1-Boc-四氢吡咯结构式
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常用名 | 1-Boc-四氢吡咯 | 英文名 | 2-Methyl-2-propanyl 1-pyrrolidinecarboxylate |
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| CAS号 | 86953-79-9 | 分子量 | 171.237 | |
| 密度 | 1.0±0.1 g/cm3 | 沸点 | 221.4±9.0 °C at 760 mmHg | |
| 分子式 | C9H17NO2 | 熔点 | N/A | |
| MSDS | 中文版 美版 | 闪点 | 87.7±18.7 °C | |
| 符号 |
GHS07 |
信号词 | Warning |
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Enantioselective, palladium-catalyzed α-arylation of N-Boc pyrrolidine: in situ react IR spectroscopic monitoring, scope, and synthetic applications.
J. Org. Chem. 76(15) , 5936-53, (2011) A comprehensive study of the enantioselective Pd-catalyzed α-arylation of N-Boc pyrrolidine has been carried out. The protocol involves deprotonation of N-Boc pyrrolidine using s-BuLi/(-)-sparteine in TBME or Et(2)O at -78 °C, transmetalation with ZnCl(2) and... |
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Asymmetric synthesis of enantioenriched (+)-elaeokanine A.
J. Org. Chem. 71(15) , 5674-8, (2006) The key transformation in the total synthesis of (+)-elaeokanine A was accomplished by asymmetric deprotonation of N-Boc pyrrolidine, followed by the reaction of the in situ generated enantioenriched stereogenic cuprate reagent with (E)-4-bromo-1-iodo-1-trime... |
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Enantioselective, palladium-catalyzed α-arylation of N-boc-pyrrolidine. Campos KR, et al.
J. Am. Chem. Soc. 128(11) , 3538-3539, (2006)
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Copper mediated scalemic organolithium reagents in alkaloid syntheses. 3Dieter RK, et al.
Tetrahedron 61(13) , 3221-3230, (2005)
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Stereoselective synthesis of hydroxyindolizidines via sparteine-assisted deprotonation of N-Boc-pyrrolidine. Majewski M, et al.
Tetrahedron Lett. 39(38) , 6787-6790, (1998)
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Synthesis of methylphenidate analogues and their binding affinities at dopamine and serotonin transport sites. Davies HML, et al.
Bioorg. Med. Chem. Lett. 14(7) , 1799-1802, (2004)
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Catalytic asymmetric C-H activation by methyl thiophen-3-yldiazoacetate applied to the synthesis of (+)-cetiedil. Davies HML, et al.
Tetrahedron Lett. 43(28) , 4981-4983, (2002)
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