D-arabinofuranose
EINECS 257-992-5
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