氯甲酸甲酯

一般危化品
氯甲酸甲酯结构式
氯甲酸甲酯结构式
常用名 氯甲酸甲酯 英文名 Methyl chloroformate
CAS号 79-22-1 分子量 94.497
密度 1.2±0.1 g/cm3 沸点 71.0±0.0 °C at 760 mmHg
分子式 C2H3ClO2 熔点 -61°C
MSDS 中文版 美版 闪点 17.8±0.0 °C
符号 GHS02 GHS05 GHS06
GHS02, GHS05, GHS06
信号词 Danger

Ibuprofen-in-cyclodextrin-in-W/O/W emulsion - Improving the initial and long-term encapsulation efficiency of a model active ingredient.

Int. J. Pharm. 487 , 1-7, (2015)

A challenge in formulating water-in-oil-in-water (W/O/W) emulsions is the uncontrolled release of the encapsulated compound prior to application. Pharmaceuticals and nutraceuticals usually have amphipathic nature, which may contribute to leakage of the active...

A new analytical method to determine non-steroidal anti-inflammatory drugs in surface water using in situ derivatization combined with ultrasound-assisted emulsification microextraction followed by gas chromatography-mass spectrometry.

Talanta 129 , 552-9, (2014)

Because of the high stability and potential toxic effects of non-steroidal anti-inflammatory drugs (NSAIDs), it is important to closely monitor their concentrations in the environment using a sensitive analytical method. In this study, a simple, rapid, effici...

Highly sensitive GC/MS/MS method for quantitation of amino and nonamino organic acids.

Anal. Chem. 83(7) , 2705-11, (2011)

Metabolite profiling methods are important tools for measurement of metabolite pools in biological systems. While most metabolite profiling methods report relative intensities or depend on a few internal standards representing all metabolites, the ultimate re...

Determination of octylphenol and nonylphenol in aqueous sample using simultaneous derivatization and dispersive liquid-liquid microextraction followed by gas chromatography-mass spectrometry.

J. Chromatogr. A. 1217(43) , 6762-8, (2010)

A simple and fast sample preparation method for the determination of nonylphenol (NP) and octylphenol (OP) in aqueous samples by simultaneous derivatization and dispersive liquid-liquid microextraction (DLLME) was investigated using gas chromatography-mass sp...

Presence of tetrahydro-beta-carboline-3-carboxylic acids in foods by gas chromatography-mass spectrometry as their N-methoxycarbonyl methyl ester derivatives.

J. Chromatogr. A. 765(2) , 265-77, (1997)

Various tetrahydro-beta-carboline-3-carboxylic acids (TH beta C-3-COOH) are identified in commercial foods and drinks by GC-MS. Positive identification of 1-methyl-1,2,3,4-tetrahydro-beta-carboline-3-carboxylic acid (MTCA) is demonstrated in soy and tabasco s...

A convenient derivatization method for the determination of amphetamine and related drugs in urine.

J. Forensic Sci. 41(1) , 148-51, (1996)

The most commonly abused CNS stimulant in Sweden is amphetamine followed by phenmetrazine. Methamphetamine and phentermine are rarely seen but still of interest. This paper describes a rapid and sensitive method for the analysis of amphetamine, methamphetamin...

Simultaneous extraction and derivatization of amino acids and free fatty acids in meat products.

J. Chromatogr. A. 1241 , 96-102, (2012)

In meat products the contents of free amino acids and free fatty acids are two important parameters used to establish their quality. These compounds play a very important role in defining the sensorial characteristics and acceptability of meat products. An in...

Microscale analysis of amino acids using gas chromatography-mass spectrometry after methyl chloroformate derivatization.

J. Chromatogr. B. Analyt. Technol. Biomed. Life Sci. 878(24) , 2199-208, (2010)

To conduct studies of stable isotope incorporation and dilution in growing plants, a rapid microscale method for determination of amino acid profiles from minute amounts of plant samples was developed. The method involves solid-phase ion exchange followed by ...

Comparison of derivatization and chromatographic methods for GC-MS analysis of amino acid enantiomers in physiological samples.

J. Chromatogr. B. Analyt. Technol. Biomed. Life Sci. 878(15-16) , 1103-12, (2010)

GC-MS analysis of fluorinated and non-fluorinated chloroformate and anhydride derivatives of amino acid (AA) enantiomers on two different chiral columns was compared for the direct quantification of free L- and D-AAs in human serum and urine in a single analy...

Determination of amino acids in selenium-enriched yeast by gas chromatography-mass spectrometry after microwave assisted hydrolysis.

Anal. Chim. Acta 744 , 54-9, (2012)

A simple, rapid microwave digestion procedure for protein hydrolysis preceding the determination of amino acids in yeast using gas chromatography-mass spectrometry (GC-MS) is described. Protein hydrolysis was performed in a focused microwave using 4M methanes...