α-Bromocinnamaldehyde

Modify Date: 2024-01-11 18:36:57

α-Bromocinnamaldehyde Structure
α-Bromocinnamaldehyde structure
Common Name α-Bromocinnamaldehyde
CAS Number 5443-49-2 Molecular Weight 211.055
Density 1.5±0.1 g/cm3 Boiling Point 304.4±30.0 °C at 760 mmHg
Molecular Formula C9H7BrO Melting Point 66-68 °C(lit.)
MSDS Chinese USA Flash Point 110.2±11.9 °C
Symbol GHS07
GHS07
Signal Word Warning

 Names

Name 2-Bromocinnamaldehyde
Synonym More Synonyms

 Chemical & Physical Properties

Density 1.5±0.1 g/cm3
Boiling Point 304.4±30.0 °C at 760 mmHg
Melting Point 66-68 °C(lit.)
Molecular Formula C9H7BrO
Molecular Weight 211.055
Flash Point 110.2±11.9 °C
Exact Mass 209.968018
PSA 17.07000
LogP 2.44
Vapour Pressure 0.0±0.6 mmHg at 25°C
Index of Refraction 1.627
Storage condition 2-8°C

 Toxicological Information

CHEMICAL IDENTIFICATION

RTECS NUMBER :
GD6480000
CHEMICAL NAME :
Cinnamaldehyde, alpha-bromo-
CAS REGISTRY NUMBER :
5443-49-2
BEILSTEIN REFERENCE NO. :
1099733
LAST UPDATED :
199612
DATA ITEMS CITED :
2
MOLECULAR FORMULA :
C9-H7-Br-O
MOLECULAR WEIGHT :
211.07
WISWESSER LINE NOTATION :
VHYEU1R

HEALTH HAZARD DATA

ACUTE TOXICITY DATA

TYPE OF TEST :
LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE :
Oral
SPECIES OBSERVED :
Rodent - mouse
DOSE/DURATION :
470 mg/kg
TOXIC EFFECTS :
Sense Organs and Special Senses (Eye) - ptosis Behavioral - ataxia Gastrointestinal - hypermotility, diarrhea

MUTATION DATA

TYPE OF TEST :
Mutation in microorganisms
TEST SYSTEM :
Bacteria - Salmonella typhimurium
DOSE/DURATION :
5 nmol/plate
REFERENCE :
MUREAV Mutation Research. (Elsevier Science Pub. B.V., POB 211, 1000 AE Amsterdam, Netherlands) V.1- 1964- Volume(issue)/page/year: 110,1,1983

 Safety Information

Symbol GHS07
GHS07
Signal Word Warning
Hazard Statements H302-H315-H319-H335
Precautionary Statements P261-P305 + P351 + P338
Personal Protective Equipment dust mask type N95 (US);Eyeshields;Gloves
Hazard Codes Xn:Harmful
Risk Phrases R22;R36/37/38
Safety Phrases S26-S36/37/39-S22
RIDADR UN 3335
WGK Germany 3
RTECS GD6480000
HS Code 2913000090

 Synthetic Route

~83%

α-Bromocinnamaldehyde Structure

α-Bromocinnamal...

CAS#:5443-49-2

Literature: Saraf, S. D. Journal fuer Praktische Chemie (Leipzig), 1981 , vol. 323, # 4 p. 673 - 676

~92%

α-Bromocinnamaldehyde Structure

α-Bromocinnamal...

CAS#:5443-49-2

Literature: Yao, Changsheng; Wang, Donglin; Lu, Jun; Li, Tuanjie; Jiao, Weihui; Yu, Chenxia Chemistry - A European Journal, 2012 , vol. 18, # 7 p. 1914 - 1917

~42%

α-Bromocinnamaldehyde Structure

α-Bromocinnamal...

CAS#:5443-49-2

Literature: Migalina, Yu. V.; Galla-Bobik, S. V.; Lendel, V. G.; Staninets, V. I. J. Gen. Chem. USSR (Engl. Transl.), 1982 , vol. 52, # 7 p. 1563 - 1566,1380 - 1382

~%

α-Bromocinnamaldehyde Structure

α-Bromocinnamal...

CAS#:5443-49-2

Literature: Chemische Berichte, , vol. 95, p. 3003 - 3007

~%

α-Bromocinnamaldehyde Structure

α-Bromocinnamal...

CAS#:5443-49-2

Literature: Chemische Berichte, , vol. 17, p. 1815

 Customs

HS Code 2913000090
Summary HS: 2913000090 halogenated, sulphonated, nitrated or nitrosated derivatives of products of heading 2912 Educational tariff:17.0% Tax rebate rate:9.0% Regulatory conditions:none Most favored nation tariff:5.5% General tariff:30.0%

 Articles5

More Articles
Masuda borylation-Suzuki coupling (MBSC) sequence of vinylhalides and its application in a one-pot synthesis of 3,4-biarylpyrazoles.

Org. Biomol. Chem. 11(36) , 6113-8, (2013)

The Masuda borylation-Suzuki coupling (MBSC) sequence was successfully extended to the challenging coupling of vinylhalides with various (hetero)arylhalides using sterically hindered phosphane ligands...

[Alpha-bromocinnamaldehyde, its mutagenicity and contents in commercial products].

Eisei Shikenjo Hokoku. (107) , 21-5, (1989)

The amount of alpha-bromocinnamaldehyde (BCA), an anti-mildew agent, in some commercial products, was examined by high performance liquid chromatography (HPLC) using the following conditions: column, ...

Guanidinium ylide mediated aziridination: identification of a spiro imidazolidine-oxazolidine intermediate.

J. Org. Chem. 71(17) , 6600-3, (2006)

We successfully isolated a spiro imidazolidine-oxazolidine intermediate in the reaction of guanidinium ylide mediated aziridination using alpha-bromocinnamaldehyde. X-ray crystallographic analysis una...

 Synonyms

A-BROMOCINNAMIC ACID
b36
b37
2-bromo-3-phenylpropenal
α-Bromocinnamic aldehyde
(2Z)-2-bromo-3-phenylprop-2-enal
2-Propenal, 2-bromo-3-phenyl-, (Z)-
EINECS 226-637-6
Cinnamaldehyde, α-bromo-
BROMOCINNAMAL
2-Propenal, 2-bromo-3-phenyl-, (2Z)-
Alphabrocine
a-Bromocinnamaldehyde
2-bromo-3-phenylacrylaldehyde
MFCD00006965
2-bromo-3-phenylacrolein
(2Z)-2-Bromo-3-phenylacrylaldehyde
α-Bromocinnamaldehyde