![]() 对甲基苯甲醛结构式
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常用名 | 对甲基苯甲醛 | 英文名 | p-Tolualdehyde |
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CAS号 | 104-87-0 | 分子量 | 120.148 | |
密度 | 1.015 | 沸点 | 204-205 ºC | |
分子式 | C8H8O | 熔点 | -6 °C | |
MSDS | 中文版 美版 | 闪点 | 80 ºC | |
符号 |
![]() GHS07 |
信号词 | Warning |
Synthesis, luminescence, and electrochemical studies of a new series of octanuclear ruthenium(II) complexes of tolylterpyridine appended calixresorcarenes.
Dalton Trans. 44 , 14813-22, (2015) A new series of octanuclear Ru(ii) complexes of tolylterpyridine appended calixresorcarenes [{Ru(ttpy)}8()](PF6)16 (), [{Ru(ttpy)}8()](PF6)16 (), and [{Ru(ttpy)}8()](PF6)16 () [ = 2,8,14,20-tetraethyl-4,6,10,12,16,18,22,24-octa(4'-p-benzyloxy-(2,2':6',2''-ter... |
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Quantitative structure-activity relationship analysis of inhibitors of the nicotine metabolizing CYP2A6 enzyme.
J. Med. Chem. 48 , 440-9, (2005) The purpose of this study was to develop screening and in silico modeling methods to obtain accurate information on the active center of CYP2A6, a nicotine oxidizing enzyme. The inhibitory potencies of 26 naphthalene and 16 non-naphthalene derivatives were de... |
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Toward the development of chemoprevention agents. Part 1: Design, synthesis, and anti-inflammatory activities of a new class of 2,5-disubstituted-dioxacycloalkanes.
Bioorg. Med. Chem. 15 , 4775-99, (2007) A new class of 2,5-disubstituted-dioxacycloalkanes were designed and synthesized via stereoselective synthetic method as cancer chemoprevention agents. The anti-inflammatory activities of these compounds were tested using the xylene-induced mouse ear edema mo... |
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Simultaneous production of p-tolualdehyde and hydrogen peroxide in photocatalytic oxygenation of p-xylene and reduction of oxygen with 9-mesityl-10-methylacridinium ion derivatives.
Chem. Commun. (Camb.) 46(4) , 601-3, (2010) Photooxygenation of p-xylene by oxygen occurs efficiently under photoirradiation of 9-mesityl-2,7,10-trimethylacridinium ion (Me(2)Acr(+)-Mes) to yield p-tolualdehyde and hydrogen peroxide, which is initiated via photoinduced electron transfer of Me(2)Acr(+)-... |
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Oxidation of tolualdehydes to toluic acids catalyzed by cytochrome P450-dependent aldehyde oxygenase in the mouse liver.
Drug Metab. Dispos. 23(2) , 261-5, (1995) Mouse hepatic microsomal enzymes catalyzed the oxidation of o-, m-, and p-tolualdehydes, intermediate metabolites of xylene, to the corresponding toluic acids. Cofactor requirement for the catalytic activity indicates that the microsomes contain NAD- and NADP... |
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(E)-3-(4-Methyl-phen-yl)-1-(1,3-thia-zol-2-yl)prop-2-en-1-one.
Acta Crystallogr. Sect. E Struct. Rep. Online 68(Pt 6) , o1875, (2012) In the title chalcone, C(13)H(11)NOS, derived from the condensation of p-tolualdehyde and 1-(1,3-thia-zol-2-yl)ethanone, the olefine group has a trans configuration. No classical hydrogen bonding is present in the crystal structure. |
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Metabolism of toluene and xylenes by Pseudomonas (putida (arvilla) mt-2: evidence for a new function of the TOL plasmid.
J. Bacteriol. 124(1) , 7-13, (1975) Pseudomonas putida (arvilla) mt-2 carries genes for the catabolism of toluene, m-xylene, and p-xylene on a transmissible plasmid, TOL. These compounds are degraded by oxidation of one of the methyl substituents via the corresponding alcohols and aldehydes to ... |
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100 selective oxygenation of p-xylene to p-tolualdehyde via photoinduced electron transfer
Org. Lett. 2(23) , 3647-50, (2000) The 100% selective oxygenation of p-xylene to p-tolualdehyde is initiated by photoinduced electron transfer from p-xylene to the singlet excited state of 10-methyl-9-phenylacridinium ion under visible light irradiation, yielding p-tolualdehyde exclusively as ... |
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A one-pot multicomponent coupling reaction for the stereocontrolled synthesis of (Z)-trisubstituted allylic alcohols.
J. Am. Chem. Soc. 126(12) , 3702-3, (2004) In this Communication, we outline a new one-pot, multicomponent coupling reaction that allows easy access to (Z)-trisubstituted allylic alcohols. Our strategy is based on E to Z isomerization of the 1-bromo-1-dialkylvinylborane upon reaction with dialkylzinc ... |
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Synthesis of cationic diiron μ-vinylcarbyne complexes. Casey CP, et al.
Polyhedron 7(10) , 881-992, (1988)
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