tert-Butyl allylcarbamate

Modify Date: 2024-01-02 17:22:22

tert-Butyl allylcarbamate Structure
tert-Butyl allylcarbamate structure
Common Name tert-Butyl allylcarbamate
CAS Number 78888-18-3 Molecular Weight 157.210
Density 0.9±0.1 g/cm3 Boiling Point 218.2±19.0 °C at 760 mmHg
Molecular Formula C8H15NO2 Melting Point 36-38ºC
MSDS Chinese USA Flash Point 85.7±21.5 °C
Symbol GHS07
GHS07
Signal Word Warning

 Names

Name tert-Butyl allylcarbamate
Synonym More Synonyms

 Chemical & Physical Properties

Density 0.9±0.1 g/cm3
Boiling Point 218.2±19.0 °C at 760 mmHg
Melting Point 36-38ºC
Molecular Formula C8H15NO2
Molecular Weight 157.210
Flash Point 85.7±21.5 °C
Exact Mass 157.110275
PSA 38.33000
LogP 1.94
Appearance of Characters Low Melting Solid | Colorless
Vapour Pressure 0.1±0.4 mmHg at 25°C
Index of Refraction 1.439
Water Solubility Insoluble in water. Soluble in methanol.

 Safety Information

Symbol GHS07
GHS07
Signal Word Warning
Hazard Statements H302
Hazard Codes Xi: Irritant;
Risk Phrases 22-36/37/38
Safety Phrases 22-26-36/37/39
RIDADR UN 1325 4.1/PG 2
WGK Germany 3
HS Code 2924199090

 Synthetic Route

~63%

tert-Butyl allylcarbamate Structure

tert-Butyl ally...

CAS#:78888-18-3

Literature: Betschmann, Patrick; Burchat, Andrew F.; Calderwood, David J.; Curtin, Michael L.; Davidsen, Steven K.; Davis, Heather M.; Frey, Robin R.; Heyman, Howard R.; Hirst, Gavin C.; Hrnciar, Peter; Michaelides, Michael R.; Muckey, Melanie A.; Rafferty, Paul; Wada, Carol K. Patent: US2005/43347 A1, 2005 ; Location in patent: Page/Page column 67-68 ; US 20050043347 A1

~99%

tert-Butyl allylcarbamate Structure

tert-Butyl ally...

CAS#:78888-18-3

Literature: Tayama, Eiji; Sugai, Sayaka Tetrahedron Letters, 2007 , vol. 48, # 35 p. 6163 - 6166

~86%

tert-Butyl allylcarbamate Structure

tert-Butyl ally...

CAS#:78888-18-3

Literature: Takeda Chemical Industries, Ltd. Patent: EP278621 B1, 1991 ;

~80%

tert-Butyl allylcarbamate Structure

tert-Butyl ally...

CAS#:78888-18-3

Literature: Shea, Regan G.; Fitzner, Jeffrey N.; Fankhauser, John E.; Spaltenstein, Andreas; Carpino, Philip A.; et al. Journal of Organic Chemistry, 1986 , vol. 51, # 26 p. 5243 - 5252

~66%

tert-Butyl allylcarbamate Structure

tert-Butyl ally...

CAS#:78888-18-3

Literature: Shea, Regan G.; Fitzner, Jeffrey N.; Fankhauser, John E.; Spaltenstein, Andreas; Carpino, Philip A.; et al. Journal of Organic Chemistry, 1986 , vol. 51, # 26 p. 5243 - 5252

~%

tert-Butyl allylcarbamate Structure

tert-Butyl ally...

CAS#:78888-18-3

Literature: US4558071 A1, ;

~%

tert-Butyl allylcarbamate Structure

tert-Butyl ally...

CAS#:78888-18-3

Literature: Journal of Organic Chemistry, , vol. 79, # 4 p. 1620 - 1625

~%

tert-Butyl allylcarbamate Structure

tert-Butyl ally...

CAS#:78888-18-3

Literature: Journal of Organic Chemistry, , vol. 79, # 4 p. 1620 - 1625

 Customs

HS Code 2924199090
Summary 2924199090. other acyclic amides (including acyclic carbamates) and their derivatives; salts thereof. VAT:17.0%. Tax rebate rate:13.0%. . MFN tariff:6.5%. General tariff:30.0%

 Synonyms

1X1&1&OVM2U1
Allylcarbamic acid tert-butyl ester
Carbamic acid, N-2-propen-1-yl-, 1,1-dimethylethyl ester
tert-Butyl allylcarbamate
tert-Butyl N-allylcarbamate
MFCD00191870
2-Methyl-2-propanyl allylcarbamate