Ethyl 2,4-dimethyl-1,3-thiazole-5-carboxylate

Modify Date: 2024-01-04 22:41:02

Ethyl 2,4-dimethyl-1,3-thiazole-5-carboxylate Structure
Ethyl 2,4-dimethyl-1,3-thiazole-5-carboxylate structure
Common Name Ethyl 2,4-dimethyl-1,3-thiazole-5-carboxylate
CAS Number 7210-77-7 Molecular Weight 185.243
Density 1.2±0.1 g/cm3 Boiling Point 254.3±20.0 °C at 760 mmHg
Molecular Formula C8H11NO2S Melting Point 48-50 °C
MSDS Chinese USA Flash Point 107.6±21.8 °C

 Names

Name ethyl 2,4-dimethylthiazole-5-carboxylate
Synonym More Synonyms

 Chemical & Physical Properties

Density 1.2±0.1 g/cm3
Boiling Point 254.3±20.0 °C at 760 mmHg
Melting Point 48-50 °C
Molecular Formula C8H11NO2S
Molecular Weight 185.243
Flash Point 107.6±21.8 °C
Exact Mass 185.051056
PSA 67.43000
LogP 2.07
Vapour Pressure 0.0±0.5 mmHg at 25°C
Index of Refraction 1.525

 MSDS

Name: Ethyl 2 4-dimethylthiazole-5-carboxylate Material Safety Data Sheet
Synonym: None Known
CAS: 7210-77-7
Section 1 - Chemical Product MSDS Name:Ethyl 2 4-dimethylthiazole-5-carboxylate Material Safety Data Sheet
Synonym:None Known

Section 2 - COMPOSITION, INFORMATION ON INGREDIENTS
CAS# Chemical Name content EINECS#
7210-77-7 Ethyl 2,4-dimethylthiazole-5-carboxyla ca. 98 unlisted
Hazard Symbols: None Listed.
Risk Phrases: None Listed.

Section 3 - HAZARDS IDENTIFICATION
EMERGENCY OVERVIEW
The toxicological properties of this material have not been fully investigated.
Potential Health Effects
Eye:
May cause eye irritation.
Skin:
May cause skin irritation. May be harmful if absorbed through the skin.
Ingestion:
May cause irritation of the digestive tract. The toxicological properties of this substance have not been fully investigated. May be harmful if swallowed.
Inhalation:
May cause respiratory tract irritation. The toxicological properties of this substance have not been fully investigated. May be harmful if inhaled.
Chronic:
No information found.

Section 4 - FIRST AID MEASURES
Eyes: Flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid.
Skin:
Get medical aid. Flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes.
Ingestion:
If swallowed, do not induce vomiting unless directed to do so by medical personnel. Never give anything by mouth to an unconscious person. Get medical aid.
Inhalation:
If inhaled, remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical aid.
Notes to Physician:
Treat symptomatically and supportively.

Section 5 - FIRE FIGHTING MEASURES
General Information:
As in any fire, wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. During a fire, irritating and highly toxic gases may be generated by thermal decomposition or combustion.
Extinguishing Media:
Use water spray, dry chemical, carbon dioxide, or chemical foam.

Section 6 - ACCIDENTAL RELEASE MEASURES
General Information: Use proper personal protective equipment as indicated in Section 8.
Spills/Leaks:
Vacuum or sweep up material and place into a suitable disposal container. Clean up spills immediately, observing precautions in the Protective Equipment section. Avoid generating dusty conditions.
Provide ventilation.

Section 7 - HANDLING and STORAGE
Handling:
Wash thoroughly after handling. Use with adequate ventilation.
Minimize dust generation and accumulation. Avoid breathing dust, vapor, mist, or gas. Avoid contact with eyes, skin, and clothing.
Keep container tightly closed. Avoid ingestion and inhalation.
Storage:
Store in a cool, dry place. Store in a tightly closed container.

Section 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION
Engineering Controls:
Facilities storing or utilizing this material should be equipped with an eyewash facility and a safety shower. Use adequate ventilation to keep airborne concentrations low.
Exposure Limits CAS# 7210-77-7: Personal Protective Equipment Eyes: Wear chemical splash goggles.
Skin:
Wear appropriate protective gloves to prevent skin exposure.
Clothing:
Wear appropriate protective clothing to prevent skin exposure.
Respirators:
Follow the OSHA respirator regulations found in 29 CFR 1910.134 or European Standard EN 149. Use a NIOSH/MSHA or European Standard EN 149 approved respirator if exposure limits are exceeded or if irritation or other symptoms are experienced.

Section 9 - PHYSICAL AND CHEMICAL PROPERTIES

Physical State: Powder and chunks
Color: off-white to yellow
Odor: Not available.
pH: Not available.
Vapor Pressure: Not available.
Viscosity: Not available.
Boiling Point: Not available.
Freezing/Melting Point: 48 - 50 deg C
Autoignition Temperature: Not available.
Flash Point: Not available.
Explosion Limits, lower: Not available.
Explosion Limits, upper: Not available.
Decomposition Temperature:
Solubility in water:
Specific Gravity/Density:
Molecular Formula: C8H11NO2S
Molecular Weight: 185.25

Section 10 - STABILITY AND REACTIVITY
Chemical Stability:
Stable under normal temperatures and pressures.
Conditions to Avoid:
Dust generation.
Incompatibilities with Other Materials:
Oxidizing agents, reducing agents, acids, bases.
Hazardous Decomposition Products:
Hydrogen cyanide, sulfur dioxide, carbon monoxide, oxides of nitrogen, carbon dioxide, sulfuric acid, nitric acid.
Hazardous Polymerization: Has not been reported

Section 11 - TOXICOLOGICAL INFORMATION
RTECS#:
CAS# 7210-77-7 unlisted.
LD50/LC50:
Not available.
Carcinogenicity:
Ethyl 2,4-dimethylthiazole-5-carboxylate - Not listed by ACGIH, IARC, or NTP.

Section 12 - ECOLOGICAL INFORMATION


Section 13 - DISPOSAL CONSIDERATIONS
Dispose of in a manner consistent with federal, state, and local regulations.

Section 14 - TRANSPORT INFORMATION

IATA
Shipping Name: Not regulated.
Hazard Class:
UN Number:
Packing Group:
IMO
Shipping Name: Not regulated.
Hazard Class:
UN Number:
Packing Group:
RID/ADR
Not regulated as a hazardous material.

Section 15 - REGULATORY INFORMATION

European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: Not available.
Risk Phrases:
Safety Phrases:
S 24/25 Avoid contact with skin and eyes.
WGK (Water Danger/Protection)
CAS# 7210-77-7: No information available.
Canada
None of the chemicals in this product are listed on the DSL/NDSL list.
CAS# 7210-77-7 is not listed on Canada's Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 7210-77-7 is not listed on the TSCA inventory.
It is for research and development use only.


SECTION 16 - ADDITIONAL INFORMATION
N/A

 Safety Information

Risk Phrases R36/37/38
Safety Phrases S24/25
RIDADR NONH for all modes of transport
HS Code 2934100090

 Synthetic Route

~97%

Ethyl 2,4-dimethyl-1,3-thiazole-5-carboxylate Structure

Ethyl 2,4-dimet...

CAS#:7210-77-7

Literature: Yavari, Issa; Sayyed-Alangi, S. Zahra; Hajinasiri, Rahimeh; Sajjadi-Ghotbabadi, Hadi Monatshefte fur Chemie, 2009 , vol. 140, # 2 p. 209 - 211

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Ethyl 2,4-dimethyl-1,3-thiazole-5-carboxylate Structure

Ethyl 2,4-dimet...

CAS#:7210-77-7

Literature: US5817829 A1, ;

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Ethyl 2,4-dimethyl-1,3-thiazole-5-carboxylate Structure

Ethyl 2,4-dimet...

CAS#:7210-77-7

Literature: Proceedings - Indian Academy of Sciences, Section A, , # 22 p. 362,376 Yakugaku Zasshi, , vol. 73, p. 126 Chem.Abstr., , p. 12358

 Customs

HS Code 2934100090
Summary 2934100090 other compounds containing an unfused thiazole ring (whether or not hydrogenated) in the structure VAT:17.0% Tax rebate rate:9.0% Supervision conditions:none MFN tariff:6.5% General tariff:20.0%

 Synonyms

Ethyl 2,4-dimethyl-1,3-thiazole-5-carboxylate
5-Thiazolecarboxylic acid, 2,4-dimethyl-, ethyl ester
MFCD00052874