乙酸己酯

【用途一】
GB 2760—96规定为允许使用的食用香料。主要用于配制苹果、梨等水果型香精。
【用途二】
乙酸乙酯具有果香气，在食用果实香精中使用。也用于有机合成。

[ 密度 ]:
0.9±0.1 g/cm3

[ 沸点 ]:
171.5±3.0 °C at 760 mmHg

[ 熔点 ]:
−80 °C(lit.)

[ 分子式 ]:
C₈H₁₆O₂

[ 分子量 ]:
144.211

[ 闪点 ]:
37.2±0.0 °C

[ 精确质量 ]:
144.115036

[ PSA ]:
26.30000

[ LogP ]:
2.83

[ 外观性状 ]:
无色液体

[ 蒸汽压 ]:
1.4±0.3 mmHg at 25°C

[ 折射率 ]:
1.413

[ 储存条件 ]:
库房通风低温干燥,与氧化剂分开存放

[ 水溶解性 ]:
immiscible

详细MSDS(安全技术说明书)

CHEMICAL IDENTIFICATION

RTECS NUMBER :

AI0875000

CHEMICAL NAME :

Acetic acid, hexyl ester

CAS REGISTRY NUMBER :

142-92-7

BEILSTEIN REFERENCE NO. :

1747138

LAST UPDATED :

199701

DATA ITEMS CITED :

6

MOLECULAR FORMULA :

C8-H16-O2

MOLECULAR WEIGHT :

144.24

WISWESSER LINE NOTATION :

6OV1

HEALTH HAZARD DATA

ACUTE TOXICITY DATA

TYPE OF TEST :

Standard Draize test

ROUTE OF EXPOSURE :

Administration onto the skin

SPECIES OBSERVED :

Rodent - rabbit

REFERENCE :

85JCAE "Prehled Prumyslove Toxikologie; Organicke Latky," Marhold, J., Prague, Czechoslovakia, Avicenum, 1986 Volume(issue)/page/year: -,359,1986

TYPE OF TEST :

Standard Draize test

ROUTE OF EXPOSURE :

Administration into the eye

SPECIES OBSERVED :

Rodent - rabbit

REFERENCE :

85JCAE "Prehled Prumyslove Toxikologie; Organicke Latky," Marhold, J., Prague, Czechoslovakia, Avicenum, 1986 Volume(issue)/page/year: -,359,1986 ** ACUTE TOXICITY DATA **

TYPE OF TEST :

LD50 - Lethal dose, 50 percent kill

ROUTE OF EXPOSURE :

Oral

SPECIES OBSERVED :

Rodent - rat

DOSE/DURATION :

41500 uL/kg

TOXIC EFFECTS :

Details of toxic effects not reported other than lethal dose value

REFERENCE :

TXAPA9 Toxicology and Applied Pharmacology. (Academic Press, Inc., 1 E. First St., Duluth, MN 55802) V.1- 1959- Volume(issue)/page/year: 28,313,1974

TYPE OF TEST :

LD50 - Lethal dose, 50 percent kill

ROUTE OF EXPOSURE :

Administration onto the skin

SPECIES OBSERVED :

Rodent - rabbit

DOSE/DURATION :

>5 gm/kg

TOXIC EFFECTS :

Details of toxic effects not reported other than lethal dose value

REFERENCE :

FCTXAV Food and Cosmetics Toxicology. (London, UK) V.1-19, 1963-81. For publisher information, see FCTOD7. Volume(issue)/page/year: 12,913,1974 *** NIOSH STANDARDS DEVELOPMENT AND SURVEILLANCE DATA *** NIOSH OCCUPATIONAL EXPOSURE SURVEY DATA : NOES - National Occupational Exposure Survey (1983) NOES Hazard Code - X6657 No. of Facilities: 837 (estimated) No. of Industries: 4 No. of Occupations: 7 No. of Employees: 4038 (estimated) No. of Female Employees: 1755 (estimated)

[ 符号 ]:

GHS02

[ 信号词 ]:
Warning

[ 危害声明 ]:
H226

[ 个人防护装备 ]:
Eyeshields;Faceshields;full-face respirator (US);Gloves;multi-purpose combination respirator cartridge (US);type ABEK (EN14387) respirator filter

[ 危害码 (欧洲) ]:
F+

[ 风险声明 (欧洲) ]:
R10

[ 安全声明 (欧洲) ]:
S16

[ 危险品运输编码 ]:
UN 3272 3/PG 3

[ WGK德国 ]:
1

[ RTECS号 ]:
AI0875000

[ 包装等级 ]:
III

[ 危险类别 ]:
3

[ 海关编码 ]:
2915390090

详细合成路线

乙酸己酯上游产品

乙酸己酯下游产品

1.由乙酸与已醇酯化而得。在搪玻璃反应锅内加入23kg正已醇、15kg乙酸、18kg苯、250g硫酸。慢慢加热回流，蒸出物经冷凝在油水分离器分出苯，回流到反应锅中。约2h后，回流的苯清亮时，即水分已脱完。继续蒸出苯，回收套用。剩余物为粗品，加5%碳酸钠溶液洗涤几次，再用水洗涤。经无水碳酸钾干燥后进行分馏，收集170-173℃馏分即得成品。

2.由正己醇和过量乙酐沸腾(或在浓硫酸存在下和过量乙酸)反应而得。

3. 烟草：FC，40。

[ 海关编码 ]: 2915390090

[ 中文概述 ]:
2915390090. 其他乙酸酯. 增值税率:17.0%. 退税率:13.0%. 监管条件:AB(入境货物通关单,出境货物通关单). 最惠国关税:5.5%. 普通关税:30.0%

[ 申报要素 ]: 品名, 成分含量, 用途

[ 监管条件 ]: A.入境货物通关单 B.出境货物通关单

[ 检验检疫 ]: R.进口食品卫生监督检验 S.出口食品卫生监督检验 M.进口商品检验 N.出口商品检验

[ Summary ]:
2915390090. esters of acetic acid. VAT:17.0%. Tax rebate rate:13.0%. Supervision conditions:AB(certificate of inspection for goods inward,certificate of inspection for goods outward). MFN tariff:5.5%. General tariff:30.0%

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公司名：上海化源世纪贸易有限公司

区域：上海市普陀区

价格：

联系人：徐经理

产品详情：乙酸正己酯

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公司名：上海吉至生化科技有限公司

区域：上海市奉贤区

价格：
￥168.0/500ml

联系人：刘佳

产品详情：乙酸正己酯

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公司名：上海阿拉丁生化科技股份有限公司

区域：上海市浦东新区

价格：
￥需询单/1mg ￥需询单/1g ￥需询单/1g ￥需询单/1g

联系人：阿拉丁

产品详情：乙酸正己酯

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