2-溴丙烷

2-溴丙烷用途

【用途一】
用于有机合成、医药、农药中间体
【用途二】
用于有机合成及制药工业
【用途三】
用于有机合成及医药、农药中间体
【用途四】
2-溴丙烷是杀虫剂氰戊菊酯、氟氰戊菊酯、残杀威，杀菌剂灭锈胺、氟酰胺及除草剂毒草胺、莎稗磷的中间体。
【用途五】
用作Grignard试剂和原料，药物和染料的中间体，还用于农药（敌草胺）等的制造。

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2-溴丙烷名称

[ CAS 号 ]:
75-26-3

[ 中文名 ]:
2-溴丙烷

[ 英文名 ]:
2-Bromopropane

[中文别名 ]:

[英文别名 ]:

i-propyl bromide
2-Brompropan
iso-C3H7Br
2-bromo-propane
2-bromo-propan
sec-Propyl bromide
2-propyl bromide
PropylBromide~
isopropyl-bromide
MFCD00000147

2-溴丙烷物理化学性质

[ 密度 ]:
1.3±0.1 g/cm3

[ 沸点 ]:
60.6±8.0 °C at 760 mmHg

[ 熔点 ]:
-89 °C

[ 分子式 ]:
C₃H₇Br

[ 分子量 ]:
122.992

[ 闪点 ]:
19.4±0.0 °C

[ 精确质量 ]:
121.973106

[ LogP ]:
2.03

[ 外观性状 ]:
无色透明液体

[ 蒸汽压 ]:
205.0±0.1 mmHg at 25°C

[ 折射率 ]:
1.429

[ 储存条件 ]:
库房通风低温干燥,与氧化剂分开存放

[ 稳定性 ]:
Stable. Flammable. Incompatible with strong oxidizing agents.

[ 水溶解性 ]:
0.3 g/100 mL

2-溴丙烷MSDS

2-溴丙烷毒性和生态

CHEMICAL IDENTIFICATION

RTECS NUMBER :: TX4111000

CHEMICAL NAME :: Propane, 2-bromo-

CAS REGISTRY NUMBER :: 75-26-3

LAST UPDATED :: 199712

DATA ITEMS CITED :: 8

MOLECULAR FORMULA :: C3-H7-Br

MOLECULAR WEIGHT :: 123.01

WISWESSER LINE NOTATION :: EY1&1

HEALTH HAZARD DATA

ACUTE TOXICITY DATA

TYPE OF TEST :: LD50 - Lethal dose, 50 percent kill

ROUTE OF EXPOSURE :: Intraperitoneal

SPECIES OBSERVED :: Rodent - mouse

DOSE/DURATION :: 4837 mg/kg

TOXIC EFFECTS :: Details of toxic effects not reported other than lethal dose value

REFERENCE :: GTPZAB Gigiena Truda i Professional'nye Zabolevaniya. Labor Hygiene and Occupational Diseases. (V/O Mezhdunarodnaya Kniga, 113095 Moscow, USSR) V.1-36, 1957-1992. For publisher information, see MTPEEI Volume(issue)/page/year: 20(12),52,1976

TYPE OF TEST :: LC50 - Lethal concentration, 50 percent kill

ROUTE OF EXPOSURE :: Inhalation

SPECIES OBSERVED :: Mammal - species unspecified

DOSE/DURATION :: 36 gm/m3

TOXIC EFFECTS :: Details of toxic effects not reported other than lethal dose value

REFERENCE :: GTPZAB Gigiena Truda i Professional'nye Zabolevaniya. Labor Hygiene and Occupational Diseases. (V/O Mezhdunarodnaya Kniga, 113095 Moscow, USSR) V.1-36, 1957-1992. For publisher information, see MTPEEI Volume(issue)/page/year: 18(4),55,1974 ** OTHER MULTIPLE DOSE TOXICITY DATA **

TYPE OF TEST :: TCLo - Lowest published toxic concentration

ROUTE OF EXPOSURE :: Inhalation

SPECIES OBSERVED :: Rodent - rat

DOSE/DURATION :: 172 gm/m3/30M/1W-I

TOXIC EFFECTS :: Lungs, Thorax, or Respiration - other changes Blood - hemorrhage

REFERENCE :: JPETAB Journal of Pharmacology and Experimental Therapeutics. (Williams & Wilkins Co., 428 E. Preston St., Baltimore, MD 21202) V.1- 1909/10- Volume(issue)/page/year: 80,139,1944 ** REPRODUCTIVE DATA **

TYPE OF TEST :: TDLo - Lowest published toxic dose

ROUTE OF EXPOSURE :: Intraperitoneal

DOSE :: 18900 mg/kg

SEX/DURATION :: female 14 day(s) pre-mating female 7 day(s) after conception

TOXIC EFFECTS :: Reproductive - Maternal Effects - ovaries, fallopian tubes Reproductive - Maternal Effects - menstrual cycle changes or disorders

REFERENCE :: INHEAO Industrial Health. (National Institute of Industrial Health, 6-21-1 Nagao, Tama-ku, Kawasaki, 213 Japan) V.1- 1963- Volume(issue)/page/year: 35,278,1997 *** NIOSH STANDARDS DEVELOPMENT AND SURVEILLANCE DATA *** NIOSH OCCUPATIONAL EXPOSURE SURVEY DATA : NOES - National Occupational Exposure Survey (1983) NOES Hazard Code - X4017 No. of Facilities: 17 (estimated) No. of Industries: 1 No. of Occupations: 1 No. of Employees: 1582 (estimated) No. of Female Employees: 323 (estimated)

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2-溴丙烷安全信息

[ 符号 ]:

GHS02, GHS08

[ 信号词 ]:
Danger

[ 危害声明 ]:
H225-H360F-H373

[ 补充危害声明 ]:
Repeated exposure may cause skin dryness or cracking.

[ 警示性声明 ]:
P201-P210-P308 + P313

[ 个人防护装备 ]:
Eyeshields;Faceshields;full-face respirator (US);Gloves;multi-purpose combination respirator cartridge (US)

[ 危害码 (欧洲) ]:
F:Flammable

[ 风险声明 (欧洲) ]:
R11;R48/20;R60;R66

[ 安全声明 (欧洲) ]:
S53-S16-S45

[ 危险品运输编码 ]:
UN 2344 3/PG 2

[ WGK德国 ]:
1

[ RTECS号 ]:
TX4111000

[ 包装等级 ]:
II

[ 危险类别 ]:
3

[ 海关编码 ]:
2930909090

2-溴丙烷合成路线

2-溴丙烷上下游产品

2-溴丙烷上游产品

2-溴丙烷下游产品

2-溴丙烷制备

1.由异丙醇与氢溴酸反应而得。将异丙醇在冷却下慢慢加入浓硫酸中，控制温度在30℃以下，加完后再加入氢溴酸，慢慢加热回流4h，然后蒸馏至出现油珠为止，将所得的粗品，分别以浓硫酸、水和5%碳酸钠洗涤，再用无水碳酸钠干燥、过滤、分馏，收集58.5-60.5℃馏分即为成品。另外还有异丙醇-溴化钠法。

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2-溴丙烷海关

[ 海关编码 ]: 2930909090

[ 中文概述 ]:
2930909090. 其他有机硫化合物. 增值税率:17.0%. 退税率:13.0%. 监管条件:无. 最惠国关税:6.5%. 普通关税:30.0%

[ 申报要素 ]: 品名, 成分含量, 用途

[ Summary ]:
2930909090. other organo-sulphur compounds. VAT:17.0%. Tax rebate rate:13.0%. . MFN tariff:6.5%. General tariff:30.0%

2-溴丙烷文献

Halogenated derivatives QSAR model using spectral moments to predict haloacetic acids (HAA) mutagenicity.

Bioorg. Med. Chem. 16 , 5720-32, (2008)

The risk of the presence of haloacetic acids in drinking water as chlorination by-products and the shortage of experimental mutagenicity data for most of them requires a research work. This paper desc...

Reproductive toxicology: current and future directions.

Biochem. Pharmacol. 62(12) , 1557-64, (2001)

During the 20th century, there has been an increased risk from environmental by-products that may be harmful to reproductive function in humans. Therefore, as the 21st century begins, it is appropriat...

Occupational reproductive function abnormalities and bladder cancer in Korea.

J. Korean Med. Sci. 25(Suppl) , S41-5, (2010)

The purpose of this study was to review occupational reproductive abnormalities and occupational bladder cancer in Korea and to discuss their toxicological implications. Reproductive dysfunction as a ...

更多文献

2-溴丙烷

2-溴丙烷用途

2-溴丙烷名称

2-溴丙烷物理化学性质

2-溴丙烷MSDS

详细MSDS(安全技术说明书)

2-溴丙烷毒性和生态

CHEMICAL IDENTIFICATION

HEALTH HAZARD DATA

ACUTE TOXICITY DATA

2-溴丙烷安全信息

2-溴丙烷合成路线

详细合成路线

2-溴丙烷上下游产品

2-溴丙烷上游产品

2-溴丙烷下游产品

2-溴丙烷制备

2-溴丙烷海关

2-溴丙烷文献

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