Methyl 3-((trimethylsilyl)oxy)-2-butenoate

Modify Date: 2024-01-09 12:22:08

Methyl 3-((trimethylsilyl)oxy)-2-butenoate Structure
Methyl 3-((trimethylsilyl)oxy)-2-butenoate structure
Common Name Methyl 3-((trimethylsilyl)oxy)-2-butenoate
CAS Number 62269-44-7 Molecular Weight 188.296
Density 0.9±0.1 g/cm3 Boiling Point 178.6±23.0 °C at 760 mmHg
Molecular Formula C8H16O3Si Melting Point N/A
MSDS N/A Flash Point 63.9±0.0 °C

 Names

Name 3-(trimethylsilyloxy)crotonic acid methyl ester
Synonym More Synonyms

 Chemical & Physical Properties

Density 0.9±0.1 g/cm3
Boiling Point 178.6±23.0 °C at 760 mmHg
Molecular Formula C8H16O3Si
Molecular Weight 188.296
Flash Point 63.9±0.0 °C
Exact Mass 188.086868
PSA 35.53000
LogP 2.25
Vapour Pressure 1.0±0.3 mmHg at 25°C
Index of Refraction 1.427
Storage condition 2-8°C

 Safety Information

Hazard Codes Xi
Risk Phrases 36/37/38-10
Safety Phrases 26-36/37/39-24/25-23
RIDADR UN 1993 3/PG 3
WGK Germany 3
Packaging Group III
Hazard Class 3.2
HS Code 2931900090

 Synthetic Route

~86%

Methyl 3-((trimethylsilyl)oxy)-2-butenoate Structure

Methyl 3-((trim...

CAS#:62269-44-7

Literature: Kimura, Masanari; Ezoe, Akihiro; Mori, Masahiko; Iwata, Keisuke; Tamaru, Yoshinao Journal of the American Chemical Society, 2006 , vol. 128, # 26 p. 8559 - 8568

~83%

Methyl 3-((trimethylsilyl)oxy)-2-butenoate Structure

Methyl 3-((trim...

CAS#:62269-44-7

Literature: Organix, Inc.; President and Fellows of Harvard College Patent: US5770180 A1, 1998 ; US 5770180 A

~88%

Methyl 3-((trimethylsilyl)oxy)-2-butenoate Structure

Methyl 3-((trim...

CAS#:62269-44-7

Literature: Aizpurua, Jesus Mari; Palomo, Claudio Synthesis, 1982 , # 4 p. 280 - 281

~%

Methyl 3-((trimethylsilyl)oxy)-2-butenoate Structure

Methyl 3-((trim...

CAS#:62269-44-7

Literature: Synthesis, , p. 722 - 724

~%

Methyl 3-((trimethylsilyl)oxy)-2-butenoate Structure

Methyl 3-((trim...

CAS#:62269-44-7

Literature: J. Gen. Chem. USSR (Engl. Transl.), , vol. 40, # 1 p. 97 - 104,88 - 93

~%

Methyl 3-((trimethylsilyl)oxy)-2-butenoate Structure

Methyl 3-((trim...

CAS#:62269-44-7

Literature: Liebigs Annalen der Chemie, , # 7 p. 1237 - 1248

~%

Methyl 3-((trimethylsilyl)oxy)-2-butenoate Structure

Methyl 3-((trim...

CAS#:62269-44-7

Literature: Organic Mass Spectrometry, , vol. 22, p. 486 - 492

~%

Methyl 3-((trimethylsilyl)oxy)-2-butenoate Structure

Methyl 3-((trim...

CAS#:62269-44-7

Literature: J. Gen. Chem. USSR (Engl. Transl.), , vol. 40, # 1 p. 97 - 104,88 - 93

~%

Methyl 3-((trimethylsilyl)oxy)-2-butenoate Structure

Methyl 3-((trim...

CAS#:62269-44-7

Literature: Zeitschrift fuer Chemie (Stuttgart, Germany), , vol. 28, # 11 p. 409 - 410

 Customs

HS Code 2931900090
Summary 2931900090. other organo-inorganic compounds. VAT:17.0%. Tax rebate rate:13.0%. Supervision conditions:AB(certificate of inspection for goods inward,certificate of inspection for goods outward). MFN tariff:6.5%. General tariff:30.0%

 Synonyms

2-Butenoic acid, 3-[(trimethylsilyl)oxy]-, methyl ester, (2E)-
3-TRIMETHYLSILOXY-2-BUTENOIC ACID METHYL ESTER
Methyl (2Z)-3-[(trimethylsilyl)oxy]but-2-enoate
methyl 3-trimethylsilyloxy-2-butenoate
methyl 3-trimethylsiloxybut-2-enoate
MFCD00008457
Methyl (2Z)-3-[(trimethylsilyl)oxy]-2-butenoate
Methyl 3-((trimethylsilyl)oxy)-2-butenoate
METHYL ACETOACETATE ENOL TRIMETHYLSILYL ETHER
2-Butenoic acid, 3-[(trimethylsilyl)oxy]-, methyl ester, (2Z)-
Methyl (2E)-3-[(trimethylsilyl)oxy]-2-butenoate
METHYL 3-TRIMETHYLSILOXY-2-BUTENOATE
EINECS 263-483-9
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