2,3-二氢呋喃

2,3-二氢呋喃结构式
2,3-二氢呋喃结构式
品牌特惠专场
常用名 2,3-二氢呋喃 英文名 2,3-DHF
CAS号 1191-99-7 分子量 70.090
密度 1.0±0.1 g/cm3 沸点 54.5±0.0 °C at 760 mmHg
分子式 C4H6O 熔点 N/A
MSDS 中文版 美版 闪点 -24.4±0.0 °C
符号 GHS02
GHS02
信号词 Danger

An integrated microreactor system for self-optimization of a Heck reaction: from micro- to mesoscale flow systems.

Angew. Chem. Int. Ed. Engl. 49(39) , 7076-80, (2010)

A gold(I)-catalyzed intramolecular reaction of propargylic/homopropargylic alcohols with oxirane.

Chemistry 14(23) , 7011-8, (2008)

The gold(I)-catalyzed cycloisomerization of epoxy alkynes in the presence of a nucleophile is an efficient protocol to provide ketal skeletons with high stereoselectivity. An intramolecular reaction of propargylic/homopropargylic alcohols with oxirane to prod...

Short, enantioselective total synthesis of aflatoxin B2 using an asymmetric [3+2]-cycloaddition step.

J. Am. Chem. Soc. 127(34) , 11958-9, (2005)

A highly enantioselective [3+2]-cycloaddition reaction of 2,3-dihydrofuran with 1,4-benzoquinones using a chiral oxazaborolidinium triflimidate as catalyst has been developed which allows rapid access to a variety of chiral phenolic tricycles (enantiomeric ex...

Phosphine-catalyzed domino reaction for the synthesis of conjugated 2,3-dihydrofurans from allenoates and Nazarov reagents.

Chem. Asian J. 7(7) , 1533-7, (2012)

A new domino reaction for Nazarov reagents: An efficient approach was developed for the construction of highly functionalized conjugated 2,3-dihydrofuran skeletons. Nazarov reagents were used for the first time in a phosphine-catalyzed domino reaction and suc...

First successful application of diphosphite ligands in the asymmetric hydroformylation of dihydrofurans.

Chem. Commun. (Camb.) (9) , 1221-3, (2005)

Good enantioselectivities and excellent regioselectivities are achieved in the Rh-catalyzed asymmetric hydroformylation of 2,5- and 2,3-dihydrofuran using diphosphite ligands; whereby the backbone of the ligand is crucial to suppressing isomerization and obta...

An efficient carbonyl-alkene metathesis of bicyclic oxetanes: photoinduced electron transfer reduction of the Paternò-Büchi adducts from 2,3-dihydrofuran and aromatic aldehydes.

Photochem. Photobiol. Sci. 5(1) , 51-5, (2006)

The bicyclic oxetanes and resulting from photocycloaddition of aromatic aldehydes to 2,3-dihydrofuran, were efficiently cleaved by means of electron-transfer reduction, photoinduced by the electronically excited reductants 1-methoxynaphthalene (MN) and 2,7-di...

Novel synthesis of cholesterol analogs: condensation of pregnenolone with dihydropyran or dihydrofuran.

Steroids 56(9) , 458-63, (1991)

Pregnenolone 3-(2'-tetrahydropyranyl) ether (1) was condensed with 3,4-[2H]dihydropyran to mainly give (20R)-[6'-(3',4'-[2'H]dihydropyranyl)]-pregn-5-ene-3 beta,20-diol 3-(2'-tetrahydropyranyl) ether (20R-3), according to nuclear magnetic resonance (NMR). Col...

Palladium-catalyzed asymmetric Heck arylation of 2,3-dihydrofuran--effect of prolinate salts.

Dalton Trans. 42(4) , 1215-22, (2013)

Chiral ionic liquids (CILs) containing L-prolinate and L-lactate anions and non-chiral quaternary ammonium cations were employed in the palladium catalyzed enantioselective Heck arylation of 2,3-dihydrofuran with aryl iodides (iodobenzene, 4-iodotoluene, 2-io...

Adsorption and reactivity of 2,3-dihydrofuran and 2,5-dihydrofuran on Pd(111): influence of the C=C position on the reactivity of cyclic ethers.

Langmuir 26(16) , 13320-32, (2010)

High-resolution electron energy loss spectroscopy (HREELS) and temperature-programmed desorption (TPD) were used to study the adsorption and thermal chemistry of 2,3-dihydrofuran (2,3-DHF) and 2,5-dihydrofuran (2,5-DHF) on Pd(111). The results, paired with ea...

Streptococcus agalactiae in the environment of bovine dairy herds--rewriting the textbooks?

Vet. Microbiol. 184 , 64-72, (2016)

Many free-stall bovine dairy herds in Norway fail to eradicate Streptococcus agalactiae despite long-term control measures. In a longitudinal study of 4 free-stall herds with automatic milking systems (AMS), milk and extramammary sites were sampled 4 times wi...