铱粉

Nature Chemistry 5(4) , 300-6, (2013)

The development of hydrogen-based energy sources as viable alternatives to fossil-fuel technologies has revolutionized clean energy production using fuel cells. However, to date, the slow rate of the hydrogen oxidation reaction (HOR) in alkaline environments ...

J. Am. Chem. Soc. 135(10) , 3971-82, (2013)

Si-H activation in triethyl- and triarylsilanes by a square-planar pyridine-diimine iridium complex with a terminal nitrido unit leads to the corresponding silyl amido complexes, which were unambiguously characterized by X-ray crystallography. Based on detail...

Org. Lett. 15(24) , 6170-3, (2013)

The iridium-catalyzed diastereo- and regioselective isomerization of primary allylic alcohols using Crabtree's catalyst or sterically modified analogs is reported. The importance of the size of the substituents on either the substrates or the catalysts has be...

In Vivo 3(4) , 285-93, (1989)

Recent results on the antitumor activity of organometallic compounds of rhodium, iridium, copper and gold are reviewed. Coordination compounds of some organic ligands are also briefly mentioned. The most promising seem to be copper and gold complexes which ex...

Inorg. Chem. 52(7) , 3687-98, (2013)

The synthesis of four novel heteroleptic dipyrrinato complexes [(η(6)-arene)RuCl(2-pcdpm)] (η(6)-arene = C6H6, 1; C10H14, 2) and [(η(5)-C5Me5)MCl(2-pcdpm)] (M = Rh, 3; Ir, 4) containing a new chelating ligand 4-(2-methoxypyridyl)-phenyldipyrromethene (2-pcdpm...

Chem. Soc. Rev. 41(8) , 3264-79, (2012)

This review describes how the incorporation of dicarba-closo-dodecarboranes into half-sandwich complexes of ruthenium, osmium, rhodium and iridium might lead to the development of a new class of compounds with applications in medicine. Such a combination not ...

Dalton Trans. 42(16) , 5655-60, (2013)

The Nδ,Nε-dimethylated histidinium salt (His*) was tethered to oligopeptides and metallated to form Ir(III) and Rh(I) NHC complexes. Peptide-based histidylidene complexes containing only alanine, Ala-Ala-His*-[M] and Ala-Ala-Ala-His*-[M] were synthesised ([M]...

Conf. Proc. IEEE Eng. Med. Biol. Soc. 2012 , 819-22, (2012)

Iridium is one of the main electrode materials for applications like neural stimulation. Iridium has a higher charge injection capacity when activated and transformed into AIROF (activated iridium oxide film) using specific electrical signals. Activation is n...

Conf. Proc. IEEE Eng. Med. Biol. Soc. 2012 , 2788-91, (2012)

Activated Iridium Oxide Film (AIROF) microelectrodes are regarded as advantage for stimulation of neural tissue owing to their superior charge injection capabilities, as compared to other noble-metal based electrodes. Including AIROF electrodes within an impl...

Chem. Commun. (Camb.) 49(31) , 3230-2, (2013)

Five iridium(III) complexes with two N-heterocyclic carbene (NHC) ligands and an ancillary ligand have been designed and successfully synthesized. With multicolor photoluminescence and low toxicity, these carbene complexes were tested, for the first time, as ...