3-炔基-2-丁酮
3-炔基-2-丁酮结构式
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常用名 | 3-炔基-2-丁酮 | 英文名 | 3-Butyn-2-one |
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| CAS号 | 1423-60-5 | 分子量 | 68.074 | |
| 密度 | 0.87 | 沸点 | 85 ºC | |
| 分子式 | C4H4O | 熔点 | N/A | |
| MSDS | 美版 | 闪点 | -1.1±0.0 °C | |
| 符号 |
GHS02, GHS06 |
信号词 | Danger |
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Short total syntheses of both the putative and actual structures of the clerodane diterpenoid (+/-)-sacacarin by double annulation.
Org. Lett. 3(25) , 4027-30, (2001) [reaction: see text] The putative structure of the naturally occurring clerodane diterpenoid (+/-)-sacacarin has been prepared in only 10 steps, six of which are C-C bond-forming steps, in a chemo-, regio-, and diastereoselective manner. The key part of the s... |
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A heterocycle-forming double michael reaction. [5 + 1] annulation route to highly substituted and functionalized piperidines.
Org. Lett. 3(18) , 2911-4, (2001) [reaction: see text]. Nitrogen-containing tethered diacids, easily prepared by reductive alkylation of diethyl aminomalonate or ethyl cyanoglycinate, undergo double Michael reactions with 3-butyn-2-one to give highly functionalized and substituted piperidines... |
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Chiral aminophosphines as catalysts for enantioselective double-Michael indoline syntheses.
Molecules 17(5) , 5626-50, (2012) The bisphosphine-catalyzed double-Michael addition of dinucleophiles to electron-deficient acetylenes is an efficient process for the synthesis of many nitrogen-containing heterocycles. Because the resulting heterocycles contain at least one stereogenic cente... |
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Synlett , 809, (2007)
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