硫酸肼
硫酸肼用途
用作分析试剂及还原剂，也用于稀有金属的提纯
【用途二】
用于医药、有机合成、农药、塑料、橡胶等工业
【用途三】
用作制造药品的原料。有机工业用作偶氮二异丁腈等产品的原料。电镀上用作还原剂。农业上用作杀虫剂、灭菌剂。用作塑料和橡胶的发泡剂等。
【用途四】
重量测定镍、钴和镉，提纯稀有金属，还原剂，有机合成，分离钋与碲，测定氯酸盐、次氯酸和羧基化合物，肝功能试验中制备麝香草酚浊度液。工业上用于制异烟肼、呋喃西林、百生肼、无水肼、杀虫剂和杀菌剂等，用于火箭燃料处理、防锈产品中，制造ADC发泡剂。广泛用于医药, 有机合成, 农药, 塑料, 橡胶等工业;
硫酸肼名称
[ CAS 号 ]:
10034-93-2
[ 中文名 ]:
硫酸肼
[ 英文名 ]:
Hydrazine sulfate
[中文别名 ]:
[英文别名 ]:
- MFCD00044873
- idrazinasolfato
- Hydrazine sulphate
- EINECS 233-110-4
- diamidogensulfate
- HydrazineSulphateGr
- Hydrazine sulfate
- Hydrazine sulfate (1:1)
- Hydrazinium sulfate
- monohydrazine sulfate
硫酸肼物理化学性质
[ 密度 ]:
1,37 g/cm3
[ 沸点 ]:
330ºC at 760mmHg
[ 熔点 ]:
254 °C(lit.)
[ 分子式 ]:
H6N2O4S
[ 分子量 ]:
130.124
[ 精确质量 ]:
130.004822
[ PSA ]:
135.02000
[ LogP ]:
0.64740
[ 外观性状 ]:
白色晶体
[ 蒸汽压 ]:
3.35E-05mmHg at 25°C
[ 储存条件 ]:
室温
[ 稳定性 ]:
Stable. Incompatible with nitrites, strong oxidizing agents.
[ 水溶解性 ]:
30 g/L (20 ºC)
硫酸肼MSDS
硫酸肼毒性和生态
CHEMICAL IDENTIFICATION
- RTECS NUMBER :
- MV9625000
- CAS REGISTRY NUMBER :
- 10034-93-2
- LAST UPDATED :
- 199710
- DATA ITEMS CITED :
- 63
- MOLECULAR FORMULA :
- H4-N2.H2-O4-S
- MOLECULAR WEIGHT :
- 130.14
- WISWESSER LINE NOTATION :
- ZZ &S-O4
HEALTH HAZARD DATA
ACUTE TOXICITY DATA
- TYPE OF TEST :
- Standard Draize test
- ROUTE OF EXPOSURE :
- Administration into the eye
- SPECIES OBSERVED :
- Rodent - rabbit
- TYPE OF TEST :
- TDLo - Lowest published toxic dose
- ROUTE OF EXPOSURE :
- Oral
- SPECIES OBSERVED :
- Human
- DOSE/DURATION :
- 201 mg/kg/8D
- TOXIC EFFECTS :
- Peripheral Nerve and Sensation - paresthesis Behavioral - somnolence (general depressed activity) Gastrointestinal - nausea or vomiting
- TYPE OF TEST :
- LD50 - Lethal dose, 50 percent kill
- ROUTE OF EXPOSURE :
- Oral
- SPECIES OBSERVED :
- Rodent - rat
- DOSE/DURATION :
- 601 mg/kg
- TOXIC EFFECTS :
- Details of toxic effects not reported other than lethal dose value
- TYPE OF TEST :
- LD50 - Lethal dose, 50 percent kill
- ROUTE OF EXPOSURE :
- Intraperitoneal
- SPECIES OBSERVED :
- Rodent - rat
- DOSE/DURATION :
- 230 mg/kg
- TOXIC EFFECTS :
- Details of toxic effects not reported other than lethal dose value
- TYPE OF TEST :
- LD50 - Lethal dose, 50 percent kill
- ROUTE OF EXPOSURE :
- Oral
- SPECIES OBSERVED :
- Rodent - mouse
- DOSE/DURATION :
- 434 mg/kg
- TOXIC EFFECTS :
- Details of toxic effects not reported other than lethal dose value
- TYPE OF TEST :
- LD50 - Lethal dose, 50 percent kill
- ROUTE OF EXPOSURE :
- Intraperitoneal
- SPECIES OBSERVED :
- Rodent - mouse
- DOSE/DURATION :
- 152 mg/kg
- TOXIC EFFECTS :
- Liver - hepatitis (hepatocellular necrosis), diffuse Kidney, Ureter, Bladder - changes in tubules (including acute renal failure, acute tubular necrosis)
- TYPE OF TEST :
- LD50 - Lethal dose, 50 percent kill
- ROUTE OF EXPOSURE :
- Subcutaneous
- SPECIES OBSERVED :
- Rodent - mouse
- DOSE/DURATION :
- 455 mg/kg
- TOXIC EFFECTS :
- Details of toxic effects not reported other than lethal dose value
- TYPE OF TEST :
- LDLo - Lowest published lethal dose
- ROUTE OF EXPOSURE :
- Oral
- SPECIES OBSERVED :
- Mammal - dog
- DOSE/DURATION :
- 100 mg/kg
- TOXIC EFFECTS :
- Details of toxic effects not reported other than lethal dose value
- TYPE OF TEST :
- LDLo - Lowest published lethal dose
- ROUTE OF EXPOSURE :
- Oral
- SPECIES OBSERVED :
- Rodent - rabbit
- DOSE/DURATION :
- 100 mg/kg
- TOXIC EFFECTS :
- Details of toxic effects not reported other than lethal dose value
- TYPE OF TEST :
- LC - Lethal concentration
- ROUTE OF EXPOSURE :
- Inhalation
- SPECIES OBSERVED :
- Mammal - species unspecified
- DOSE/DURATION :
- >6400 ug/m3
- TOXIC EFFECTS :
- Details of toxic effects not reported other than lethal dose value
- TYPE OF TEST :
- TDLo - Lowest published toxic dose
- ROUTE OF EXPOSURE :
- Oral
- SPECIES OBSERVED :
- Rodent - rat
- DOSE/DURATION :
- 1500 mg/kg/15D-I
- TOXIC EFFECTS :
- Nutritional and Gross Metabolic - weight loss or decreased weight gain
- TYPE OF TEST :
- TDLo - Lowest published toxic dose
- ROUTE OF EXPOSURE :
- Intraperitoneal
- SPECIES OBSERVED :
- Rodent - rat
- DOSE/DURATION :
- 1200 mg/kg/30D-I
- TOXIC EFFECTS :
- Endocrine - changes in thymus weight Nutritional and Gross Metabolic - weight loss or decreased weight gain Related to Chronic Data - changes in ovarian weight
- TYPE OF TEST :
- TDLo - Lowest published toxic dose
- ROUTE OF EXPOSURE :
- Oral
- SPECIES OBSERVED :
- Rodent - mouse
- DOSE/DURATION :
- 1500 mg/kg/15D-I
- TOXIC EFFECTS :
- Nutritional and Gross Metabolic - weight loss or decreased weight gain
- TYPE OF TEST :
- TDLo - Lowest published toxic dose
- ROUTE OF EXPOSURE :
- Oral
- SPECIES OBSERVED :
- Rodent - rat
- DOSE/DURATION :
- 43 gm/kg/85W-C
- TOXIC EFFECTS :
- Tumorigenic - Carcinogenic by RTECS criteria Lungs, Thorax, or Respiration - tumors Liver - tumors
- TYPE OF TEST :
- TDLo - Lowest published toxic dose
- ROUTE OF EXPOSURE :
- Oral
- SPECIES OBSERVED :
- Rodent - mouse
- DOSE/DURATION :
- 1892 mg/kg multigenerations
- TOXIC EFFECTS :
- Tumorigenic - Carcinogenic by RTECS criteria Reproductive - Tumorigenic effects - transplacental tumorigenesis Lungs, Thorax, or Respiration - tumors
- TYPE OF TEST :
- TDLo - Lowest published toxic dose
- ROUTE OF EXPOSURE :
- Oral
- SPECIES OBSERVED :
- Rodent - mouse
- DOSE/DURATION :
- 19 gm/kg/61W-C
- TOXIC EFFECTS :
- Tumorigenic - Carcinogenic by RTECS criteria Lungs, Thorax, or Respiration - tumors Liver - tumors
- TYPE OF TEST :
- TDLo - Lowest published toxic dose
- ROUTE OF EXPOSURE :
- Intraperitoneal
- SPECIES OBSERVED :
- Rodent - mouse
- DOSE/DURATION :
- 832 mg/kg/8W-I
- TOXIC EFFECTS :
- Tumorigenic - equivocal tumorigenic agent by RTECS criteria Lungs, Thorax, or Respiration - tumors
- TYPE OF TEST :
- TDLo - Lowest published toxic dose
- ROUTE OF EXPOSURE :
- Oral
- SPECIES OBSERVED :
- Rodent - hamster
- DOSE/DURATION :
- 29702 mg/kg/2Y-C
- TOXIC EFFECTS :
- Tumorigenic - Carcinogenic by RTECS criteria Liver - tumors
- TYPE OF TEST :
- TD - Toxic dose (other than lowest)
- ROUTE OF EXPOSURE :
- Oral
- SPECIES OBSERVED :
- Rodent - rat
- DOSE/DURATION :
- 38 gm/kg/68W-I
- TOXIC EFFECTS :
- Tumorigenic - neoplastic by RTECS criteria Lungs, Thorax, or Respiration - tumors Liver - tumors
- TYPE OF TEST :
- TD - Toxic dose (other than lowest)
- ROUTE OF EXPOSURE :
- Oral
- SPECIES OBSERVED :
- Rodent - mouse
- DOSE/DURATION :
- 1664 mg/kg/8W-I
- TOXIC EFFECTS :
- Tumorigenic - neoplastic by RTECS criteria Lungs, Thorax, or Respiration - tumors
- TYPE OF TEST :
- TD - Toxic dose (other than lowest)
- ROUTE OF EXPOSURE :
- Oral
- SPECIES OBSERVED :
- Rodent - mouse
- DOSE/DURATION :
- 1280 mg/kg/4w-I
- TOXIC EFFECTS :
- Tumorigenic - neoplastic by RTECS criteria Lungs, Thorax, or Respiration - tumors Liver - tumors
- TYPE OF TEST :
- TD - Toxic dose (other than lowest)
- ROUTE OF EXPOSURE :
- Oral
- SPECIES OBSERVED :
- Rodent - mouse
- DOSE/DURATION :
- 11 gm/kg/46W-I
- TOXIC EFFECTS :
- Tumorigenic - equivocal tumorigenic agent by RTECS criteria Lungs, Thorax, or Respiration - tumors
- TYPE OF TEST :
- TD - Toxic dose (other than lowest)
- ROUTE OF EXPOSURE :
- Intraperitoneal
- SPECIES OBSERVED :
- Rodent - mouse
- DOSE/DURATION :
- 950 mg/kg/10W-I
- TOXIC EFFECTS :
- Tumorigenic - equivocal tumorigenic agent by RTECS criteria Lungs, Thorax, or Respiration - tumors
- TYPE OF TEST :
- TD - Toxic dose (other than lowest)
- ROUTE OF EXPOSURE :
- Intraperitoneal
- SPECIES OBSERVED :
- Rodent - mouse
- DOSE/DURATION :
- 475 mg/kg/5W-I
- TOXIC EFFECTS :
- Tumorigenic - equivocal tumorigenic agent by RTECS criteria Lungs, Thorax, or Respiration - tumors
- TYPE OF TEST :
- TD - Toxic dose (other than lowest)
- ROUTE OF EXPOSURE :
- Oral
- SPECIES OBSERVED :
- Rodent - mouse
- DOSE/DURATION :
- 14080 mg/kg/64W-I
- TOXIC EFFECTS :
- Tumorigenic - equivocal tumorigenic agent by RTECS criteria Lungs, Thorax, or Respiration - tumors Liver - tumors
- TYPE OF TEST :
- TD - Toxic dose (other than lowest)
- ROUTE OF EXPOSURE :
- Oral
- SPECIES OBSERVED :
- Rodent - mouse
- DOSE/DURATION :
- 18524 mg/kg/84W-I
- TOXIC EFFECTS :
- Tumorigenic - Carcinogenic by RTECS criteria Lungs, Thorax, or Respiration - tumors
- TYPE OF TEST :
- TD - Toxic dose (other than lowest)
- ROUTE OF EXPOSURE :
- Oral
- SPECIES OBSERVED :
- Rodent - mouse
- DOSE/DURATION :
- 18480 mg/kg/84W-I
- TOXIC EFFECTS :
- Tumorigenic - neoplastic by RTECS criteria Lungs, Thorax, or Respiration - tumors
- TYPE OF TEST :
- TD - Toxic dose (other than lowest)
- ROUTE OF EXPOSURE :
- Oral
- SPECIES OBSERVED :
- Rodent - mouse
- DOSE/DURATION :
- 226 mg/kg
- TOXIC EFFECTS :
- Tumorigenic - neoplastic by RTECS criteria Lungs, Thorax, or Respiration - tumors
- TYPE OF TEST :
- DNA inhibition
- TYPE OF TEST :
- DNA adduct
MUTATION DATA
- TYPE OF TEST :
- Sister chromatid exchange
- TEST SYSTEM :
- Rodent - hamster Lung
- REFERENCE :
- MUREAV Mutation Research. (Elsevier Science Pub. B.V., POB 211, 1000 AE Amsterdam, Netherlands) V.1- 1964- Volume(issue)/page/year: 118,103,1983 *** REVIEWS *** IARC Cancer Review:Animal Sufficient Evidence IMEMDT IARC Monographs on the Evaluation of Carcinogenic Risk of Chemicals to Man. (WHO Publications Centre USA, 49 Sheridan Ave., Albany, NY 12210) V.1- 1972- Volume(issue)/page/year: 4,127,1974 *** NIOSH STANDARDS DEVELOPMENT AND SURVEILLANCE DATA *** NIOSH RECOMMENDED EXPOSURE LEVEL (REL) : NIOSH REL TO HYDRAZINES-air:CA CL 0.03 ppm/120M REFERENCE : NIOSH* National Institute for Occupational Safety and Health, U.S. Dept. of Health, Education, and Welfare, Reports and Memoranda. Volume(issue)/page/year: DHHS #92-100,1992 NIOSH OCCUPATIONAL EXPOSURE SURVEY DATA : NOES - National Occupational Exposure Survey (1983) NOES Hazard Code - X4065 No. of Facilities: 223 (estimated) No. of Industries: 4 No. of Occupations: 5 No. of Employees: 945 (estimated) No. of Female Employees: 259 (estimated)
硫酸肼安全信息
[ 符号 ]:
GHS05, GHS06, GHS08, GHS09
[ 信号词 ]:
Danger
[ 危害声明 ]:
H301 + H311 + H331-H314-H317-H350-H410
[ 警示性声明 ]:
P201-P261-P273-P280-P301 + P310-P305 + P351 + P338
[ 个人防护装备 ]:
Eyeshields;Faceshields;full-face particle respirator type N100 (US);Gloves;respirator cartridge type N100 (US);type P1 (EN143) respirator filter;type P3 (EN 143) respirator cartridges
[ 危害码 (欧洲) ]:
T:Toxic;N:Dangerousfortheenvironment;
[ 风险声明 (欧洲) ]:
R23/24/25;R43;R45;R50/53
[ 安全声明 (欧洲) ]:
S53-S45-S60-S61
[ 危险品运输编码 ]:
UN 2923 8/PG 3
[ WGK德国 ]:
3
[ RTECS号 ]:
MV9625000
[ 包装等级 ]:
II
[ 危险类别 ]:
8
[ 海关编码 ]:
2825109000
硫酸肼合成路线
硫酸肼上下游产品
硫酸肼上游产品
硫酸肼下游产品
硫酸肼制备
1.尿素法将尿素、次氯酸钠、液碱，在高锰酸钾存在下进行反应，经蒸馏，再同硫酸进行中和反应，生成物经冷却结晶、过滤、干燥制得硫酸肼成品.
2.在动物胶存在下，用次氯酸钠使氨发生部分氧化，并以硫酸中和即可生成硫酸肼。在1L的锥形瓶中加入200mL 20%的氨水和5mL 1%的动物胶(明胶)溶液，将浓度为1mol/L的次氯酸钠溶液加入后，迅速加热至沸并煮沸约半小时，使多余的NH3完全挥发除去。将溶液蒸发至原体积的一半左右后，迅速冷却至微热，用硫酸中和此溶液，用pH试纸进行检验，使pH值为7～8。放置一段时间，等动物胶成为灰色的絮状物沉淀下来。将沉淀物过滤除去，用硫酸对滤液进行强烈地酸化。放置过夜，硫酸肼结晶析出。将结晶抽滤出来，必要时可用沸水进行重结晶提纯。
硫酸肼海关
[ 海关编码 ]: 2825109000
硫酸肼文献
ACS Nano 9 , 7583-95, (2015)
An integrated microfluidic/magnetophoretic methodology was developed for improving signal response time and detection limits for the chronoamperometric observation of discrete nanoparticle/electrode i...
Electrocatalytic oxidation of hydrazine and hydroxylamine by graphene oxide-Pd nanoparticle-modified glassy carbon electrode.J. Nanosci. Nanotechnol. 12(12) , 8886-92, (2012)
Pd nanoparticle catalysts supported by thiolated graphene oxide (tGO) on a glassy carbon electrode (GCE), and denoted as tGO-Pd/GCE, are used in this study for the electrochemical determination of hyd...
Discrete Fourier Transform as applicable technique in electrochemical detection of hydrazine using multi-walled carbon nanotube/polyacrylonitrile ceramic fiber as working electrode.Mater. Sci. Eng. C. Mater. Biol. Appl. 33(4) , 1969-74, (2013)
Effect of "Discrete Fourier Transform" (DFT) is studied for electrochemical detection of some electroactive species using multi-walled carbon nanotube/polyacrylonitrile ceramic fiber as ultra micro el...
相关化工产品/化学物质：
推荐生产厂家/供应商：
公司名：南通润丰石油化工有限公司
区域：南通市崇川区
价格：
￥需询单/1kg
￥需询单/1ton
联系人：曹经理
产品详情：硫酸肼
公司名：上海吉至生化科技有限公司
区域：上海市奉贤区
价格：
￥128.0/500g
联系人：刘佳
产品详情：硫酸肼
公司名：上海阿拉丁生化科技股份有限公司
区域：上海市浦东新区
价格：
￥149.9/1kg
￥319.9/3kg
￥78.9/500g
￥33.9/100g
联系人：阿拉丁李高志
产品详情：硫酸联氨
公司名：上海创赛科技有限公司
区域：上海市嘉定区
价格：
￥34.0/100g
￥84.0/500g
￥323.0/2500g
￥59.0/500g
联系人：夏言
产品详情：[Perfemiker]硫酸联氨,AR，99.0%
公司名：中山市迪欣化工有限公司
区域：中山市三角镇
价格：
￥60.0/25kg
联系人：王洁
产品详情：硫酸肼
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相关化合物
【硫酸肼】化源网提供硫酸肼CAS号10034-93-2，硫酸肼MSDS及其说明、性质、英文名、生产厂家、作用/用途、分子量、密度、沸点、熔点、结构式等。CAS号查询硫酸肼上化源网，专业又轻松。>>电脑版：硫酸肼
标题：硫酸肼_MSDS_用途_密度_硫酸肼CAS号【10034-93-2】_化源网 地址：https://m.chemsrc.com/mip/cas/10034-93-2_826339.html