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丙二酰胺

丙二酰胺用途

【用途一】
主要用作有机合成的原料
【用途二】
用于有机合成。

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丙二酰胺名称

[ CAS 号 ]:
108-13-4

[ 中文名 ]:
丙二酰胺

[ 英文名 ]:
Malonamide

[英文别名 ]:

Malonamide
Methylenebisformamide
Propanediamide
METHYLENEDIFORMAMIDE
Malondiamide
EINECS 203-553-8
MFCD00008034
Malonic acid diamide
MALONIC DIAMIDE
Malonodiamide

丙二酰胺物理化学性质

[ 密度 ]:
1.3±0.1 g/cm3

[ 沸点 ]:
460.9±28.0 °C at 760 mmHg

[ 熔点 ]:
172-175 °C(lit.)

[ 分子式 ]:
C₃H₆N₂O₂

[ 分子量 ]:
102.092

[ 闪点 ]:
232.5±24.0 °C

[ 精确质量 ]:
102.042931

[ PSA ]:
86.18000

[ LogP ]:
-2.54

[ 外观性状 ]:
白色结晶粉末

[ 蒸汽压 ]:
0.0±1.1 mmHg at 25°C

[ 折射率 ]:
1.491

[ 储存条件 ]:
室温，密封

[ 水溶解性 ]:
180 g/L (20 ºC)

丙二酰胺MSDS

丙二酰胺毒性和生态

CHEMICAL IDENTIFICATION

RTECS NUMBER :: ON9125000

CHEMICAL NAME :: Malonamide

CAS REGISTRY NUMBER :: 108-13-4

LAST UPDATED :: 199709

DATA ITEMS CITED :: 3

MOLECULAR FORMULA :: C3-H6-N2-O2

MOLECULAR WEIGHT :: 102.11

WISWESSER LINE NOTATION :: ZV1VZ

HEALTH HAZARD DATA

ACUTE TOXICITY DATA

TYPE OF TEST :: LD50 - Lethal dose, 50 percent kill

ROUTE OF EXPOSURE :: Oral

SPECIES OBSERVED :: Rodent - mouse

DOSE/DURATION :: 6 gm/kg

TOXIC EFFECTS :: Tumorigenic - active as anti-cancer agent

REFERENCE :: BIJOAK Biochemical Journal. (Biochemical Soc. Book Depot, POB 32, Commerce Way, Colchester, Essex CO2 8HP, UK) V.1- 1906- Volume(issue)/page/year: 34,1196,1940

TYPE OF TEST :: LD - Lethal dose

ROUTE OF EXPOSURE :: Intraperitoneal

SPECIES OBSERVED :: Rodent - mouse

DOSE/DURATION :: >3 gm/kg

TOXIC EFFECTS :: Details of toxic effects not reported other than lethal dose value

REFERENCE :: PCJOAU Pharmaceutical Chemistry Journal (English Translation). Translation of KHFZAN. (Plenum Pub. Corp., 233 Spring St., New York, NY 10013) No.1- 1967- Volume(issue)/page/year: 11,1383,1977

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丙二酰胺安全信息

[ 个人防护装备 ]:
Eyeshields;Gloves;type N95 (US);type P1 (EN143) respirator filter

[ 危害码 (欧洲) ]:
C

[ 安全声明 (欧洲) ]:
S22-S24/25

[ 危险品运输编码 ]:
NONH for all modes of transport

[ WGK德国 ]:
2

[ RTECS号 ]:
ON9125000

[ 海关编码 ]:
29241900

丙二酰胺合成路线

丙二酰胺上下游产品

丙二酰胺上游产品

丙二酰胺下游产品

丙二酰胺制备

由丙二酸二乙酯与氨反应而得。将氨水加入搪瓷桶内，冷至25℃以下，在搅拌下慢慢加入丙二酸二乙酯，反应温度在20℃左右，反应完后在室温放置两天。滤出底部结晶，减压浓缩，加入脱色炭，经抽滤，冷却结晶，于80℃干燥，粉碎即为成品。

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丙二酰胺海关

[ 海关编码 ]: 2924199090

[ 中文概述 ]:
2924199090. 其他无环酰胺（包括无环氨基甲酸酯)(包括其衍生物及盐）. 增值税率:17.0%. 退税率:13.0%. 监管条件:无. 最惠国关税:6.5%. 普通关税:30.0%

[ 申报要素 ]: 品名, 成分含量, 用途, 包装

[ Summary ]:
2924199090. other acyclic amides (including acyclic carbamates) and their derivatives; salts thereof. VAT:17.0%. Tax rebate rate:13.0%. . MFN tariff:6.5%. General tariff:30.0%

丙二酰胺文献

Altering in vivo macrophage responses with modified polymer properties.

Biomaterials 56 , 187-97, (2015)

Macrophage reprogramming has long been the focus of research in disease therapeutics and biomaterial implantation. With different chemical and physical properties of materials playing a role in macrop...

Influence of Ligand Shell Composition upon Interparticle Interactions in Multifunctional Nanoparticles.

Langmuir 31 , 12742-52, (2015)

The interactions of nanoparticles with biomolecules, surfaces, or other nanostructures are dictated by the nanoparticle's surface chemistry. Thus, far, shortcomings of syntheses of nanoparticles with ...

Effect of surface modification and macrophage phenotype on particle internalization.

Biomacromolecules 15(11) , 4102-10, (2014)

Material properties play a key role in the cellular internalization of polymeric particles. In the present study, we have investigated the effects of material characteristics such as water contact ang...

更多文献

丙二酰胺

丙二酰胺用途

丙二酰胺名称

丙二酰胺物理化学性质

丙二酰胺MSDS

详细MSDS(安全技术说明书)

丙二酰胺毒性和生态

CHEMICAL IDENTIFICATION

HEALTH HAZARD DATA

ACUTE TOXICITY DATA

丙二酰胺安全信息

丙二酰胺合成路线

详细合成路线

丙二酰胺上下游产品

丙二酰胺上游产品

丙二酰胺下游产品

丙二酰胺制备

丙二酰胺海关

丙二酰胺文献

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