三氯乙酰基异氰酸酯结构式
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常用名 | 三氯乙酰基异氰酸酯 | 英文名 | Trichloroacetyl isocyanate |
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CAS号 | 3019-71-4 | 分子量 | 188.397 | |
密度 | 1.7±0.1 g/cm3 | 沸点 | 186.0±35.0 °C at 760 mmHg | |
分子式 | C3Cl3NO2 | 熔点 | N/A | |
MSDS | 中文版 美版 | 闪点 | 65.6±0.0 °C | |
符号 |
GHS05, GHS06, GHS08 |
信号词 | Danger |
Potential scans and potential energy distributions of normal vibrational modes of trichloroacetyl isocyanate.
J. Mol. Model. 8(2) , 44-9, (2002) The conformational stability and vibrational infrared and Raman spectra of trichloroacetyl isocyanate (CCl3CONCO) were investigated by ab initio MP2 and density functional B3LYP calculations using the 6-311++G** basis set. From the potential energy scans of t... |
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Improved catalytic and stereoselective glycosylation with glycosyl N-trichloroacetylcarbamate: application to various 1-hydroxy sugars.
Carbohydr. Res. 345(6) , 740-9, (2010) Efficient catalytic and stereoselective glycosylation was achieved by activating a glycosyl N-trichloroacetylcarbamate with a catalytic amount of Lewis acid in the presence of a glycosyl acceptor and 5A molecular sieves. Catalytic one-pot dehydrative glycosyl... |
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D.R. Taylor
Can. J. Chem. 54 , 189, (1976)
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M. Budesinsky et al.
Collect. Czech. Chem. Commun. 45 , 2784, (1980)
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H. Fujiwara, A.K. Bose
Pract. Spectrosc. 3 , 329, (1980)
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Determination of chain branching in epoxy resins by nuclear magnetic resonance spectrometry.
Anal. Chem. 44 , 837, (1972)
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Total synthesis of the antimitotic marine macrolide (-)-leiodermatolide.
Angew. Chem. Int. Ed. Engl. 53(10) , 2692-5, (2014) Leiodermatolide is an antimitotic macrolide isolated from the marine sponge Leiodermatium sp. whose potentially novel tubulin-targeting mechanism of action makes it an exciting lead for anticancer drug discovery. In pursuit of a sustainable supply, we report ... |
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Tetrahedron Lett. 48 , 65, (2007)
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NMR spectral studies-XII: Trichloroacetyl isocyanate as an in situ derivatizing reagent for 13C NMR spectroscopy of alcohols, phenols and amines. Bose AK and Srinivasan PR.
Tetrahedron 31(24) , 3025-29, (1975)
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[2+ 2] Cycloaddition of trichloroacetyl isocyanate to glycals. Chmielewski M and Kaluza Z.
Carbohydr. Res. 167 , 143-52, (1987)
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