Ethyl 2-methylthiazole-4-carboxylate

Modify Date: 2024-01-04 13:41:54

Ethyl 2-methylthiazole-4-carboxylate Structure
Ethyl 2-methylthiazole-4-carboxylate structure
Common Name Ethyl 2-methylthiazole-4-carboxylate
CAS Number 6436-59-5 Molecular Weight 171.217
Density 1.2±0.1 g/cm3 Boiling Point 242.1±13.0 °C at 760 mmHg
Molecular Formula C7H9NO2S Melting Point 54-56°C
MSDS Chinese USA Flash Point 100.2±19.8 °C

 Names

Name Ethyl 2-methylthiazole-4-carboxylate
Synonym More Synonyms

 Chemical & Physical Properties

Density 1.2±0.1 g/cm3
Boiling Point 242.1±13.0 °C at 760 mmHg
Melting Point 54-56°C
Molecular Formula C7H9NO2S
Molecular Weight 171.217
Flash Point 100.2±19.8 °C
Exact Mass 171.035400
PSA 67.43000
LogP 1.61
Vapour Pressure 0.0±0.5 mmHg at 25°C
Index of Refraction 1.528
Storage condition Refrigerated.

 MSDS

Name: Ethyl 2-methyl-1 3-thiazole-4-carboxylate 97% Material Safety Data Sheet
Synonym:
CAS: 6436-59-5
Section 1 - Chemical Product MSDS Name:Ethyl 2-methyl-1 3-thiazole-4-carboxylate 97% Material Safety Data Sheet
Synonym:

Section 2 - COMPOSITION, INFORMATION ON INGREDIENTS
CAS# Chemical Name content EINECS#
6436-59-5 Ethyl 2-methyl-1,3-thiazole-4-carboxyl 97% unlisted
Hazard Symbols: None Listed.
Risk Phrases: None Listed.

Section 3 - HAZARDS IDENTIFICATION
EMERGENCY OVERVIEW
Not available.
Potential Health Effects
Eye:
May cause eye irritation.
Skin:
May cause skin irritation. May be harmful if absorbed through the skin.
Ingestion:
May cause irritation of the digestive tract. May be harmful if swallowed.
Inhalation:
May cause respiratory tract irritation. May be harmful if inhaled.
Chronic:
Not available.

Section 4 - FIRST AID MEASURES
Eyes: Flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid.
Skin:
Get medical aid. Flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes.
Ingestion:
Get medical aid. Wash mouth out with water.
Inhalation:
Remove from exposure and move to fresh air immediately.
Notes to Physician:
Treat symptomatically and supportively.

Section 5 - FIRE FIGHTING MEASURES
General Information:
As in any fire, wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear.
Extinguishing Media:
Use water spray, dry chemical, carbon dioxide, or chemical foam.

Section 6 - ACCIDENTAL RELEASE MEASURES
General Information: Use proper personal protective equipment as indicated in Section 8.
Spills/Leaks:
Vacuum or sweep up material and place into a suitable disposal container.

Section 7 - HANDLING and STORAGE
Handling:
Avoid breathing dust, vapor, mist, or gas. Avoid contact with skin and eyes.
Storage:
Store in a cool, dry place. Store in a tightly closed container.

Section 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION
Engineering Controls:
Use adequate ventilation to keep airborne concentrations low.
Exposure Limits CAS# 6436-59-5: Personal Protective Equipment Eyes: Not available.
Skin:
Wear appropriate protective gloves to prevent skin exposure.
Clothing:
Wear appropriate protective clothing to prevent skin exposure.
Respirators:
Follow the OSHA respirator regulations found in 29 CFR 1910.134 or European Standard EN 149. Use a NIOSH/MSHA or European Standard EN 149 approved respirator if exposure limits are exceeded or if irritation or other symptoms are experienced.

Section 9 - PHYSICAL AND CHEMICAL PROPERTIES

Physical State: Solid
Color: yellow - brown
Odor: Not available.
pH: Not available.
Vapor Pressure: Not available.
Viscosity: Not available.
Boiling Point: Not available.
Freezing/Melting Point: 54 - 56 deg C
Autoignition Temperature: Not available.
Flash Point: Not available.
Explosion Limits, lower: Not available.
Explosion Limits, upper: Not available.
Decomposition Temperature:
Solubility in water:
Specific Gravity/Density:
Molecular Formula: C7H9NO2S
Molecular Weight: 171

Section 10 - STABILITY AND REACTIVITY
Chemical Stability:
Not available.
Conditions to Avoid:
Incompatible materials.
Incompatibilities with Other Materials:
Oxidizing agents, reducing agents, bases, amines.
Hazardous Decomposition Products:
Hydrogen cyanide, nitrogen oxides, carbon monoxide, oxides of sulfur, carbon dioxide.
Hazardous Polymerization: Has not been reported

Section 11 - TOXICOLOGICAL INFORMATION
RTECS#:
CAS# 6436-59-5 unlisted.
LD50/LC50:
Not available.
Carcinogenicity:
Ethyl 2-methyl-1,3-thiazole-4-carboxylate - Not listed by ACGIH, IARC, or NTP.

Section 12 - ECOLOGICAL INFORMATION


Section 13 - DISPOSAL CONSIDERATIONS
Dispose of in a manner consistent with federal, state, and local regulations.

Section 14 - TRANSPORT INFORMATION

IATA
No information available.
IMO
No information available.
RID/ADR
No information available.

Section 15 - REGULATORY INFORMATION

European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: Not available.
Risk Phrases:
Safety Phrases:
S 24/25 Avoid contact with skin and eyes.
WGK (Water Danger/Protection)
CAS# 6436-59-5: No information available.
Canada
None of the chemicals in this product are listed on the DSL/NDSL list.
CAS# 6436-59-5 is not listed on Canada's Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 6436-59-5 is not listed on the TSCA inventory.
It is for research and development use only.


SECTION 16 - ADDITIONAL INFORMATION
N/A

 Safety Information

Hazard Codes Xi
Risk Phrases R36/37/38
Safety Phrases S26-S37
RIDADR NONH for all modes of transport
HS Code 2934100090

 Synthetic Route

~96%

Ethyl 2-methylthiazole-4-carboxylate Structure

Ethyl 2-methylt...

CAS#:6436-59-5

Literature: Zhan, Weiqiang; Jiang, Yi; Brodie, Peggy J.; Kingston, David G. I.; Liotta, Dennis C.; Snyder, James P. Organic Letters, 2008 , vol. 10, # 8 p. 1565 - 1568

~93%

Ethyl 2-methylthiazole-4-carboxylate Structure

Ethyl 2-methylt...

CAS#:6436-59-5

Literature: Williams, David R.; Lowder, Patrick D.; Gu, Yu-Gui; Brooks, Dawn A. Tetrahedron Letters, 1997 , vol. 38, # 3 p. 331 - 334

~67%

Ethyl 2-methylthiazole-4-carboxylate Structure

Ethyl 2-methylt...

CAS#:6436-59-5

Literature: Huang, Yue; Gan, Haifeng; Li, Shang; Xu, Jinyi; Wu, Xiaoming; Yao, Hequan Tetrahedron Letters, 2010 , vol. 51, # 13 p. 1751 - 1753

~%

Ethyl 2-methylthiazole-4-carboxylate Structure

Ethyl 2-methylt...

CAS#:6436-59-5

Literature: Tetrahedron Letters, , vol. 55, # 16 p. 2671 - 2674

~56%

Ethyl 2-methylthiazole-4-carboxylate Structure

Ethyl 2-methylt...

CAS#:6436-59-5

Literature: Kim, Hong-Seok; Kwon, Il-Cheon; Kim, Oh-Hwoan Journal of Heterocyclic Chemistry, 1995 , vol. 32, # 3 p. 937 - 940

~%

Ethyl 2-methylthiazole-4-carboxylate Structure

Ethyl 2-methylt...

CAS#:6436-59-5

Literature: Organic Letters, , vol. 14, # 24 p. 6354 - 6357

~%

Ethyl 2-methylthiazole-4-carboxylate Structure

Ethyl 2-methylt...

CAS#:6436-59-5

Literature: Bioorganic and Medicinal Chemistry Letters, , vol. 12, # 8 p. 1203 - 1208

~%

Ethyl 2-methylthiazole-4-carboxylate Structure

Ethyl 2-methylt...

CAS#:6436-59-5

Literature: Journal of the Chemical Society. Perkin transactions 1, , vol. 12, p. 1061 - 1065

~%

Ethyl 2-methylthiazole-4-carboxylate Structure

Ethyl 2-methylt...

CAS#:6436-59-5

Literature: Tetrahedron Letters, , vol. 55, # 16 p. 2671 - 2674

 Customs

HS Code 2934100090
Summary 2934100090 other compounds containing an unfused thiazole ring (whether or not hydrogenated) in the structure VAT:17.0% Tax rebate rate:9.0% Supervision conditions:none MFN tariff:6.5% General tariff:20.0%

 Synonyms

4-Thiazolecarboxylic acid, 2-methyl-, ethyl ester
2-Methyl-thiazole-4-carboxylic acid ethyl ester
Ethyl 2-methyl-1,3-thiazole-4-carboxylate
Ethyl 2-methylthiazole-4-carboxylate
MFCD00156148
Top Suppliers:I want be here



Get all suppliers and price by the below link:

Ethyl 2-methylthiazole-4-carboxylate suppliers

Ethyl 2-methylthiazole-4-carboxylate price