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菲啶

菲啶用途

国际标准样品、对照品、标样、分析标准品

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菲啶名称

[ CAS 号 ]:
229-87-8

[ 中文名 ]:
菲啶

[ 英文名 ]:
Phenanthridine

[中文别名 ]:

[英文别名 ]:

3,4-Benzoquinoline
Benzo[h]quinoline
9-Azaphenanthrene
MFCD00004989
PHENANTHRIDIN
EINECS 205-934-4
6-Phenanthridine
3,4-Benzoisoquinoline
5-azaphenanthrene
5-phenantridine

菲啶物理化学性质

[ 密度 ]:
1.2±0.1 g/cm3

[ 沸点 ]:
350.4±11.0 °C at 760 mmHg

[ 熔点 ]:
104-107 °C(lit.)

[ 分子式 ]:
C₁₃H₉N

[ 分子量 ]:
179.217

[ 闪点 ]:
155.9±11.9 °C

[ 精确质量 ]:
179.073502

[ PSA ]:
12.89000

[ LogP ]:
3.32

[ 外观性状 ]:
白色至米色粉末

[ 蒸汽压 ]:
0.0±0.7 mmHg at 25°C

[ 折射率 ]:
1.727

[ 储存条件 ]:
室温，密封，干燥

[ 水溶解性 ]:
可溶于：甲醇

菲啶MSDS

菲啶毒性和生态

CHEMICAL IDENTIFICATION

RTECS NUMBER :: SF7928000

CHEMICAL NAME :: Phenanthridine

CAS REGISTRY NUMBER :: 229-87-8

BEILSTEIN REFERENCE NO. :: 0120204

LAST UPDATED :: 199710

DATA ITEMS CITED :: 3

MOLECULAR FORMULA :: C13-H9-N

MOLECULAR WEIGHT :: 179.23

WISWESSER LINE NOTATION :: T B666 HNJ

HEALTH HAZARD DATA

ACUTE TOXICITY DATA

MUTATION DATA

TYPE OF TEST :: Mutation in microorganisms

TEST SYSTEM :: Bacteria - Salmonella typhimurium

DOSE/DURATION :: 50 ug/plate

REFERENCE :: 50NNAZ "Polynuclear Aromatic Hydrocarbons, International Symposium, 7th, 1982," Cooke, M., and A.J. Dennis, eds., Columbus, OH, Battelle Press, 1983 Volume(issue)/page/year: 7,73,1983

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菲啶安全信息

[ 符号 ]:

GHS05, GHS06

[ 信号词 ]:
Danger

[ 危害声明 ]:
H301-H315-H318-H335

[ 警示性声明 ]:
P261-P280-P301 + P310-P305 + P351 + P338

[ 个人防护装备 ]:
dust mask type N95 (US);Eyeshields;Faceshields;Gloves

[ 危害码 (欧洲) ]:
Xn: Harmful;

[ 风险声明 (欧洲) ]:
R40

[ 安全声明 (欧洲) ]:
S26-S39

[ 危险品运输编码 ]:
UN 2811 6.1/PG 3

[ WGK德国 ]:
3

[ RTECS号 ]:
SF7928000

[ 海关编码 ]:
2933990090

菲啶合成路线

菲啶上下游产品

菲啶上游产品

菲啶下游产品

菲啶海关

[ 海关编码 ]: 2933990090

[ 中文概述 ]:
2933990090. 其他仅含氮杂原子的杂环化合物. 增值税率:17.0%. 退税率:13.0%. 监管条件:无. 最惠国关税:6.5%. 普通关税:20.0%

[ 申报要素 ]: 品名, 成分含量, 用途, 乌洛托品请注明外观, 6－己内酰胺请注明外观, 签约日期

[ Summary ]:
2933990090. heterocyclic compounds with nitrogen hetero-atom(s) only. VAT:17.0%. Tax rebate rate:13.0%. . MFN tariff:6.5%. General tariff:20.0%

菲啶文献

Convenient QSAR model for predicting the complexation of structurally diverse compounds with β-cyclodextrins

Bioorg. Med. Chem. 17 , 896-904, (2009)

This paper reports a QSAR study for predicting the complexation of a large and heterogeneous variety of substances (233 organic compounds) with beta-cyclodextrins (beta-CDs). Several different theoret...

Direct, catalytic, and regioselective synthesis of 2-alkyl-, aryl-, and alkenyl-substituted N-heterocycles from N-oxides.

Org. Lett. 16(3) , 864-7, (2014)

A one-step transformation of heterocyclic N-oxides to 2-alkyl-, aryl-, and alkenyl-substituted N-heterocycles is described. The success of this broad-scope methodology hinges on the combination of cop...

Analogues of morphanthridine and the tear gas dibenz[b,f][1,4]oxazepine (CR) as extremely potent activators of the human transient receptor potential ankyrin 1 (TRPA1) channel.

J. Med. Chem. 53 , 7011-20, (2010)

The TRPA1 channel can be considered as a key biological sensor to irritant chemicals. In this paper, the discovery of 11H-dibenz[b,e]azepines (morphanthridines) and dibenz[b,f][1,4]oxazepines is descr...

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菲啶