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对溴苯胺

对溴苯胺用途

【用途一】
用于偶氮染料制造及有机合成
【用途二】
有机合成中间体。
【用途三】
4-溴苯胺（106-40-1）用于制造染料原料，如偶氮染料、喹啉染料等，医药及有机合成中间体。
【用途四】
有机合成，制备二氢喹唑啉。
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对溴苯胺名称

[ CAS 号 ]:
106-40-1

[ 中文名 ]:
4-溴苯胺

[ 英文名 ]:
4-Bromoaniline

[中文别名 ]:

[英文别名 ]:

对溴苯胺物理化学性质

[ 密度 ]:
1.6±0.1 g/cm3

[ 沸点 ]:
225.9±13.0 °C at 760 mmHg

[ 熔点 ]:
56-62 °C(lit.)

[ 分子式 ]:
C6H6BrN

[ 分子量 ]:
172.023

[ 闪点 ]:
90.4±19.8 °C

[ 精确质量 ]:
170.968353

[ PSA ]:
26.02000

[ LogP ]:
2.05

[ 外观性状 ]:
结晶

[ 蒸汽压 ]:
0.1±0.4 mmHg at 25°C

[ 折射率 ]:
1.626

[ 储存条件 ]:
库房通风低温干燥,与氧化剂、酸类、食品添加剂分开存放

[ 稳定性 ]:
Stable. Combustible. Incompatible with strong oxidizing agents, peroxides, acids, acid chlorides, acid anhydrides, chloroformates. May be air sensitive.

[ 水溶解性 ]:
<0.1 g/100 mL at 23 ºC

对溴苯胺MSDS

详细MSDS(安全技术说明书)

对溴苯胺毒性和生态

CHEMICAL IDENTIFICATION

RTECS NUMBER :
BW9280000
CHEMICAL NAME :
Aniline, p-bromo-
CAS REGISTRY NUMBER :
106-40-1
BEILSTEIN REFERENCE NO. :
0742031
LAST UPDATED :
199710
DATA ITEMS CITED :
11
MOLECULAR FORMULA :
C6-H6-Br-N
MOLECULAR WEIGHT :
172.04
WISWESSER LINE NOTATION :
ZR DE

HEALTH HAZARD DATA

ACUTE TOXICITY DATA

TYPE OF TEST :
LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE :
Oral
SPECIES OBSERVED :
Rodent - rat
DOSE/DURATION :
456 mg/kg
TOXIC EFFECTS :
Details of toxic effects not reported other than lethal dose value
TYPE OF TEST :
LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE :
Oral
SPECIES OBSERVED :
Rodent - mouse
DOSE/DURATION :
289 mg/kg
TOXIC EFFECTS :
Details of toxic effects not reported other than lethal dose value
TYPE OF TEST :
LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE :
Intraperitoneal
SPECIES OBSERVED :
Rodent - mouse
DOSE/DURATION :
248 mg/kg
TOXIC EFFECTS :
Details of toxic effects not reported other than lethal dose value

MUTATION DATA

TYPE OF TEST :
Unscheduled DNA synthesis
TEST SYSTEM :
Rodent - rat Liver
DOSE/DURATION :
50 umol/L
REFERENCE :
ENMUDM Environmental Mutagenesis. (New York, NY) V.1-9, 1979-87. For publisher information, see EMMUEG. Volume(issue)/page/year: 3,11,1981 *** NIOSH STANDARDS DEVELOPMENT AND SURVEILLANCE DATA *** NIOSH OCCUPATIONAL EXPOSURE SURVEY DATA : NOHS - National Occupational Hazard Survey (1974) NOHS Hazard Code - M2753 No. of Facilities: 174 (estimated) No. of Industries: 1 No. of Occupations: 2 No. of Employees: 1744 (estimated) NOES - National Occupational Exposure Survey (1983) NOES Hazard Code - M2753 No. of Facilities: 184 (estimated) No. of Industries: 3 No. of Occupations: 6 No. of Employees: 4703 (estimated) No. of Female Employees: 3745 (estimated)
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对溴苯胺安全信息

[ 符号 ]:

GHS06

[ 信号词 ]:
Danger

[ 危害声明 ]:
H302-H311-H315-H319-H335

[ 警示性声明 ]:
P261-P280-P305 + P351 + P338-P312

[ 个人防护装备 ]:
dust mask type N95 (US);Eyeshields;Faceshields;Gloves

[ 危害码 (欧洲) ]:
Xn:Harmful

[ 风险声明 (欧洲) ]:
R20/21/22;R36/37/38

[ 安全声明 (欧洲) ]:
S26-S36/37-S36/37/39

[ 危险品运输编码 ]:
UN 2811 6.1/PG 3

[ WGK德国 ]:
3

[ RTECS号 ]:
BW9280000

[ 包装等级 ]:
III

[ 危险类别 ]:
6.1

[ 海关编码 ]:
29214210

对溴苯胺合成路线

详细合成路线

对溴苯胺上下游产品

对溴苯胺上游产品

对溴苯胺下游产品

对溴苯胺制备

以对硝基苯胺为原料，经重氮化、溴代得到对溴硝基苯，然后用铁粉还原得到。
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对溴苯胺海关

[ 海关编码 ]: 2921420090

[ 中文概述 ]:
2921420090 其他苯胺衍生物及其盐. 增值税率:17.0% 退税率:9.0% 监管条件:无 最惠国关税:6.5% 普通关税:30.0%

[ 申报要素 ]: 品名, 成分含量, 用途

[ Summary ]:
HS:2921420090 aniline derivatives and their salts VAT:17.0% Tax rebate rate:9.0% Supervision conditions:none MFN tariff:6.5% General tariff:30.0%

对溴苯胺文献

Synthetic and biological studies on thioxoquinazolinone substituted isoxazoles.

J. Environ Biol. 36 , 909-18, (2015)

Eighteen novel 5-phenyl-3-(substitutedthioxoquinazolinonyl) isoxazoles (5a-r) were synthesized by cycloaddition of various chalcones with hydroxylaminehydrochloride (NH2OH.HCl). All the newly synthesi...

Biopartitioning micellar chromatography to predict mutagenicity of aromatic amines.

Eur. J. Med. Chem. 42 , 1396-402, (2007)

Mutagenicity is a toxicity endpoint associated with the chronic exposure to chemicals. Aromatic amines have considerable industrial and environmental importance due to their widespread use in industry...

Acute metobromuron poisoning with severe associated methemoglobinemia. Identification of four metabolites in plasma and urine by LC-DAD, LC-ESI-MS, and LC-ESI-MS-MS.

J. Anal. Toxicol. 24(3) , 157-64, (2000)

A case of self poisoning with metobromuron, a urea derivative used as a herbicide, is reported. Severe methemoglobinemia observed at the admission (80%) disappeared only at day 11, and hemolysis appea...


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推荐生产厂家/供应商：

公司名：上海吉至生化科技有限公司

区域：上海市奉贤区

价格：
￥158.0/100g ￥618.0/500g

联系人：刘佳

产品详情：对溴苯胺

公司名：上海阿拉丁生化科技股份有限公司

区域：上海市浦东新区

价格：
￥29.0/5g ￥375.0/500g ￥59.0/25g ￥199.0/250g

联系人：阿拉丁李高志

产品详情：4-溴苯胺

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相关化合物

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