五氯硝基苯
五氯硝基苯用途
用作拌种剂和土壤处理剂，用于防治棉花立枯病、炭疽病、小麦腥黑穗病、散黑穗病、蔬菜猝倒病、大蒜白腐病等
【用途二】
保护性杀菌剂，低毒，无内吸作用。用于种子清毒和土壤处理，其杀菌机制是影响菌丝细胞的有丝分裂。防治小麦腥黑穗病、散黑穗病，用40%粉剂500g拌种100kg；防治棉花苗期病害用40%粉剂1000g拌种100kg；防治油菜菌核病，每百平方米用40%粉剂65.6g拌细土1.5～3kg，在发病初期撒于根部附近；防治马铃薯疮痂病，每百平方米用50%可湿性粉剂375～675g，条施于播种沟内。
【用途三】
优良的土壤杀菌剂，用作拌种剂和土壤处理剂，用于防治棉花立枯病、猝倒病，小麦、高梁腥黑穗病，马铃薯疮痂病，甘兰根肿病，莴苣灰霉病等。喷洒可防治水稻纹枯病。
【用途四】
优良的土壤杀菌剂，用作拌种剂和土壤处理剂，用于防治棉花立枯病、猝倒病，小麦、高梁腥黑穗病，马铃薯疮痂病，甘兰根肿病，莴苣灰霉病等。喷洒可防治水稻纹枯病。校准仪器和装置；评价方法；工作标准；质量保证/质量控制；其他。
五氯硝基苯名称
[ CAS 号 ]:
82-68-8
[ 中文名 ]:
五氯硝基苯
[ 英文名 ]:
Pentachloronitrobenzene
[中文别名 ]:
[英文别名 ]:
- Folosan (VAN)
- Brassicol
- PCNB
- Batrilex
- Benzene, 1,2,3,4,5-pentachloro-6-nitro-
- 2,3,4,5,6-pentachloronitrobenzene
- terraclor
- Benzene,pentachloronitro
- EINECS 201-435-0
- Quintozene
五氯硝基苯物理化学性质
[ 密度 ]:
1.8±0.1 g/cm3
[ 沸点 ]:
328.0±0.0 °C at 760 mmHg
[ 熔点 ]:
140-143 °C(lit.)
[ 分子式 ]:
C6Cl5NO2
[ 分子量 ]:
295.335
[ 闪点 ]:
161.6±26.5 °C
[ 精确质量 ]:
292.837158
[ PSA ]:
45.82000
[ LogP ]:
4.16
[ 外观性状 ]:
白色至淡黄色固体
[ 蒸汽压 ]:
0.0±0.6 mmHg at 25°C
[ 折射率 ]:
1.630
[ 储存条件 ]:
库房通风低温干燥,与食品原料分开储运
[ 稳定性 ]:
Stable. Incompatible with strong bases, strong oxidizing agents.
[ 水溶解性 ]:
Insoluble
五氯硝基苯MSDS
五氯硝基苯毒性和生态
CHEMICAL IDENTIFICATION
- RTECS NUMBER :
- DA6650000
- CHEMICAL NAME :
- Benzene, pentachloronitro-
- CAS REGISTRY NUMBER :
- 82-68-8
- BEILSTEIN REFERENCE NO. :
- 1914324
- LAST UPDATED :
- 199712
- DATA ITEMS CITED :
- 45
- MOLECULAR FORMULA :
- C6-Cl5-N-O2
- MOLECULAR WEIGHT :
- 295.32
- WISWESSER LINE NOTATION :
- WNR BG CG DG EG FG
HEALTH HAZARD DATA
ACUTE TOXICITY DATA
- TYPE OF TEST :
- LD50 - Lethal dose, 50 percent kill
- ROUTE OF EXPOSURE :
- Oral
- SPECIES OBSERVED :
- Rodent - rat
- DOSE/DURATION :
- 1100 mg/kg
- TOXIC EFFECTS :
- Details of toxic effects not reported other than lethal dose value
- TYPE OF TEST :
- LC50 - Lethal concentration, 50 percent kill
- ROUTE OF EXPOSURE :
- Inhalation
- SPECIES OBSERVED :
- Rodent - rat
- DOSE/DURATION :
- 1400 mg/m3
- TOXIC EFFECTS :
- Details of toxic effects not reported other than lethal dose value
- TYPE OF TEST :
- LD50 - Lethal dose, 50 percent kill
- ROUTE OF EXPOSURE :
- Intraperitoneal
- SPECIES OBSERVED :
- Rodent - rat
- DOSE/DURATION :
- 5 gm/kg
- TOXIC EFFECTS :
- Details of toxic effects not reported other than lethal dose value
- TYPE OF TEST :
- LD50 - Lethal dose, 50 percent kill
- ROUTE OF EXPOSURE :
- Oral
- SPECIES OBSERVED :
- Rodent - mouse
- DOSE/DURATION :
- 1400 mg/kg
- TOXIC EFFECTS :
- Details of toxic effects not reported other than lethal dose value
- TYPE OF TEST :
- LC50 - Lethal concentration, 50 percent kill
- ROUTE OF EXPOSURE :
- Inhalation
- SPECIES OBSERVED :
- Rodent - mouse
- DOSE/DURATION :
- 2 gm/m3
- TOXIC EFFECTS :
- Details of toxic effects not reported other than lethal dose value
- TYPE OF TEST :
- LD50 - Lethal dose, 50 percent kill
- ROUTE OF EXPOSURE :
- Intraperitoneal
- SPECIES OBSERVED :
- Rodent - mouse
- DOSE/DURATION :
- 4500 mg/kg
- TOXIC EFFECTS :
- Details of toxic effects not reported other than lethal dose value
- TYPE OF TEST :
- LD - Lethal dose
- ROUTE OF EXPOSURE :
- Oral
- SPECIES OBSERVED :
- Mammal - dog
- DOSE/DURATION :
- >2500 mg/kg
- TOXIC EFFECTS :
- Gastrointestinal - nausea or vomiting
- TYPE OF TEST :
- LD50 - Lethal dose, 50 percent kill
- ROUTE OF EXPOSURE :
- Oral
- SPECIES OBSERVED :
- Rodent - rabbit
- DOSE/DURATION :
- 800 mg/kg
- TOXIC EFFECTS :
- Details of toxic effects not reported other than lethal dose value
- TYPE OF TEST :
- LD - Lethal dose
- ROUTE OF EXPOSURE :
- Administration onto the skin
- SPECIES OBSERVED :
- Rodent - rabbit
- DOSE/DURATION :
- >4 gm/kg
- TOXIC EFFECTS :
- Details of toxic effects not reported other than lethal dose value
- TYPE OF TEST :
- TDLo - Lowest published toxic dose
- ROUTE OF EXPOSURE :
- Oral
- SPECIES OBSERVED :
- Rodent - rat
- DOSE/DURATION :
- 11250 mg/kg/90D-C
- TOXIC EFFECTS :
- Liver - changes in liver weight Kidney, Ureter, Bladder - changes in bladder weight Nutritional and Gross Metabolic - weight loss or decreased weight gain
- TYPE OF TEST :
- TDLo - Lowest published toxic dose
- ROUTE OF EXPOSURE :
- Oral
- SPECIES OBSERVED :
- Rodent - mouse
- DOSE/DURATION :
- 13650 mg/kg/13W-I
- TOXIC EFFECTS :
- Liver - changes in liver weight
- TYPE OF TEST :
- TDLo - Lowest published toxic dose
- ROUTE OF EXPOSURE :
- Oral
- SPECIES OBSERVED :
- Rodent - mouse
- DOSE/DURATION :
- 135 gm/kg/77W-C
- TOXIC EFFECTS :
- Tumorigenic - Carcinogenic by RTECS criteria Lungs, Thorax, or Respiration - tumors Liver - tumors
- TYPE OF TEST :
- TDLo - Lowest published toxic dose
- ROUTE OF EXPOSURE :
- Oral
- DOSE :
- 5 gm/kg
- SEX/DURATION :
- female 7-16 day(s) after conception
- TOXIC EFFECTS :
- Reproductive - Specific Developmental Abnormalities - craniofacial (including nose and tongue) Reproductive - Specific Developmental Abnormalities - musculoskeletal system Reproductive - Effects on Embryo or Fetus - fetal death
- TYPE OF TEST :
- TDLo - Lowest published toxic dose
- ROUTE OF EXPOSURE :
- Oral
- DOSE :
- 1935 mg/kg
- SEX/DURATION :
- female 6-14 day(s) after conception
- TOXIC EFFECTS :
- Reproductive - Effects on Embryo or Fetus - extra-embryonic structures (e.g., placenta, umbilical cord) Reproductive - Specific Developmental Abnormalities - eye/ear Reproductive - Specific Developmental Abnormalities - urogenital system
- TYPE OF TEST :
- TDLo - Lowest published toxic dose
- ROUTE OF EXPOSURE :
- Oral
- DOSE :
- 4176 mg/kg
- SEX/DURATION :
- female 6-10 day(s) after conception
- TOXIC EFFECTS :
- Reproductive - Effects on Embryo or Fetus - fetotoxicity (except death, e.g., stunted fetus) Reproductive - Specific Developmental Abnormalities - Central Nervous System Reproductive - Specific Developmental Abnormalities - craniofacial (including nose and tongue)
- TYPE OF TEST :
- TDLo - Lowest published toxic dose
- ROUTE OF EXPOSURE :
- Oral
- DOSE :
- 4176 mg/kg
- SEX/DURATION :
- female 6-14 day(s) after conception
- TOXIC EFFECTS :
- Reproductive - Fertility - litter size (e.g. # fetuses per litter; measured before birth)
MUTATION DATA
- TYPE OF TEST :
- Cytogenetic analysis
- TEST SYSTEM :
- Rodent - hamster Ovary
- DOSE/DURATION :
- 7500 ug/L
- REFERENCE :
- EMMUEG Environmental and Molecular Mutagenesis. (Alan R. Liss, Inc., 41 E. 11th St., New York, NY 10003) V.10- 1987- Volume(issue)/page/year: 10(Suppl 10),1,1987 *** REVIEWS *** ACGIH TLV-Not classifiable as a human carcinogen DTLVS* The Threshold Limit Values (TLVs) and Biological Exposure Indices (BEIs) booklet issues by American Conference of Governmental Industrial Hygienists (ACGIH), Cincinnati, OH, 1996 Volume(issue)/page/year: TLV/BEI,1997 ACGIH TLV-TWA 0.5 mg/m3 DTLVS* The Threshold Limit Values (TLVs) and Biological Exposure Indices (BEIs) booklet issues by American Conference of Governmental Industrial Hygienists (ACGIH), Cincinnati, OH, 1996 Volume(issue)/page/year: TLV/BEI,1997 IARC Cancer Review:Animal Limited Evidence IMEMDT IARC Monographs on the Evaluation of Carcinogenic Risk of Chemicals to Man. (WHO Publications Centre USA, 49 Sheridan Ave., Albany, NY 12210) V.1- 1972- Volume(issue)/page/year: 5,211,1974 IARC Cancer Review:Human No Adequate Data IMEMDT IARC Monographs on the Evaluation of Carcinogenic Risk of Chemicals to Man. (WHO Publications Centre USA, 49 Sheridan Ave., Albany, NY 12210) V.1- 1972- Volume(issue)/page/year: 5,211,1974 IARC Cancer Review:Group 3 IMSUDL IARC Monographs, Supplement. (WHO Publications Centre USA, 49 Sheridan Ave., Albany, NY 12210) No.1- 1979- Volume(issue)/page/year: 7,56,1987 TOXICOLOGY REVIEW RREVAH Residue Reviews. (Springer-Verlag New York, Inc., Service Center, 44 Hartz Way, Secaucus, NJ 07094) V.1- 1962- Volume(issue)/page/year: 56,107,1975 TOXICOLOGY REVIEW 85CVA2 "Oncology 1970, Proceedings of the Tenth International Cancer Congress," Chicago, Year Book Medical Pub., 1971 Volume(issue)/page/year: 5,250,1970 *** U.S. STANDARDS AND REGULATIONS *** EPA FIFRA 1988 PESTICIDE SUBJECT TO REGISTRATION OR RE-REGISTRATION FEREAC Federal Register. (U.S. Government Printing Office, Supt. of Documents, Washington, DC 20402) V.1- 1936- Volume(issue)/page/year: 54,7740,1989 *** NIOSH STANDARDS DEVELOPMENT AND SURVEILLANCE DATA *** NIOSH OCCUPATIONAL EXPOSURE SURVEY DATA : NOHS - National Occupational Hazard Survey (1974) NOHS Hazard Code - M0806 No. of Facilities: 18 (estimated) No. of Industries: 1 No. of Occupations: 1 No. of Employees: 18 (estimated) NOES - National Occupational Exposure Survey (1983) NOES Hazard Code - M0806 No. of Facilities: 38 (estimated) No. of Industries: 1 No. of Occupations: 2 No. of Employees: 574 (estimated) No. of Female Employees: 77 (estimated)
五氯硝基苯安全信息
[ 符号 ]:
GHS02, GHS06, GHS08, GHS09
[ 信号词 ]:
Danger
[ 危害声明 ]:
H225-H301 + H311 + H331-H370-H411
[ 警示性声明 ]:
P210-P260-P273-P280-P301 + P310-P311
[ 个人防护装备 ]:
dust mask type N95 (US);Eyeshields;Faceshields;Gloves
[ 危害码 (欧洲) ]:
Xi:Irritant;N:Dangerousfortheenvironment;
[ 风险声明 (欧洲) ]:
R43;R50/53
[ 安全声明 (欧洲) ]:
S13-S24-S37-S60-S61-S45-S36/37
[ 危险品运输编码 ]:
UN 3077 9/PG 3
[ WGK德国 ]:
2
[ RTECS号 ]:
DA6650000
[ 危险类别 ]:
9.0
[ 海关编码 ]:
2904909013
五氯硝基苯合成路线
五氯硝基苯上下游产品
五氯硝基苯上游产品
五氯硝基苯下游产品
五氯硝基苯制备
以碘为催化剂、氯磺酸为溶剂，将2,4,5-三氯硝基苯与氯气在80-85℃反应。溶剂氯磺酸的用量为三氯硝基苯重量的1-3倍，碘用量为三氯硝基苯重量的0.2-0.3%，通氯至过量1%。然后冷至30℃，滤出五氯硝基苯，用80-90℃热水洗至中性，70℃下干燥，可得含量98-99%的产品，收率94%。而2,4,5-三氯硝基苯是由1,2,4三氯苯硝化得到的。上述方法耗用碘和氯磺酸，设备易腐蚀，另一种生产方法是采用由六六六无毒体得到的三氯苯埋接硝化、氯化，可得到氯硝基苯含量大于70%的原粉。
1,2,4-三氯苯经硝化，得三氯硝基苯。再以氯磺酸为溶剂，碘为催化剂，于80～85℃通氯，氯化后制得五氯硝基苯。五氯硝基苯海关
[ 海关编码 ]: 2904909013
[ 中文概述 ]:
2904909013 五氯硝基苯。监管条件:S(进出口农药登记证明)。增值税率:17.0%。退税率:0.0%。最低关税:5.5%。普通关税:30.0%
[ 申报要素 ]: 品名, 成分含量, 用途
[ 监管条件 ]: S.进出口农药登记证明
[ Summary ]:
2904909013 1,2,3,4,5-pentachloro-6-nitrobenzene。supervision conditions:s(import or export registration certificate for pesticides)。VAT:17.0%。tax rebate rate:0.0%。MFN tarrif:5.5%。general tariff:30.0%
五氯硝基苯文献
Sci. Total Environ. 505 , 1142-7, (2014)
The application of greenhouse vegetable cultivation has dramatically expanded worldwide during the last several decades. However, little information is available on the distribution and uptake of pest...
Fusarium verticillioides: evaluation of fumonisin production and effect of fungicides on in vitro inhibition of mycelial growth.Mycopathologia 171 , 77-84, (2011)
The objectives of this study were to evaluate the fumonisin production by 16 F. verticillioides strains on corn cultures and the effect of quintozene and fludioxonil + metalaxyl-M fungicides on "in vi...
Effect of waxy (Low Amylose) on Fungal Infection of Sorghum Grain.Phytopathology 105 , 786-96, (2015)
Loss of function mutations in waxy, encoding granule bound starch synthase (GBSS) that synthesizes amylose, results in starch granules containing mostly amylopectin. Low amylose grain with altered sta...
相关化工产品/化学物质：
推荐生产厂家/供应商：
公司名：上海化源世纪贸易有限公司
区域：上海市普陀区
价格：
联系人：徐经理
产品详情：五氯硝基苯
公司名：上海吉至生化科技有限公司
区域：上海市奉贤区
价格：
￥178.0/25g
￥348.0/100g
联系人：刘佳
产品详情：五氯硝基苯
公司名：上海阿拉丁生化科技股份有限公司
区域：上海市浦东新区
价格：
￥需询单/1mg
￥需询单/1g
￥需询单/1g
￥需询单/1g
联系人：阿拉丁
产品详情：甲醇中五氯硝基苯溶液
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相关化合物
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