三氧化硫
三氧化硫用途
用于制硫酸、氯磺酸、氨基磺酸、硫酸二甲酯、洗涤剂及用作有机合成磺化剂
【用途二】
主要用于有机化合物的磺化及硫酸盐化方面。在表面活性剂和离子交换树脂生产中广泛用作反应剂。也用于磺胺的合成。用于染料中间体的生产,石油润滑馏分的精制。
三氧化硫名称
[ CAS 号 ]:
7446-11-9
[ 中文名 ]:
三氧化硫
[ 英文名 ]:
Sulfur trioxide
[中文别名 ]:
[英文别名 ]:
- Schwefeltrioxid
- MFCD00011452
- SULPHUR TRIOXIDE
- Sulfan
- Sulfur oxide (SO3)
- Sulfuric oxide
- SULFAN(R)
- sulfuric acid anhydride
- SO3
- EINECS 231-197-3
三氧化硫物理化学性质
[ 密度 ]:
1.97 g/mL at 25 °C(lit.)
[ 沸点 ]:
44.8 °C
[ 熔点 ]:
16.8 °C(lit.)
[ 分子式 ]:
O3S
[ 分子量 ]:
80.06320
[ 精确质量 ]:
79.95680
[ PSA ]:
83.30000
[ LogP ]:
0.29180
[ 外观性状 ]:
针状或聚合物
[ 蒸汽密度 ]:
2.8 (vs air)
[ 蒸汽压 ]:
280 mm Hg ( 25 °C)
[ 储存条件 ]:
库房通风低温干燥,与有机物、还原物、易燃物分开存放
[ 稳定性 ]:
Stable. Incompatible with organic materials, finely powdered metals, bases, water, cyanides and a wide variety of other chemicals. Reacts violently with water, oxygen and other chemicals - read a full data sheet before use.
[ 水溶解性 ]:
reacts violently
三氧化硫MSDS
三氧化硫毒性和生态
CHEMICAL IDENTIFICATION
- RTECS NUMBER :
- WT4830000
- CHEMICAL NAME :
- Sulfur trioxide
- CAS REGISTRY NUMBER :
- 7446-11-9
- LAST UPDATED :
- 199710
- DATA ITEMS CITED :
- 13
- MOLECULAR FORMULA :
- O3-S
- MOLECULAR WEIGHT :
- 80.06
- WISWESSER LINE NOTATION :
- S O3
HEALTH HAZARD DATA
ACUTE TOXICITY DATA
- TYPE OF TEST :
- TCLo - Lowest published toxic concentration
- ROUTE OF EXPOSURE :
- Inhalation
- SPECIES OBSERVED :
- Human
- DOSE/DURATION :
- 30 mg/m3
- TOXIC EFFECTS :
- Sense Organs and Special Senses (Olfaction) - effect, not otherwise specified Lungs, Thorax, or Respiration - cough Lungs, Thorax, or Respiration - other changes
- REFERENCE :
- JPBAA7 Journal of Pathology and Bacteriology. (London, UK) V.1-96, 1892-1968. For publisher information, see JPTLAS. Volume(issue)/page/year: 68,197,1954
- TYPE OF TEST :
- LCLo - Lowest published lethal concentration
- ROUTE OF EXPOSURE :
- Inhalation
- SPECIES OBSERVED :
- Rodent - guinea pig
- DOSE/DURATION :
- 30 mg/m3/6H
- TOXIC EFFECTS :
- Liver - hepatitis (hepatocellular necrosis), diffuse Lungs, Thorax, or Respiration - structural or functional change in trachea or bronchi Endocrine - other changes
- REFERENCE :
- JPBAA7 Journal of Pathology and Bacteriology. (London, UK) V.1-96, 1892-1968. For publisher information, see JPTLAS. Volume(issue)/page/year: 68,197,1954 *** REVIEWS *** IARC Cancer Review:Human Sufficient Evidence IMEMDT IARC Monographs on the Evaluation of Carcinogenic Risk of Chemicals to Man. (WHO Publications Centre USA, 49 Sheridan Ave., Albany, NY 12210) V.1- 1972- Volume(issue)/page/year: 54,41,1992 IARC Cancer Review:Group 1 IMEMDT IARC Monographs on the Evaluation of Carcinogenic Risk of Chemicals to Man. (WHO Publications Centre USA, 49 Sheridan Ave., Albany, NY 12210) V.1- 1972- Volume(issue)/page/year: 54,41,1992 TOXICOLOGY REVIEW AEHLAU Archives of Environmental Health. (Heldref Pub., 4000 Albemarle St., NW, Washington, DC 20016) V.1- 1960- Volume(issue)/page/year: 16,903,1968 *** OCCUPATIONAL EXPOSURE LIMITS *** OEL-FINLAND:STEL 1 ppm (3 mg/m3);Skin JAN 1993 OEL-HUNGARY:STEL 1 mg/m3 JAN 1993 OEL-POLAND:TWA 1 mg/m3 JAN 1993 OEL-RUSSIA:STEL 1 mg/m3;Skin JAN 1993 *** NIOSH STANDARDS DEVELOPMENT AND SURVEILLANCE DATA *** NIOSH OCCUPATIONAL EXPOSURE SURVEY DATA : NOHS - National Occupational Hazard Survey (1974) NOHS Hazard Code - M0745 No. of Facilities: 1316 (estimated) No. of Industries: 20 No. of Occupations: 39 No. of Employees: 51404 (estimated) NOES - National Occupational Exposure Survey (1983) NOES Hazard Code - M0745 No. of Facilities: 2524 (estimated) No. of Industries: 17 No. of Occupations: 27 No. of Employees: 56102 (estimated) No. of Female Employees: 3077 (estimated)
三氧化硫安全信息
[ 符号 ]:
GHS05, GHS07
[ 信号词 ]:
Danger
[ 危害声明 ]:
H314-H335
[ 补充危害声明 ]:
Reacts violently with water.
[ 警示性声明 ]:
P261-P280-P305 + P351 + P338-P310
[ 个人防护装备 ]:
Faceshields;full-face respirator (US);Gloves;Goggles;multi-purpose combination respirator cartridge (US)
[ 危害码 (欧洲) ]:
C:Corrosive;
[ 风险声明 (欧洲) ]:
R14;R34
[ 安全声明 (欧洲) ]:
S53-S17-S26-S36/37/39-S45-S8-S25
[ 危险品运输编码 ]:
UN 1829 8/PG 1
[ WGK德国 ]:
1
[ RTECS号 ]:
WT4830000
[ 包装等级 ]:
I
[ 危险类别 ]:
8
三氧化硫合成路线
三氧化硫上下游产品
三氧化硫上游产品
三氧化硫下游产品
三氧化硫制备
三氧化硫文献
Drug Test. Anal. 7(4) , 320-30, (2015)
Our previous study indicated that sulphur-fumigation of ginseng in post-harvest handling processes could induce chemical transformation of ginsenosides to generate multiple ginsenoside sulphur derivat...
Preparation and in vitro antioxidant activities of 6-amino-6-deoxychitosan and its sulfonated derivatives.Biopolymers 103 , 539-49, (2015)
The 6-amino-6-deoxychitosan (NC) and their 2, 6-di-N-sulfonated derivatives were prepared via N-phthaloylation, tosylation, azidation, hydrazinolysis, reduction of azide groups and N-sulfonation, and ...
Ligand regulation of a constitutively dimeric EGF receptor.Nat. Commun. 6 , 7380, (2015)
Ligand-induced receptor dimerization has traditionally been viewed as the key event in transmembrane signalling by epidermal growth factor receptors (EGFRs). Here we show that the Caenorhabditis elega...
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三氧化硫相关知识
2019-07-19 20:37:09
会。三氧化硫是硫酸的酸酐,是一种酸性氧化物,酸性氧化物会和氢氧化钠这类碱发生反应。发生的反应应为三氧化硫与氢氧化钠反应生成硫酸钠与水的反应,反应方程式为:2NaOH+SO3=Na2SO4+H2O当SO3过量时的反应式为:NaOH+SO3=NaHSO4
2019-07-30 21:19:32
三氧化硫的物理性质为:三氧化硫是一种无色易升华的固体,有三种物态。(高中化学一般认为其在通常情况下是液体,标准状况下是固体,加热后是气体。)α-SO3丝质纤维状和针状,密度1.97g/cm³,熔点62.3℃;β-SO3石棉纤维状,熔点62.4℃,在50℃可升华; γ-SO3玻璃状,熔点16.8℃,...
相关化合物
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