三苯基氧化膦
三苯基氧化膦结构式
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常用名 | 三苯基氧化膦 | 英文名 | Triphenylphosphine oxide |
|---|---|---|---|---|
| CAS号 | 791-28-6 | 分子量 | 278.285 | |
| 密度 | 1.2±0.1 g/cm3 | 沸点 | 462.9±18.0 °C at 760 mmHg | |
| 分子式 | C18H15OP | 熔点 | 150-157 °C(lit.) | |
| MSDS | 中文版 美版 | 闪点 | 233.8±21.2 °C | |
| 符号 |
GHS07 |
信号词 | Warning |
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Toward prediction of alkane/water partition coefficients.
J. Med. Chem. 51 , 3720-30, (2008) Partition coefficients were measured for 47 compounds in the hexadecane/water ( P hxd) and 1-octanol/water ( P oct) systems. Some types of hydrogen bond acceptor presented by these compounds to the partitioning systems are not well represented in the literatu... |
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Mechanism of lipid peroxidation in cancer cells in response to gamma-linolenic acid (GLA) analyzed by GC-MS(I): Conjugated dienes with peroxyl (or hydroperoxyl) groups and cell-killing effects.
Anticancer Res. 13(1) , 193-9, (1993) We have investigated the nature of lipid peroxidation occurring in association with cancer-killing produced by gamma-linolenic acid (GLA) and iron (Fe) in cultured human breast cancer cells (ZR-75-1: ZR). UV-spectrophotometry, high performance liquid chromato... |
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Solubilization of triphenylamine, triphenylphosphine, triphenylphosphineoxide and triphenylmethanol in single and binary surfactant systems.
J. Colloid. Interface Sci. 364(1) , 163-9, (2011) Solubilization and co-solubilization of triphenyls (TPs) viz., triphenylphosphine (TPP), triphenylphosphineoxide (TPPO), triphenylamine (TPA) and triphenylmethanol (TPM) were studied in various single and binary surfactant systems at 25 °C using UV-visible sp... |
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Structure of triphenylphosphine oxide hemihydrate.
Acta Crystallogr. C 46 ( Pt 4) , 715-7, (1990) C18H15OP.1/2H2O, Mr = 287.30, orthorhombic, Fdd2, a = 19.794 (18), b = 32.540 (12), c = 9.459 (6) A, V = 6092.5 (22) A3, Z = 16, Dx = 1.253 g cm-3, lambda(Mo K alpha) = 0.71073 A, mu = 1.76 cm-1, F(000) = 2416, T = 294 K, R = 0.037 for 1677 reflections with I... |
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Characterization of spectroscopic of Pr(DBM)3(TPPO)2 containing poly(methyl methacrylate).
Spectrochim. Acta. A. Mol. Biomol. Spectrosc. 63(2) , 289-94, (2006) The absorption and fluorescence spectra of Pr(DBM)3(TPPO)2 (DBM: dibenzoylmethane, TPPO: triphenylphosphine oxide) containing poly(methyl methacrylate) (PMMA) were measured. The energy levels are assigned and analyzed in terms of the free-ion Hamiltonian mode... |
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Acute toxicity to the golden apple snail and estimated bioconcentration potential of triphenylphosphine oxide and series of related compounds.
Bull. Environ. Contam. Toxicol. 65(1) , 104-11, (2000)
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Staphylococcus aureus triggers nitric oxide production in human upper airway epithelium.
Int. Forum Allergy Rhinol. 5 , 808-13, (2015) Nitric oxide (NO) is an important antibacterial defense molecule produced by upper airway (sinonasal) epithelial cells. We previously showed that a bitter taste receptor expressed in airway epithelium detects quorum-sensing molecules secreted by Gram-negative... |
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A convenient method for the efficient removal of ruthenium byproducts generated during olefin metathesis reactions.
Org. Lett. 3(9) , 1411-3, (2001) [reaction in text] An efficient method for removing ruthenium byproducts generated during olefin metathesis reactions with Grubbs catalysts is described. Treatment of the crude reaction products with triphenylphosphine oxide or dimethyl sulfoxide, followed by... |
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Determination of NMR interaction parameters from double rotation NMR.
J. Magn. Reson. 188(2) , 246-59, (2007) It is shown that the anisotropic NMR parameters for half-integer quadrupolar nuclei can be determined using double rotation (DOR) NMR at a single magnetic field with comparable accuracy to multi-field static and MAS experiments. The (17)O nuclei in isotopical... |
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Extent of sonochemical degradation and change of toxicity of a pharmaceutical precursor (triphenylphosphine oxide) in water as a function of treatment conditions.
Environ. Int. 31(2) , 207-11, (2005) The degradation of triphenylphosphine oxide (TPPO) in water, a toxic compound typically found in effluents from the pharmaceutical industry, by means of ultrasonic irradiation at 20 kHz has been investigated with emphasis on the effect of various parameters o... |