8-溴喹啉结构式
|
常用名 | 8-溴喹啉 | 英文名 | 8-Bromoquinoline |
---|---|---|---|---|
CAS号 | 16567-18-3 | 分子量 | 208.055 | |
密度 | 1.6±0.1 g/cm3 | 沸点 | 303.0±0.0 °C at 760 mmHg | |
分子式 | C9H6BrN | 熔点 | 58-59 °C | |
MSDS | 中文版 美版 | 闪点 | 132.8±19.8 °C | |
符号 |
GHS07 |
信号词 | Warning |
Reactivity of the bifunctional ambiphilic molecule 8-(dimesitylboryl)quinoline: hydrolysis and coordination to Cu(I), Ag(I) and Pd(II).
Dalton Trans. 39(45) , 11081-90, (2010) The ambiphilic molecule 8-(dimesitylboryl)quinoline (1) was synthesized by treatment of 8-bromoquinoline or 8-iodoquinoline with n-BuLi followed by dimesitylboronfluoride. Hydrolysis of 1 is unusually rapid compared to bulky triorganoboranes with the sequenti... |
|
Direct synthesis of tricyclic 5H-pyrido[3,2,1-ij]quinolin-3-one by domino palladium catalyzed reaction.
Org. Biomol. Chem. 4(20) , 3760-2, (2006) Unexpectedly, the palladium catalyzed coupling reaction of acrolein with 8-bromoquinoline gave 5H-pyrido[3,2,1-ij]quinolin-3-one in a single step. |
|
Facile synthesis of 8-substituted quinolines. Suggs JW and Pearson GDN.
J. Org. Chem. 45(8) , 1514-15, (1980)
|
|
Synthesis and coordination behaviour of the new (8-quinolyl) cyclopentadienyl ligand. Enders M, et al.
J. Organomet. Chem. 622(1) , 66-73, (2001)
|
|
Synthesis of n, n'-biquinolines by a coupling reaction of bromoquinolines using organonickel (0) complexes. Benito Y, et al.
Appl. Organomet. Chem. 1(6) , 535-40, (1987)
|
|
Direct heteroarylation of 5-bromothiophen-2-ylpyridine and of 8-bromoquinoline via palladium-catalysed C-H bond activation: simpler access to heteroarylated nitrogen-based derivatives. Laroche J, et al.
Catal. Sci. Tech. 3(8) , 2072-2080, (2013)
|