二乙氧基甲烷
二乙氧基甲烷用途
用于有机合成、医药工业
【用途二】
用于合成甲苯基甲醛树脂、香料,也用作溶剂和油漆的生产。
【用途三】
用于合成甲苯基甲醛树脂;香料,也用作溶剂和油漆的生产。
二乙氧基甲烷名称
[ CAS 号 ]:
462-95-3
[ 中文名 ]:
二乙氧基甲烷
[ 英文名 ]:
diethoxymethane
[中文别名 ]:
[英文别名 ]:
- Formaldehyde Diethyl Acetal
- diethoxy methane
- diethoxymethane
- Methylene Glycol Diethyl Ether
- EINECS 207-330-6
- Formaldehyde, diethyl acetal
- (Ethoxymethoxy)ethane
- Ethane, 1,1'-[methylenebis(oxy)]bis-
- ethoxymethoxyethane
- MFCD00009246
二乙氧基甲烷物理化学性质
[ 密度 ]:
0.8±0.1 g/cm3
[ 沸点 ]:
89.0±0.0 °C at 760 mmHg
[ 熔点 ]:
-66.5 °C
[ 分子式 ]:
C5H12O2
[ 分子量 ]:
104.148
[ 闪点 ]:
-5.6±0.0 °C
[ 精确质量 ]:
104.083733
[ PSA ]:
18.46000
[ LogP ]:
0.80
[ 外观性状 ]:
透明液体
[ 蒸汽密度 ]:
3.6 (vs air)
[ 蒸汽压 ]:
67.3±0.1 mmHg at 25°C
[ 折射率 ]:
1.380
[ 储存条件 ]:
库房通风低温干燥,与氧化剂、酸类分开存放
[ 稳定性 ]:
Stable. Highly flammable. Incompatible with strong oxidizing agents, strong acids.
[ 水溶解性 ]:
4.2 G/100 ML
二乙氧基甲烷MSDS
二乙氧基甲烷毒性和生态
CHEMICAL IDENTIFICATION
- RTECS NUMBER :
- PA8500000
- CHEMICAL NAME :
- Methane, diethoxy-
- CAS REGISTRY NUMBER :
- 462-95-3
- BEILSTEIN REFERENCE NO. :
- 1697253
- LAST UPDATED :
- 199709
- DATA ITEMS CITED :
- 3
- MOLECULAR FORMULA :
- C5-H12-O2
- MOLECULAR WEIGHT :
- 104.17
- WISWESSER LINE NOTATION :
- 2O1O2
HEALTH HAZARD DATA
ACUTE TOXICITY DATA
- TYPE OF TEST :
- LD50 - Lethal dose, 50 percent kill
- ROUTE OF EXPOSURE :
- Oral
- SPECIES OBSERVED :
- Rodent - rabbit
- DOSE/DURATION :
- 2604 mg/kg
- TOXIC EFFECTS :
- Details of toxic effects not reported other than lethal dose value
- REFERENCE :
- PSEBAA Proceedings of the Society for Experimental Biology and Medicine. (Academic Press, Inc., 1 E. First St., Duluth, MN 55802) V.1- 1903/04- Volume(issue)/page/year: 29,730,1932 *** NIOSH STANDARDS DEVELOPMENT AND SURVEILLANCE DATA *** NIOSH OCCUPATIONAL EXPOSURE SURVEY DATA : NOHS - National Occupational Hazard Survey (1974) NOHS Hazard Code - 84039 No. of Facilities: 5 (estimated) No. of Industries: 1 No. of Occupations: 2 No. of Employees: 20 (estimated)
二乙氧基甲烷安全信息
[ 符号 ]:
GHS02, GHS07
[ 信号词 ]:
Danger
[ 危害声明 ]:
H225-H315-H319-H335
[ 警示性声明 ]:
P210-P261-P305 + P351 + P338
[ 个人防护装备 ]:
Eyeshields;Faceshields;full-face respirator (US);Gloves;multi-purpose combination respirator cartridge (US);type ABEK (EN14387) respirator filter
[ 危害码 (欧洲) ]:
F:Flammable;Xi:Irritant;
[ 风险声明 (欧洲) ]:
R11;R36/37/38
[ 安全声明 (欧洲) ]:
S16-S26-S36
[ 危险品运输编码 ]:
UN 2373 3/PG 2
[ WGK德国 ]:
2
[ RTECS号 ]:
PA8500000
[ 包装等级 ]:
II
[ 危险类别 ]:
3
[ 海关编码 ]:
2909199090
二乙氧基甲烷合成路线
二乙氧基甲烷上下游产品
二乙氧基甲烷上游产品
二乙氧基甲烷下游产品
二乙氧基甲烷制备
生产氯霉素的副产品。对硝基苯乙酮溶在氯苯中,在26-28℃下搅拌并滴加溴素,溴化得到对硝基-α-溴代苯乙酮。然后加入乌洛托品并补充氯苯,制成对硝基-α-溴代苯乙酮乌洛托品盐溶液。将此成盐液加入27%的盐酸溶液中,分去氯苯后,加入乙醇、食盐进行水解反应。也可由甲醛与乙醇进行醇醛缩合反应制得。
二乙氧基甲烷海关
[ 海关编码 ]: 2909199090
[ 中文概述 ]:
2909199090. 其他无环醚及其卤化衍生物(包括磺化,硝化或亚硝化衍生物). 增值税率:17.0%. 退税率:13.0%. 监管条件:无. 最惠国关税:5.5%. 普通关税:30.0%
[ 申报要素 ]: 品名, 成分含量, 用途
[ Summary ]:
2909199090. other acyclic ethers and their halogenated, sulphonated, nitrated or nitrosated derivatives. VAT:17.0%. Tax rebate rate:13.0%. . MFN tariff:5.5%. General tariff:30.0%
二乙氧基甲烷文献
J. Proteomics 128 , 18-29, (2015)
Cellular senescence causes profound changes in gene expression profile. In this study, we used a combined 2D-DIGE and nanoLC-ESI-LIT-MS/MS approach to evaluate the proteomic changes occurring both in ...
Designing greener plasticizers: Effects of alkyl chain length and branching on the biodegradation of maleate based plasticizers.Chemosphere 134 , 106-12, (2015)
The ubiquitous presence of the plasticizer di (2-ethylhexyl) phthalate (DEHP) in the environment is of concern due to negative biological effects associated with it and its metabolites. In particular,...
A novel toxicogenomics-based approach to categorize (non-)genotoxic carcinogens.Arch. Toxicol. 89 , 2413-27, (2015)
Alternative methods to detect non-genotoxic carcinogens are urgently needed, as this class of carcinogens goes undetected in the current testing strategy for carcinogenicity under REACH. A complicatin...
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