1-甲基哌啶
一般危化品
1-甲基哌啶结构式
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常用名 | 1-甲基哌啶 | 英文名 | 1-Methylpiperidine |
|---|---|---|---|---|
| CAS号 | 626-67-5 | 分子量 | 99.17410 | |
| 密度 | 0.817 g/mL at 20 °C(lit.) | 沸点 | 106-107 °C(lit.) | |
| 分子式 | C6H13N | 熔点 | -50 °C | |
| MSDS | 中文版 美版 | 闪点 | 38 °F | |
| 符号 |
GHS02, GHS05 |
信号词 | Danger |
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Simultaneous determination of perfluorinated compounds and their potential precursors in mussel tissue and fish muscle tissue and liver samples by liquid chromatography-electrospray-tandem mass spectrometry.
J. Chromatogr. A. 1387 , 13-23, (2015) An analytical method for the simultaneous determination in fish liver and muscle tissue and mussel samples of 14 perfluorinated compounds (PFCs), including three perfluoroalkylsulfonates (PFSAs), seven perfluorocarboxylic acids (PFCAs), three perfluorophospho... |
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Self aggregation of supramolecules of nitroxides@cucurbit[8]uril revealed by EPR spectra.
Langmuir 25 , 13820-13832, (2009) Supramolecular complexation behavior of cucurbiturils with paramagnetic nitroxide spin probes was examined by (1)H NMR, X-ray diffraction studies of crystals, computation, and EPR. Both cucurbit[7]uril (CB7) and cucurbit[8]uril (CB8) form a 1:1 complex with 4... |
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Simultaneous determination of perfluoroalkyl phosphonates, carboxylates, and sulfonates in drinking water.
J. Chromatogr. A. 1218(37) , 6388-95, (2011) A trace analytical method based on high performance liquid chromatography coupled to quadrupole time-of-flight high resolution mass spectrometry was developed for simultaneous determination of perfluoroalkyl phosphonates (PFPAs, carbon chain lengths C6,8,10),... |
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[Studies of pyrazine derivatives. XXV. Synthesis and the tuberculostatic activity of the products of reaction of 5-(6-methoxy- and 5-(6 morpholinopyrazinyl)-1,3,4-oxadiazol-2-thione with amines].
Acta Pol. Pharm. 45(5) , 373-9, (1988)
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Synthesis and anti-cancer activity of 2,6-disubstituted N-methylpiperidine derivatives and their N-oxides.
Anticancer Drug Des. 11(6) , 421-38, (1996) Bioreducible anti-tumour agents are prodrugs which are intended to be inactive in normal cells, but are able to undergo metabolic reduction in cancer cells to produce toxic species that can damage biomolecules. A series of N-oxides of heterocyclic aliphatic a... |
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[The mechanism of reverse inhibition of cholinesterases by thionphosphonates].
Izv. Akad. Nauk SSSR Biol. (6) , 926-9, (1988)
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Synthesis, spectroscopic and thermal structural investigations of the charge-transfer complexes formed in the reaction of 1-methylpiperidine with sigma- and pi-acceptors.
Spectrochim. Acta. A. Mol. Biomol. Spectrosc. 75(1) , 134-41, (2010) The reactions of the electron donor 1-methylpiperidine (1MP) with the pi-acceptors 7,7,8,8-tetracyanoquinodimethane (TCNQ), tetracyanoethylene (TCNE), 2,3-dichloro-5,6-dicyano-p-benzoquinone (DDQ), 2,3,5,6-tetrachloro-1,4-benzoquinone (chloranil=CHL) and iodi... |
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Design, synthesis and antitumor activity of 4-aminoquinazoline derivatives targeting VEGFR-2 tyrosine kinase.
Bioorg. Med. Chem. Lett. 22 , 110-4, (2012) We report herein the design and synthesis of novel 4-aminoquinazoline derivatives based on the inhibitors of VEGFR-2 tyrosine kinases. The VEGFR-2 inhibitory activities of these newly synthesized compounds were also evaluated and compared with that of ZD6474.... |
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The effect of neighboring 1- and 2-adamantyl group substitution on the conformations and stereodynamics of N-methylpiperidine. Dynamic NMR spectroscopy and molecular mechanics calculations.
J. Org. Chem. 66(15) , 4989-97, (2001) When a 1-adamantyl or a 2-adamantyl substituent is introduced at the 2-position in N-methylpiperidine, four different chair conformations are possible. Experimental observation using dynamic NMR spectroscopy and molecular mechanics calculations agree that the... |
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Saturated amine oxides: Part 8. Hydroacridines: Part 27. Effects of N-oxidation and of N-quaternization on the 15N NMR chemical shifts of N-methylpiperidine-derived mono-, bi-, and tricycloaliphatic tertiary amines.
Magn. Reson. Chem. 45(3) , 231-5, (2007) The (15)N chemical shifts of 13 N-methylpiperidine-derived mono-, bi- and tricycloaliphatic tertiary amines, their methiodides and their N-epimeric pairs of N-oxides were measured, and the contributions of specific structural parameters to the chemical shifts... |