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戊二酰亚胺

戊二酰亚胺用途

用作有机合成试剂(例如用以制备N-溴代戊二酰亚胺)。

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戊二酰亚胺名称

[ CAS 号 ]:
1121-89-7

[ 中文名 ]:
戊二酰亚胺

[ 英文名 ]:
Glutarimide

[中文别名 ]:

[英文别名 ]:

2,6-Piperidinedione
GlutariMide 25GR
Glutarimide
piperidin-1-yl-2,6-dione
EINECS 214-340-4
2,6-Diketopiperidine2,6-Piperidinedione
Piperidine-2,6-dione
MFCD00006670
2,6-dioxopiperidine
2,6-Piperidinedione (9CI)

戊二酰亚胺物理化学性质

[ 密度 ]:
1.2±0.1 g/cm3

[ 沸点 ]:
288.0±9.0 °C at 760 mmHg

[ 熔点 ]:
155-157 °C(lit.)

[ 分子式 ]:
C₅H₇NO₂

[ 分子量 ]:
113.115

[ 闪点 ]:
152.3±18.9 °C

[ 精确质量 ]:
113.047676

[ PSA ]:
46.17000

[ LogP ]:
-0.04

[ 外观性状 ]:
白色固体

[ 蒸汽压 ]:
0.0±0.6 mmHg at 25°C

[ 折射率 ]:
1.471

[ 储存条件 ]:
室温，干燥

戊二酰亚胺MSDS

戊二酰亚胺毒性和生态

CHEMICAL IDENTIFICATION

RTECS NUMBER :: MA4000000

CHEMICAL NAME :: Glutarimide

CAS REGISTRY NUMBER :: 1121-89-7

BEILSTEIN REFERENCE NO. :: 0110052

LAST UPDATED :: 199612

DATA ITEMS CITED :: 1

MOLECULAR FORMULA :: C5-H7-N-O2

MOLECULAR WEIGHT :: 113.13

HEALTH HAZARD DATA

ACUTE TOXICITY DATA

TYPE OF TEST :: LD50 - Lethal dose, 50 percent kill

ROUTE OF EXPOSURE :: Intraperitoneal

SPECIES OBSERVED :: Rodent - mouse

DOSE/DURATION :: >600 mg/kg

TOXIC EFFECTS :: Details of toxic effects not reported other than lethal dose value

REFERENCE :: AIPTAK Archives Internationales de Pharmacodynamie et de Therapie. (Heymans Institute of Pharmacology, De Pintelaan 185, B-9000 Ghent, Belgium) V.4- 1898- Volume(issue)/page/year: 173,115,1968

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戊二酰亚胺安全信息

[ 危害码 (欧洲) ]:
Xi:Irritant;

[ 风险声明 (欧洲) ]:
R36

[ 安全声明 (欧洲) ]:
S37/39-S26

[ 危险品运输编码 ]:
NONH for all modes of transport

[ WGK德国 ]:
3

[ RTECS号 ]:
MA4000000

[ 海关编码 ]:
2925190090

戊二酰亚胺合成路线

戊二酰亚胺上下游产品

戊二酰亚胺上游产品

戊二酰亚胺下游产品

戊二酰亚胺制备

本品可用戊二酸或戊二酸酐与氨水反应制得，也可用γ-丁内酯与氰化钾反应制取。

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戊二酰亚胺海关

[ 海关编码 ]: 2925190090

[ 中文概述 ]:
2925190090 其他酰亚胺及其衍生物盐. 增值税率:17.0% 退税率:9.0% 监管条件:无最惠国关税:6.5% 普通关税:30.0%

[ 申报要素 ]: 品名, 成分含量, 用途

[ Summary ]:
2925190090 other imides and their derivatives; salts thereof VAT:17.0% Tax rebate rate:9.0% Supervision conditions:none MFN tariff:6.5% General tariff:30.0%

戊二酰亚胺文献

Comparative characterization of the lactimidomycin and iso-migrastatin biosynthetic machineries revealing unusual features for acyltransferase-less type I polyketide synthases and providing an opportunity to engineer new analogues.

Biochemistry 53(49) , 7854-65, (2014)

Lactimidomycin (LTM, 1) and iso-migrastatin (iso-MGS, 2) belong to the glutarimide-containing polyketide family of natural products. We previously cloned and characterized the mgs biosynthetic gene cl...

Iso-migrastatin congeners from Streptomyces platensis and generation of a glutarimide polyketide library featuring the dorrigocin, lactimidomycin, migrastatin, and NK30424 scaffolds.

J. Am. Chem. Soc. 127(34) , 11930-1, (2005)

Iso-Migrastatin (10) has been shown to be the main natural product of Streptomyces platensis, which undergoes a facile, H2O-mediated rearrangement into dorrigocin A (2), 13-epi-dorrigocin A (11), dorr...

Enantiomerization mechanism of thalidomide and the role of water and hydroxide ions.

Chemistry 18(45) , 14305-13, (2012)

The significance of the molecular chirality of drugs has been widely recognized due to the thalidomide tragedy. Most of the new drugs reaching the market today are single enantiomers, rather than race...

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戊二酰亚胺

戊二酰亚胺用途

戊二酰亚胺名称

戊二酰亚胺物理化学性质

戊二酰亚胺MSDS

详细MSDS(安全技术说明书)

戊二酰亚胺毒性和生态

CHEMICAL IDENTIFICATION

HEALTH HAZARD DATA

ACUTE TOXICITY DATA

戊二酰亚胺安全信息

戊二酰亚胺合成路线

详细合成路线

戊二酰亚胺上下游产品

戊二酰亚胺上游产品

戊二酰亚胺下游产品

戊二酰亚胺制备

戊二酰亚胺海关

戊二酰亚胺文献

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