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2-乙酰基环己酮

2-乙酰基环己酮用途

1.有机合成。

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2-乙酰基环己酮名称

[ CAS 号 ]:
874-23-7

[ 中文名 ]:
2-乙酰基环己酮

[ 英文名 ]:
2-Acetylcyclohexanone

[中文别名 ]:

2-乙酰基环已酮

[英文别名 ]:

2-Acetylcyclohexanone
2-acetylcyclohexanone for synthesis
2-Acetyl-1-cyclohexanone
2-acetylcyclohexa
2-acetyl cyclohexanone
Cyclohexanone, 2-acetyl-
MFCD00001633
EINECS 212-858-5
cyclohexanone,2-acetyl-
2-acetylcyclohexanon

2-乙酰基环己酮物理化学性质

[ 密度 ]:
1.0±0.1 g/cm3

[ 沸点 ]:
224.3±0.0 °C at 760 mmHg

[ 分子式 ]:
C₈H₁₂O₂

[ 分子量 ]:
140.180

[ 闪点 ]:
79.4±0.0 °C

[ 精确质量 ]:
140.083725

[ PSA ]:
34.14000

[ LogP ]:
0.08

[ 外观性状 ]:
无色至淡黄色液体

[ 蒸汽压 ]:
0.1±0.4 mmHg at 25°C

[ 折射率 ]:
1.464

[ 储存条件 ]:
存放于惰性气体之中;避免空气

2-乙酰基环己酮MSDS

2-乙酰基环己酮安全信息

[ 个人防护装备 ]:
Eyeshields;Gloves;half-mask respirator (US);multi-purpose combination respirator cartridge (US)

[ 安全声明 (欧洲) ]:
S23-S24/25

[ 危险品运输编码 ]:
NONH for all modes of transport

[ WGK德国 ]:
3

[ 海关编码 ]:
2914299000

2-乙酰基环己酮合成路线

2-乙酰基环己酮上下游产品

2-乙酰基环己酮上游产品

2-乙酰基环己酮下游产品

2-乙酰基环己酮海关

[ 海关编码 ]: 2914299000

[ 中文概述 ]:
2914299000. 其他不含其他含氧基的环烷酮、环烯酮或环萜烯酮. 增值税率:17.0%. 退税率:13.0%. 监管条件:无. 最惠国关税:5.5%. 普通关税:30.0%

[ 申报要素 ]: 品名, 成分含量, 用途, 丙酮报明包装

[ Summary ]:
2914299000. other cyclanic, cyclenic or cyclotherpenic ketones without other oxygen function. VAT:17.0%. Tax rebate rate:13.0%. . MFN tariff:5.5%. General tariff:30.0%

2-乙酰基环己酮文献

Tautomerization of 2-acetylcyclohexanone. 1. Characterization of keto-enol/enolate equilibria and reaction rates in water.

J. Org. Chem. 68(7) , 2680-8, (2003)

The keto-enol tautomerism of 2-acetylcyclohexanone (ACHE) was studied in water under different experimental conditions. By contrast with other previously studied beta-diketones, the keto-enol intercon...

Copper-catalyzed amination of (bromophenyl)ethanolamine for a concise synthesis of aniline-containing analogues of NMDA NR2B antagonist ifenprodil.

Org. Biomol. Chem. 8(5) , 1111-20, (2010)

An operationally simple and concise synthesis of anilinoethanolamines, as NMDA NR2B receptor antagonist ifenprodil analogues, was developed via a copper-catalyzed amination of the corresponding bromoa...

An alternative to the classical α-arylation: the transfer of an intact 2-iodoaryl from ArI(O₂CCF₃)₂.

Angew. Chem. Int. Ed. Engl. 53(42) , 11298-301, (2014)

The α-arylation of carbonyl compounds is generally accomplished under basic conditions, both under metal catalysis and via aryl transfer from the diaryl λ(3)-iodanes. Here, we describe an alternative ...

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