三正辛基膦

三正辛基膦结构式
三正辛基膦结构式
品牌特惠专场
常用名 三正辛基膦 英文名 Trioctylphosphine
CAS号 4731-53-7 分子量 370.635
密度 0.831 g/mL at 25 °C(lit.) 沸点 445.0±14.0 °C at 760 mmHg
分子式 C24H51P 熔点 -60ºC
MSDS 中文版 美版 闪点 236.0±26.4 °C
符号 GHS05
GHS05
信号词 Danger

CdSe-graphene oxide light-harvesting assembly: size-dependent electron transfer and light energy conversion aspects.

ChemPhysChem 15(10) , 2129-35, (2014)

Excited-state interaction between CdSe quantum dots (QDs) of different sizes (2.3, 3.2, and 4.2 nm diameter) and graphene oxide (GO) was probed by depositing them as films on conducting glass electrodes. The emission of smaller CdSe QDs (2.3 nm) was quenched ...

Detection of microRNA in tumor cells using exonuclease III and graphene oxide-regulated signal amplification.

ACS Appl. Mater. Interfaces 6(24) , 21780-7, (2014)

In this study, we developed a label-free, ultrasensitive graphene oxide (GO)-based probe for the detection of oligonucleotides by laser desorption/ionization mass spectrometry (LDI-MS). On the basis of simple π-π stacking and electrostatic interactions betwee...

Electrocatalytic and Photocatalytic Hydrogen Production from Acidic and Neutral-pH Aqueous Solutions Using Iron Phosphide Nanoparticles.

ACS Nano 8(11) , 11101-7, (2014)

Nanostructured transition-metal phosphides have recently emerged as Earth-abundant alternatives to platinum for catalyzing the hydrogen-evolution reaction (HER), which is central to several clean energy technologies because it produces molecular hydrogen thro...

Metal-Semiconductor Hybrid Aerogels: Evolution of Optoelectronic Properties in a Low-Dimensional CdSe/Ag Nanoparticle Assembly.

ACS Nano 9 , 9810-21, (2015)

Hybrid nanomaterials composed of metal-semiconductor components exhibit unique properties in comparison to their individual counterparts, making them of great interest for optoelectronic applications. Theoretical and experimental studies suggest that interfac...

Compact and blinking-suppressed quantum dots for single-particle tracking in live cells.

J. Phys. Chem. B 118(49) , 14140-7, (2014)

Quantum dots (QDs) offer distinct advantages over organic dyes and fluorescent proteins for biological imaging applications because of their brightness, photostability, and tunability. However, a major limitation is that single QDs emit fluorescent light in a...

Mechanistic insight into the formation of cationic naked nanocrystals generated under equilibrium control.

J. Am. Chem. Soc. 136(44) , 15702-10, (2014)

Cationic naked nanocrystals (NCs) are useful building units for assembling hierarchical mesostructured materials. Until now, their preparation required strongly electrophilic reagents that irreversibly sever bonds between native organic ligands and the NC sur...

Integration of CdSe/CdSexTe1-x Type-II Heterojunction Nanorods into Hierarchically Porous TiO2 Electrode for Efficient Solar Energy Conversion.

Sci. Rep. 5 , 17472, (2015)

Semiconductor sensitized solar cells, a promising candidate for next-generation photovoltaics, have seen notable progress using 0-D quantum dots as light harvesting materials. Integration of higher-dimensional nanostructures and their multi-composition varian...

Asymmetric flow field-flow fractionation coupled to inductively coupled plasma mass spectrometry for the quantification of quantum dots bioconjugation efficiency.

J. Chromatogr. A. 1422 , 247-52, (2015)

Hyphenation of asymmetric flow field-flow fractionation (AF4) to an on-line elemental detection (inductively coupled plasma-mass spectrometry, ICP-MS) is proposed as a powerful diagnostic tool for quantum dots bioconjugation studies. In particular, conjugatio...

Band structure engineering via piezoelectric fields in strained anisotropic CdSe/CdS nanocrystals.

Nat. Commun. 6 , 7905, (2015)

Strain in colloidal heteronanocrystals with non-centrosymmetric lattices presents a unique opportunity for controlling optoelectronic properties and adds a new degree of freedom to existing wavefunction engineering and doping paradigms. We synthesized wurtzit...

Effects of a Tricaprylin Emulsion on Anti-glomerular Basement Membrane Glomerulonephritis in Rats: In Vivo and in Silico Studies.

Biol. Pharm. Bull. 38 , 1175-84, (2015)

Glomerulonephritis (GN) is a set of pathological conditions that result in the destruction of glomeruli and loss of renal function, commonly leading to the development of end-stage renal disease. Current pharmacotherapy is limited to immunosuppressive therapy...