对溴苯甲醚

【用途一】
香料和染料的原料；有机合成及医药中间体。
【用途二】
用作溶剂，也用于有机合成
【用途三】
妇科药泰舒的中间体。

[ 密度 ]:
1.4±0.1 g/cm3

[ 沸点 ]:
223.0±0.0 °C at 760 mmHg

[ 熔点 ]:
9-10 °C(lit.)

[ 分子式 ]:
C₇H₇BrO

[ 分子量 ]:
187.034

[ 闪点 ]:
94.4±0.0 °C

[ 精确质量 ]:
185.968018

[ PSA ]:
9.23000

[ LogP ]:
3.16

[ 外观性状 ]:
透明至略黄色液体

[ 蒸汽压 ]:
0.1±0.4 mmHg at 25°C

[ 折射率 ]:
1.539

[ 储存条件 ]:
库房通风低温干燥,与氧化剂、酸类、食品添加剂分开存放

[ 稳定性 ]:
Stable. Combustible. Incompatible with strong oxidizing agents.

[ 水溶解性 ]:
immiscible

详细MSDS(安全技术说明书)

CHEMICAL IDENTIFICATION

RTECS NUMBER :

BZ8501000

CHEMICAL NAME :

Anisole, p-bromo-

CAS REGISTRY NUMBER :

104-92-7

LAST UPDATED :

199701

DATA ITEMS CITED :

4

MOLECULAR FORMULA :

C7-H7-Br-O

MOLECULAR WEIGHT :

187.05

WISWESSER LINE NOTATION :

ER DO1

HEALTH HAZARD DATA

ACUTE TOXICITY DATA

TYPE OF TEST :

LD50 - Lethal dose, 50 percent kill

ROUTE OF EXPOSURE :

Oral

SPECIES OBSERVED :

Rodent - mouse

DOSE/DURATION :

2200 mg/kg

TOXIC EFFECTS :

Details of toxic effects not reported other than lethal dose value

REFERENCE :

GISAAA Gigiena i Sanitariya. For English translation, see HYSAAV. (V/O Mezhdunarodnaya Kniga, 113095 Moscow, USSR) V.1- 1936- Volume(issue)/page/year: 44(12),19,1979

TYPE OF TEST :

LD50 - Lethal dose, 50 percent kill

ROUTE OF EXPOSURE :

Intraperitoneal

SPECIES OBSERVED :

Rodent - mouse

DOSE/DURATION :

1186 mg/kg

TOXIC EFFECTS :

Details of toxic effects not reported other than lethal dose value

REFERENCE :

GISAAA Gigiena i Sanitariya. For English translation, see HYSAAV. (V/O Mezhdunarodnaya Kniga, 113095 Moscow, USSR) V.1- 1936- Volume(issue)/page/year: 44(12),19,1979 *** NIOSH STANDARDS DEVELOPMENT AND SURVEILLANCE DATA *** NIOSH OCCUPATIONAL EXPOSURE SURVEY DATA : NOHS - National Occupational Hazard Survey (1974) NOHS Hazard Code - 81912 No. of Facilities: 14 (estimated) No. of Industries: 1 No. of Occupations: 1 No. of Employees: 392 (estimated)

[ 个人防护装备 ]:
Eyeshields;Gloves;half-mask respirator (US);multi-purpose combination respirator cartridge (US)

[ 危害码 (欧洲) ]:
Xn

[ 安全声明 (欧洲) ]:
S23-S24/25

[ 危险品运输编码 ]:
NONH for all modes of transport

[ WGK德国 ]:
2

[ RTECS号 ]:
BZ8501000

[ 危险类别 ]:
6.1

[ 海关编码 ]:
29093038

详细合成路线

对溴苯甲醚上游产品

对溴苯甲醚下游产品

1.由对溴苯酚与硫酸二甲酯反应而得。将对溴苯酚溶解于稀氢氧化钠溶液，冷却至10℃以下，然后在搅拌下慢慢加入硫酸二甲酯。反应温度可升至30℃，加热至40-50℃搅拌反应2h，分出油层，水洗至中性，用无水氯化钙干燥，蒸馏得成品。

2.以苯甲醚为原料，在冰醋酸中与溴素进行溴化反应，最后经洗涤；减压蒸馏而得。

[ 海关编码 ]: 2909309090

[ 中文概述 ]:
2909309090 其他芳香醚及其卤化衍生物、磺化、硝化衍生物（包括亚硝化衍生物）。监管条件:无。增值税率:17.0%。退税率:9.0%。最惠国关税:5.5%。普通关税:30.0%

[ 申报要素 ]: 品名, 成分含量, 用途

[ Summary ]:
2909309090 other aromatic ethers and their halogenated, sulphonated, nitrated or nitrosated derivatives VAT:17.0% Tax rebate rate:9.0% Supervision conditions:none MFN tariff:5.5% General tariff:30.0%

Contributions of BrCl, Br2, BrOCl, Br2O, and HOBr to regiospecific bromination rates of anisole and bromoanisoles in aqueous solution.

Environ. Sci. Technol. 49(8) , 4937-45, (2015)

When bromide-containing waters are chlorinated, conventional wisdom typically assumes HOBr is the only active brominating agent. Several additional and often-overlooked brominating agents (including B...

Hypobromous acid, a powerful endogenous electrophile: Experimental and theoretical studies.

J. Inorg. Biochem. 146 , 61-8, (2015)

Hypobromous acid (HOBr) is an inorganic acid produced by the oxidation of the bromide anion (Br(-)). The blood plasma level of Br(-) is more than 1,000-fold lower than that of chloride anion (Cl(-)). ...

Pd-catalyzed carbonylative α-arylation of aryl bromides: scope and mechanistic studies.

Chemistry 19(52) , 17926-38, (2013)

Reaction conditions for the three-component synthesis of aryl 1,3-diketones are reported applying the palladium-catalyzed carbonylative α-arylation of ketones with aryl bromides. The optimal condition...

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公司名：上海化源生化科技有限公司

区域：上海市普陀区

价格：

联系人：徐经理

产品详情：对溴苯甲醚

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公司名：上海吉至生化科技有限公司

区域：上海市奉贤区

价格：
￥398.0/500g ￥108.0/100g

联系人：刘佳

产品详情：对溴苯甲醚

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公司名：上海阿拉丁生化科技股份有限公司

区域：上海市浦东新区

价格：
￥279.0/500g ￥39.0/25g ￥需询单/1g ￥84.0/100g

联系人：阿拉丁

产品详情：对溴苯甲醚

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公司名：中山市迪欣化工有限公司

区域：中山市三角镇

价格：
￥580.0/25kg

联系人：董生

产品详情：对溴苯甲醚

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