硒氰酸钾

硒氰酸钾结构式
硒氰酸钾结构式
品牌特惠专场
常用名 硒氰酸钾 英文名 Potassium selenocyanate
CAS号 3425-46-5 分子量 144.076
密度 2.347 沸点 134.2ºC at 760 mmHg
分子式 CKNSe 熔点 147 °C
MSDS 中文版 美版 闪点 35ºC
符号 GHS06 GHS08 GHS09
GHS06, GHS08, GHS09
信号词 Danger

Synthesis of unnatural selenocystines and beta-aminodiselenides via regioselective ring-opening of sulfamidates using a sequential, one-pot, multistep strategy.

J. Org. Chem. 75(9) , 2910-21, (2010)

A variety of N-alkyl-beta-aminodiselenides have been synthesized in high yield from sulfamidates under mild reaction conditions using potassium selenocyanate and benzyltriethylammonium tetrathiomolybdate ([BnNEt(3)](2)MoS(4)) in a sequential, one-pot, multist...

Nutritional availability and chronic toxicity of selenocyanate in the rat.

J. Nutr. 118(6) , 718-22, (1988)

To evaluate nutritional availability and chronic toxicity of KSeCN, female postweanling rats were fed casein-based diets plus 0.1, 0.5, 2.5, 5 and 10 mg Se/kg as KSeCN for 6 wk, or 0.1, 0.5 and 10 mg Se/kg as Na2SeO3. A control group was fed the basal diet (S...

Selenium assimilation and volatilization from selenocyanate-treated Indian mustard and muskgrass.

Plant Physiol. 128(2) , 625-33, (2002)

Selenocyanate (SeCN(-)) is a major contaminant in the effluents from some oil refineries, power plants, and in mine drainage water. In this study, we determined the potential of Indian mustard (Brassica juncea) and muskgrass (a macroalga, Chara canescens) for...

Production and release of selenocyanate by different green freshwater algae in environmental and laboratory samples.

Environ. Sci. Technol. 46(11) , 5867-75, (2012)

In a previous study, selenocyanate was tentatively identified as a biotransformation product when green algae were exposed to environmentally relevant concentrations of selenate. In this follow-up study, we confirm conclusively the presence of selenocyanate i...

Phenylalkyl isoselenocyanates vs phenylalkyl isothiocyanates: thiol reactivity and its implications.

Chem. Biol. Interact. 200(1) , 28-37, (2012)

Phenylalkyl isoselenocyanate (ISC) compounds were recently designed in our laboratory by incorporating the anticancer element selenium into a panel of phenylalkyl isothiocyanates (ITCs), known to have anticancer properties. A structural activity investigation...

Production of dimethyl triselenide and dimethyl diselenenyl sulfide in the headspace of metalloid-resistant Bacillus species grown in the presence of selenium oxyanions.

Anal. Biochem. 396(2) , 217-22, (2010)

A Bacillus species harvested from the environment is metalloid resistant and, when grown anaerobically in complex growth medium and amended with the selenium oxyanion selenate, selenite, or selenocyanate, produces volatile organoselenium compounds in bacteria...

Metabolism of selenocyanate in the rat.

Arch. Biochem. Biophys. 258(1) , 1-6, (1987)

Rats injected subcutaneously with 2 mg Se/kg body weight of [75Se]selenocyanate or [14C, 75Se]selenocyanate excreted dimethylselenide (DMSe) in the breath and trimethyl-selenonium ion (TMSe) in the urine. The 24-h respiratory DMSe and urinary TMSe excretions ...

Synthesis and biological evaluation of novel spiro 6-methoxytetralin-1,3'-pyrrolidine based organoselenocyanates against cadmium-induced oxidative and hepatic damage in mice.

Eur. J. Med. Chem. 45(8) , 3265-73, (2010)

A series of novel organoselenocyanate compounds (6a-d) having spiro[tetralin-1,3'-pyrrolidine] moiety were synthesized. The compounds were evaluated for their inhibitory activity against cadmium- (Cd) induced toxicity in Swiss Albino mice. All the compounds (...

Capillary electrophoretic determination of selenocyanate and selenium and tellurium oxyanions in bacterial cultures.

Anal. Biochem. 364(2) , 138-44, (2007)

A simple capillary zone electrophoretic method for the determination of biospherically important oxyanions of selenium (Se) and tellurium and another Se-containing anion, selenocyanate, has been developed. The method uses direct UV absorption detection. Time ...

No-carrier-added synthesis of aliphatic and aromatic radioselenoethers via selenocyanates.

Nucl. Med. Biol. 30(4) , 361-7, (2003)

Various aliphatic and aromatic [(75)Se]selenoethers were prepared at the no-carrier-added (n.c.a.) level using a new radiosynthetic pathway, based on the formation of alkyl[(75)Se]selenocyanates as intermediates. Using one-pot model reactions of elemental (75...