chloromethyl(4-chlorophenyl)dimethylsilane

Modify Date: 2024-01-02 09:24:16

chloromethyl(4-chlorophenyl)dimethylsilane Structure
chloromethyl(4-chlorophenyl)dimethylsilane structure
Common Name chloromethyl(4-chlorophenyl)dimethylsilane
CAS Number 770-89-8 Molecular Weight 219.18300
Density 1.1g/cm3 Boiling Point 87-89ºC (1 mmHg)
Molecular Formula C9H12Cl2Si Melting Point N/A
MSDS N/A Flash Point 116.1ºC

 Names

Name chloromethyl-(4-chlorophenyl)-dimethylsilane
Synonym More Synonyms

 Chemical & Physical Properties

Density 1.1g/cm3
Boiling Point 87-89ºC (1 mmHg)
Molecular Formula C9H12Cl2Si
Molecular Weight 219.18300
Flash Point 116.1ºC
Exact Mass 218.00900
LogP 3.45170
Index of Refraction 1.536-1.538

 MSDS

Name: Chloromethyl-4-Chlorophenyl Dimethylsilane , 97% (GC) Material Safety Data Sheet
Synonym: Chloromethyl-(4-Chlorophenyl)Dimethylsilane
CAS: 770-89-8
Section 1 - Chemical Product MSDS Name: Chloromethyl-4-Chlorophenyl Dimethylsilane , 97% (GC) Material Safety Data Sheet
Synonym: Chloromethyl-(4-Chlorophenyl)Dimethylsilane
SECTION 2 - COMPOSITION, INFORMATION ON INGREDIENTS
CAS# Chemical Name content EINECS#
770-89-8 Chloromethyl Dimethyl-4-Chlorophenylsi 97 unlisted
+++++
Hazard Symbols: C
SECTION 3 - HAZARDS IDENTIFICATION EMERGENCY OVERVIEW Causes burns.Corrosive. Potential Health Effects
Eye:
Causes eye burns.
Skin:
Causes skin burns.
Ingestion:
May cause severe and permanent damage to the digestive tract. Causes gastrointestinal tract burns. May cause nausea and vomiting.
Inhalation:
Causes chemical burns to the respiratory tract. Inhalation may be fatal as a result of spasm, inflammation, edema of the larynx and bronchi, chemical pneumonitis and pulmonary edema.
Chronic:
No information found.
SECTION 4 - FIRST AID MEASURES
Eyes:
Get medical aid. Do NOT allow victim to rub eyes or keep eyes closed. Extensive irrigation with water is required (at least 30 minutes).
Skin:
Get medical aid. Flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes. Wash clothing before reuse. Destroy contaminated shoes.
Ingestion:
Never give anything by mouth to an unconscious person. Get medical aid. Do NOT induce vomiting. If conscious and alert, rinse mouth and drink 2-4 cupfuls of milk or water.
Inhalation:
Remove from exposure and move to fresh air immediately. Get medical aid. Do NOT use mouth-to-mouth resuscitation. If breathing has ceased apply artificial respiration using oxygen and a suitable mechanical device such as a bag and a mask.
Notes to Physician:


SECTION 5 - FIRE FIGHTING MEASURES
General Information:
As in any fire, wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. During a fire, irritating and highly toxic gases may be generated by thermal decomposition or combustion. Use water spray to keep fire-exposed containers cool. Vapors may be heavier than air. They can spread along the ground and collect in low or confined areas. Containers may explode when heated.
Extinguishing Media:
Use agent most appropriate to extinguish fire. Cool containers with flooding quantities of water until well after fire is out. Use water spray, dry chemical, carbon dioxide, or appropriate foam.
SECTION 6 - ACCIDENTAL RELEASE MEASURES
General Information: Use proper personal protective equipment as indicated in Section 8.
Spills/Leaks:
Absorb spill with inert material (e.g. vermiculite, sand or earth), then place in suitable container. Avoid runoff into storm sewers and ditches which lead to waterways. Clean up spills immediately, observing precautions in the Protective Equipment section. Provide ventilation.
SECTION 7 - HANDLING and STORAGE
Handling:
Wash thoroughly after handling. Use with adequate ventilation. Avoid contact with eyes, skin, and clothing. Keep container tightly closed. Avoid ingestion and inhalation. Do not ingest or inhale. Use only in a chemical fume hood. Discard contaminated shoes.
Storage:
Keep container closed when not in use. Keep under a nitrogen blanket. Store in a cool, dry, well-ventilated area away from incompatible substances. Corrosives area.
SECTION 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION
Engineering Controls:
Facilities storing or utilizing this material should be equipped with an eyewash facility and a safety shower. Use adequate ventilation to keep airborne concentrations low. Exposure Limits CAS# 770-89-8: Personal Protective Equipment
Eyes:
Wear appropriate protective eyeglasses or chemical safety goggles as described by OSHA's eye and face protection regulations in 29 CFR 1910.133 or European Standard EN166.
Skin:
Wear appropriate protective gloves to prevent skin exposure.
Clothing:
Wear appropriate protective clothing to prevent skin exposure.
Respirators:
A respiratory protection program that meets OSHA's 29 CFR 1910.134 and ANSI Z88.2 requirements or European Standard EN 149 must be followed whenever workplace conditions warrant respirator use.
SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES
Physical State: Liquid
Color: clear almost colorless
Odor: Not available.
pH: Not available.
Vapor Pressure: Not available.
Viscosity: Not available.
Boiling Point: 119 - 120 deg C @ 3.00mm Hg
Freezing/Melting Point: Not available.
Autoignition Temperature: Not available.
Flash Point: Not available.
Explosion Limits, lower: Not available.
Explosion Limits, upper: Not available.
Decomposition Temperature:
Solubility in water:
Specific Gravity/Density:
Molecular Formula: C9H12Cl2Si
Molecular Weight: 219.19
SECTION 10 - STABILITY AND REACTIVITY
Chemical Stability:
Stable at room temperature in closed containers under normal storage and handling conditions.
Conditions to Avoid:
Incompatible materials, excess heat, oxidizers.
Incompatibilities with Other Materials:
Oxidizing agents.
Hazardous Decomposition Products:
Hydrogen chloride, carbon monoxide, irritating and toxic fumes and gases, carbon dioxide, silicon dioxide.
Hazardous Polymerization: Has not been reported.
SECTION 11 - TOXICOLOGICAL INFORMATION RTECS#: CAS# 770-89-8 unlisted.
LD50/LC50:
Not available.
Carcinogenicity:
Chloromethyl Dimethyl-4-Chlorophenylsilane - Not listed by ACGIH, IARC, or NTP.
SECTION 12 - ECOLOGICAL INFORMATION
SECTION 13 - DISPOSAL CONSIDERATIONS Dispose of in a manner consistent with federal, state, and local regulations.
SECTION 14 - TRANSPORT INFORMATION IATA
Shipping Name: CORROSIVE LIQUID, N.O.S.
Hazard Class: 8
UN Number: 1760
Packing Group: III IMO
Shipping Name: CORROSIVE LIQUID, N.O.S.
Hazard Class: 8
UN Number: 1760
Packing Group: III RID/ADR
Shipping Name: CORROSIVE LIQUID, N.O.S.
Hazard Class: 8
UN Number: 1760
Packing group: III
SECTION 15 - REGULATORY INFORMATION European/International Regulations European Labeling in Accordance with EC Directives
Hazard Symbols: C
Risk Phrases:
R 34 Causes burns.
Safety Phrases:
S 25 Avoid contact with eyes. S 28A After contact with skin, wash immediately with plenty of water. S 36/37/39 Wear suitable protective clothing, gloves and eye/face protection. S 37 Wear suitable gloves. S 45 In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible). WGK (Water Danger/Protection) CAS# 770-89-8: No information available. Canada None of the chemicals in this product are listed on the DSL/NDSL list. CAS# 770-89-8 is not listed on Canada's Ingredient Disclosure List. US FEDERAL TSCA CAS# 770-89-8 is not listed on the TSCA inventory. It is for research and development use only.
SECTION 16 - ADDITIONAL INFORMATION
MSDS Creation Date: 2/19/1999 Revision #2 Date: 3/18/2003 The information above is believed to be accurate and represents the best information currently available to us. However, we make no warranty of merchantability or any other warranty, express or implied, with respect to such information, and we assume no liability resulting from its use. Users should make their own investigations to determine the suitability of the information for their particular purposes. In no way shall the company be liable for any claims, losses, or damages of any third party or for lost profits or any special, indirect, incidental, consequential or exemplary damages, howsoever arising, even if the company has been advised of the possibility of such damages.

SECTION 16 - ADDITIONAL INFORMATION
N/A

 Safety Information

Hazard Codes Xi
Risk Phrases 36/37/38
Safety Phrases 37/39-26

 Synthetic Route

~53%

chloromethyl(4-chlorophenyl)dimethylsilane Structure

chloromethyl(4-...

CAS#:770-89-8

Literature: E. I. Du Pont de Nemours and Company Patent: US4496551 A1, 1985 ;

~55%

chloromethyl(4-chlorophenyl)dimethylsilane Structure

chloromethyl(4-...

CAS#:770-89-8

Literature: E. I. Du Pont de Nemours and Company Patent: US4510136 A1, 1985 ;

~%

chloromethyl(4-chlorophenyl)dimethylsilane Structure

chloromethyl(4-...

CAS#:770-89-8

Literature: Bulletin of the Academy of Sciences of the USSR, Division of Chemical Science (English Translation), , p. 1858 - 1862 Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, , p. 1951 - 1956

~%

chloromethyl(4-chlorophenyl)dimethylsilane Structure

chloromethyl(4-...

CAS#:770-89-8

Literature: Journal of the Chemical Society, , p. 4266 Huaxue Xuebao, , vol. 25, p. 330,331-340 Chem.Abstr., , # 16375

 Synonyms

chloromethyl dimethyl-4-chlorophenylsilane
MFCD00800543
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