顺乌头酸

顺乌头酸用途

(Z)-Aconitic acid (cis-Aconitic acid) 是 Aconitic acid 的顺式异构体。(Z)-Aconitic acid (cis-Aconitic acid) 是三羧酸循环中柠檬酸盐异构化为异柠檬酸盐的中间产物。

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顺乌头酸名称

[ CAS 号 ]:
585-84-2

[ 中文名 ]:
顺式-乌头酸

[ 英文名 ]:
cis-Aconitic acid

[中文别名 ]:

[英文别名 ]:

cis-Citridic acid
MFCD00063184
(1Z)-1-Propene-1,2,3-tricarboxylic acid
(Z)-Prop-1-ene-1,2,3-tricarboxylic acid
cis-Oxaloacetic acid
Propen-1t,2,3-tricarbonsaeure
FEMA 2010
1-Propene-1,2,3-tricarboxylic acid, (Z)-
propene-1t,2,3-tricarboxylic acid
1-Propene-1,2,3-tricarboxylic acid, (1Z)-

顺乌头酸生物活性

[ 描述 ]:

(Z)-Aconitic acid (cis-Aconitic acid) 是 Aconitic acid 的顺式异构体。(Z)-Aconitic acid (cis-Aconitic acid) 是三羧酸循环中柠檬酸盐异构化为异柠檬酸盐的中间产物。

[ 相关类别 ]:

研究领域 >> 其他

信号通路 >> 其他 >> 其他

顺乌头酸物理化学性质

[ 密度 ]:
1.7±0.1 g/cm3

[ 沸点 ]:
542.6±50.0 °C at 760 mmHg

[ 熔点 ]:
122ºC(lit.)

[ 分子式 ]:
C₆H₆O₆

[ 分子量 ]:
174.108

[ 闪点 ]:
296.0±26.6 °C

[ 精确质量 ]:
174.016434

[ PSA ]:
111.90000

[ LogP ]:
0.63

[ 外观性状 ]:
白色至近乎于白色粉末

[ 蒸汽压 ]:
0.0±3.1 mmHg at 25°C

[ 折射率 ]:
1.571

[ 储存条件 ]:
2-8°C

顺乌头酸MSDS

顺乌头酸安全信息

[ 符号 ]:

GHS08

[ 信号词 ]:
Warning

[ 危害声明 ]:
H351

[ 警示性声明 ]:
P281

[ 危害码 (欧洲) ]:
Xn,Xi

[ 风险声明 (欧洲) ]:
R36/38

[ 安全声明 (欧洲) ]:
S26-S36-S37

[ 危险品运输编码 ]:
NONH for all modes of transport

[ WGK德国 ]:
1

[ 海关编码 ]:
2917190090

顺乌头酸合成路线

顺乌头酸上下游产品

顺乌头酸上游产品

顺乌头酸下游产品

顺乌头酸制备

1.制法：

于装有搅拌器、回流冷凝器的1L反应瓶中，加入105mL水，210g(115mL)浓硫酸，搅拌下加入含1个结晶水的柠檬酸(2)210g（1mol），于140～145℃的油浴中加热反应7h，得浅棕色溶液。稍冷后倒入搪瓷盘中，不断搅动下冷却至40～45℃，析出固体。抽滤，将固体物加到预先在冰浴中冷却的70mL浓盐酸中，搅成糊状。抽滤，用冷的冰乙酸洗涤两次，抽干后，干燥器中干燥，得无色结晶状3-羟基戊烯-2-二酸(1)71～77g,收率41%～44%。

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顺乌头酸海关

[ 海关编码 ]: 2917190090

[ 中文概述 ]:
2917190090 其他无环多元羧酸. 增值税率:17.0% 退税率:9.0% 监管条件:无最惠国关税:6.5% 普通关税:30.0%

[ 申报要素 ]: 品名, 成分含量, 用途, 对苯二甲酸请注明4-CBA值, 对苯二甲酸请注明P-TL酸值, 对苯二甲酸请注明色度, 对苯二甲酸请注明水分

[ Summary ]:
2917190090 acyclic polycarboxylic acids, their anhydrides, halides, peroxides, peroxyacids and their derivatives VAT:17.0% Tax rebate rate:9.0% Supervision conditions:none MFN tariff:6.5% General tariff:30.0%

顺乌头酸文献

Physiology and pathophysiology of organic acids in cerebrospinal fluid.

J. Inherit. Metab. Dis. 16(4) , 648-69, (1993)

Concentrations of organic acids in cerebrospinal fluid (CSF) appear to be directly dependent upon their rate of production in the brain. There is evidence that the net release of short-chain monocarbo...

HMDB: a knowledgebase for the human metabolome.

Nucleic Acids Res. 37(Database issue) , D603-10, (2009)

The Human Metabolome Database (HMDB, http://www.hmdb.ca) is a richly annotated resource that is designed to address the broad needs of biochemists, clinical chemists, physicians, medical geneticists, ...

Age-related reference values for urinary organic acids in a healthy Turkish pediatric population.

Clin. Chem. 40(6) , 862-6, (1994)

Organic acid concentrations were quantified by gas chromatography and the individual acids identified by mass spectrometry in urine specimens from a healthy Turkish pediatric population of ages 2 days...

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