钯结构式
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常用名 | 钯 | 英文名 | Palladium |
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CAS号 | 7440-05-3 | 分子量 | 106.420 | |
密度 | 1.025 g/mL at 25 °C | 沸点 | 2970 °C(lit.) | |
分子式 | Pd | 熔点 | 1554 °C(lit.) | |
MSDS | 中文版 美版 | 闪点 | N/A | |
符号 |
GHS02, GHS07 |
信号词 | Danger |
Solar energy assisted starch-stabilized palladium nanoparticles and their application in C-C coupling reactions.
J. Nanosci. Nanotechnol. 13(7) , 5061-8, (2013) Present work reports a novel one step, greener protocol for the synthesis of starch-stabilized palladium nanoparticles (PdNPs) with an average particle diameter of 30-40 nm. These particles were stable and uniform in size. In present protocol, the concentrate... |
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A new deposition method for the preparation of Pt-Pd nanocatalysts on a nafion coated carbon black via the reduction of metallic precursors in a drying process.
J. Nanosci. Nanotechnol. 13(5) , 3634-7, (2013) A simple method for the synthesis of Pt-Pd nanocatalysts was developed for a proton-exchange membrane fuel cell (PEMFC), which was loaded on a nafion coated carbon black via the sequential reduction of palladium(II) bis(acetylacetonato) and platinum(II) bis(a... |
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Reduction procedure effect on the electrochemical properties of conductive carbon black supported Pt-Pd electrocatalysts.
J. Nanosci. Nanotechnol. 13(3) , 2213-7, (2013) Conductive carbon black supported Pt-Pd nanocomposites were prepared to study a difference of simultaneously and sequentially reduced Pt-Pd nanocomposites using polyol method. The concentration of Pt-Pd alloyed metals on carbon blacks (CB) was adjusted to 20 ... |
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Platinum and palladium nano-structured catalysts for polymer electrolyte fuel cells and direct methanol fuel cells.
J. Nanosci. Nanotechnol. 13(7) , 4799-824, (2013) In this review, we present the synthesis and characterization of Pt, Pd, Pt based bimetallic and multi-metallic nanoparticles with mixture, alloy and core-shell structure for nano-catalysis, energy conversion, and fuel cells. Here, Pt and Pd nanoparticles wit... |
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Solid-phase extraction in the determination of gold, palladium, and platinum.
J. Sep. Sci. 35(10-11) , 1249-65, (2012) A simple classification of various sorbents and solid-phase extraction procedures used for preconcentration of trace levels of Au, Pd, and Pt from different sample types is proposed in this review article. The large variety of available sorbents/procedures ha... |
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[Comparative studies on the genotoxic activity of a new palladium (II) acidocomplex vs cisplatin in human blood lymphocytes in vitro].
Biomed. Khim. 59(1) , 107-14, (2013) A comparative study on the genotoxic activity of cisplatin versus morfozol, the first representative of a new class of cation-anion complexes of palladium [AH]2[PdCl4] (where A-methylmorpholine) has been performed using human lymphocytes in vitro. The results... |
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Methane catalytic combustion on Pd9/gamma-Al2O3 with different degrees of Pd oxidation.
Chimia 67(4) , 271-4, (2013) This research is focused on the analysis of adsorbed CH4 intermediates at oxidized Pd9 nanoparticles supported on gamma-alumina. From first-principle density functional theory (DFT) calculations, several configurations, charge transfer and electronic density ... |
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Cobryketone derived from vitamin B12 via palladium-catalyzed cleavage of the sp3-sp3 carbon-carbon bond.
J. Org. Chem. 78(8) , 4115-22, (2013) Heptamethyl cobyrinate was transformed into hexamethyl 8-nor-cobyrinate. The crucial step involved the synthesis of new, vitamin B12 derived cobryketone via palladium-catalyzed cleavage of the sp(3)-sp(3) carbon-carbon bond with the liberation of the ketone. ... |
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Synthesis of heterocyclic compounds through palladium-catalyzed C-H cyclization processes.
Chem. Pharm. Bull. 61(10) , 987-96, (2013) Herein, we describe our development of synthetic methods for heterocyclic compounds based on the palladium-catalyzed carbon-hydrogen bond (C-H) functionalization/intramolecular carbon-heteroatom (nitrogen or sulfur) bond formation process. By this C-H cycliza... |
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Interplay between superconductivity and magnetism in Fe(1-x)Pd(x)Te.
Proc. Natl. Acad. Sci. U. S. A. 110(23) , 9283-8, (2013) The attractive/repulsive relationship between superconductivity and magnetic ordering has fascinated the condensed matter physics community for a century. In the early days, magnetic impurities doped into a superconductor were found to quickly suppress superc... |