二氯 二叔丁基-(4-二甲基氨基苯基)磷钯(II)结构式
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常用名 | 二氯 二叔丁基-(4-二甲基氨基苯基)磷钯(II) | 英文名 | BIS(DI-TERT-BUTYL(4-DIMETHYLAMINOPHENYL)PHOSPHINE)DICHLOROPALLADIUM(II) |
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| CAS号 | 887919-35-9 | 分子量 | 708.07 | |
| 密度 | N/A | 沸点 | 349.1ºC at 760 mmHg | |
| 分子式 | C32H56Cl2N2P2Pd | 熔点 | N/A | |
| MSDS | 美版 | 闪点 | 164.9ºC | |
| 符号 |
GHS07 |
信号词 | Warning |
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New air-stable catalysts for general and efficient suzuki-miyaura cross-coupling reactions of heteroaryl chlorides.
Org. Lett. 8 , 1787, (2006) [reaction: see text] New air-stable PdCl(2){P(t)Bu(2)(p-R-Ph)}(2) (R = H, NMe(2), CF(3),) complexes represent simple, general, and efficient catalysts for the Suzuki-Miyaura cross-coupling reactions of aryl halides including five-membered heteroaryl halides a... |
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Zn-mediated, Pd-catalyzed cross-couplings in water at room temperature without prior formation of organozinc reagents.
J. Am. Chem. Soc. 131 , 15592, (2009) Mix in water, stir. That is all that is required in this new approach to sp(3)-sp(2) cross-couplings between an alkyl iodide and an aryl bromide, both potentially bearing functionality. They react under catalysis by Pd(0) in the presence of zinc powder, aided... |