2,2′,2″,2′′′-(1,2-亚苯基双[(1S,3S)-四氢-5,8-二氧代-1H-[1,2,4]二氮杂磷杂环戊基[1,2-A]哒嗪-2,1,3(3H)-三基])四(N-[(1S)-1-苯乙基])苯甲酰胺结构式
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常用名 | 2,2′,2″,2′′′-(1,2-亚苯基双[(1S,3S)-四氢-5,8-二氧代-1H-[1,2,4]二氮杂磷杂环戊基[1,2-A]哒嗪-2,1,3(3H)-三基])四(N-[(1S)-1-苯乙基])苯甲酰胺 | 英文名 | 2,2',2'',2'''-(1,2-PHENYLENEBIS((1S,3S)& |
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CAS号 | 851770-14-4 | 分子量 | 1311.40000 | |
密度 | N/A | 沸点 | N/A | |
分子式 | C78H72N8O8P2 | 熔点 | 289-299ºC | |
MSDS | 美版 | 闪点 | N/A |
Highly active, regioselective, and enantioselective hydroformylation with Rh catalysts ligated by Bis-3,4-diazaphospholanes.
J. Am. Chem. Soc. 127 , 5040, (2005) Azines made by the reaction of hydrazine with ortho-formylbenzoic acid react with 1,2-diphosphinobenzene and either succinyl chloride or phthaloyl chloride in ca. 30% yield to give rac-bis-3,4-diazaphospholanes bearing benzoic acid groups in the 2 and 5 posit... |
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Highly regio- and enantioselective asymmetric hydroformylation of olefins mediated by 2,5-disubstituted phospholane ligands.
Angew. Chem. Int. Ed. Engl. 44 , 5834, (2005)
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