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1,2-环己二胺

1,2-环己二胺用途

【用途一】
奥沙利铂中间体。

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1,2-环己二胺名称

[ CAS 号 ]:
694-83-7

[ 中文名 ]:
1,2-二氨基环己烷

[ 英文名 ]:
1,2-Diaminocyclohexane

[中文别名 ]:

[英文别名 ]:

1,2-Diaminocyclohexane
cyclohexan-1,2-diamin
Cyclohexane-1,2-diamine
EINECS 211-776-7
MFCD00062985

1,2-环己二胺物理化学性质

[ 密度 ]:
0.9±0.1 g/cm3

[ 沸点 ]:
193.6±0.0 °C at 760 mmHg

[ 熔点 ]:
41685ºC

[ 分子式 ]:
C₆H₁₄N₂

[ 分子量 ]:
114.189

[ 闪点 ]:
75.0±0.0 °C

[ 精确质量 ]:
114.115700

[ PSA ]:
52.04000

[ LogP ]:
-0.12

[ 外观性状 ]:
透明暗黄色液体

[ 蒸汽压 ]:
0.5±0.3 mmHg at 25°C

[ 折射率 ]:
1.484

[ 储存条件 ]:
库房通风低温干燥,与食品原料分开储运

[ 水溶解性 ]:
miscible

1,2-环己二胺MSDS

详细MSDS(安全技术说明书)

1,2-环己二胺毒性和生态

CHEMICAL IDENTIFICATION

RTECS NUMBER :: GU8749500

CHEMICAL NAME :: 1,2-Cyclohexanediamine

CAS REGISTRY NUMBER :: 694-83-7

BEILSTEIN REFERENCE NO. :: 0506142

LAST UPDATED :: 199806

DATA ITEMS CITED :: 5

MOLECULAR FORMULA :: C6-H14-N2

MOLECULAR WEIGHT :: 114.22

HEALTH HAZARD DATA

ACUTE TOXICITY DATA

TYPE OF TEST :: Standard Draize test

ROUTE OF EXPOSURE :: Administration onto the skin

SPECIES OBSERVED :: Rodent - rabbit

REFERENCE :: ATDAEI Acute Toxicity Data. Journal of the American College of Toxicology, Part B. (Mary Ann Liebert, Inc., 1651 Third Ave., New York, NY 10128) V.1- 1990- Volume(issue)/page/year: 1,8,1990 ** ACUTE TOXICITY DATA **

TYPE OF TEST :: LD50 - Lethal dose, 50 percent kill

ROUTE OF EXPOSURE :: Oral

SPECIES OBSERVED :: Rodent - rat

DOSE/DURATION :: 4556 mg/kg

TOXIC EFFECTS :: Behavioral - somnolence (general depressed activity) Behavioral - tremor

REFERENCE :: NTIS** National Technical Information Service. (Springfield, VA 22161) Formerly U.S. Clearinghouse for Scientific & Technical Information. Volume(issue)/page/year: OTS0535386

TYPE OF TEST :: LCLo - Lowest published lethal concentration

ROUTE OF EXPOSURE :: Inhalation

SPECIES OBSERVED :: Rodent - rat

DOSE/DURATION :: 3200 mg/m3/4H

TOXIC EFFECTS :: Details of toxic effects not reported other than lethal dose value

REFERENCE :: TOXID9 Toxicologist. (Soc. of Toxicology, Inc., 475 Wolf Ledge Parkway, Akron, OH 44311) V.1- 1981- Volume(issue)/page/year: 12,357,1992

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1,2-环己二胺安全信息

[ 符号 ]:

GHS05

[ 信号词 ]:
Danger

[ 危害声明 ]:
H314

[ 警示性声明 ]:
P280-P305 + P351 + P338-P310

[ 个人防护装备 ]:
Faceshields;full-face respirator (US);Gloves;Goggles;multi-purpose combination respirator cartridge (US);type ABEK (EN14387) respirator filter

[ 危害码 (欧洲) ]:
C:Corrosive;

[ 风险声明 (欧洲) ]:
R34

[ 安全声明 (欧洲) ]:
S26-S36/37/39-S45

[ 危险品运输编码 ]:
UN 3259 8/PG 2

[ WGK德国 ]:
3

[ RTECS号 ]:
GU8749500

[ 包装等级 ]:
III

[ 危险类别 ]:
8.0

[ 海关编码 ]:
29213099

1,2-环己二胺上下游产品

1,2-环己二胺上游产品

1,2-环己二胺下游产品

1,2-环己二胺海关

[ 海关编码 ]: 29213099

1,2-环己二胺文献

Mechanical stimulation of human tendon stem/progenitor cells results in upregulation of matrix proteins, integrins and MMPs, and activation of p38 and ERK1/2 kinases.

BMC Mol. Biol. 16 , 6, (2015)

Tendons are dense connective tissues subjected periodically to mechanical stress upon which complex responsive mechanisms are activated. These mechanisms affect not only the development of these tissu...

Steric modifications tune the regioselectivity of the alkane oxidation catalyzed by non-heme iron complexes.

Inorg. Chem. 50(24) , 12651-60, (2011)

Iron complexes with the tetradentate N-donor ligand N,N'-di(phenylmethyl)-N,N'-bis(2-pyridinylmethyl)-1,2-cyclohexanediamine (bbpc) are reported. Despite the benzyl groups present on the amines, the i...

Antitumor platinum(II) complexes of N-monoalkyl-1R, 2R-diaminocyclohexane derivatives with alkyl groups as hindrance.

J. Inorg. Biochem. 112 , 68-76, (2012)

A number of platinum (II) complexes, characteristic of (1R,2R)-N(1)-alkyl-1,2-diaminocyclohexane derivatives as carrier ligands, were designed, synthesized and characterized, where the alkyl group ser...

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