DL-丝氨酸甲酯盐酸盐结构式
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常用名 | DL-丝氨酸甲酯盐酸盐 | 英文名 | Methyl serinate hydrochloride |
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| CAS号 | 5619-04-5 | 分子量 | 147.217 | |
| 密度 | 1.0±0.1 g/cm3 | 沸点 | 239.3±9.0 °C at 760 mmHg | |
| 分子式 | C10H13N | 熔点 | 134-136 °C(lit.) | |
| MSDS | 中文版 美版 | 闪点 | 100.0±14.2 °C | |
| 符号 |
GHS07 |
信号词 | Warning |
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Acylated serine derivatives: a unique class of arthropod pheromones of the Australian redback spider, Latrodectus hasselti.
Angew. Chem. Int. Ed. Engl. 49(11) , 2037-40, (2010)
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The novel and efficient direct synthesis of N,O-acetal compounds using a hypervalent iodine(III) reagent: an improved synthetic method for a key intermediate of discorhabdins.
Chem. Commun. (Camb.) (13) , 1764-6, (2005) The use of hypervalent iodine(III) reagents allowed us to develop the novel and efficient direct synthesis of N,O-acetal compounds via the oxidative fragmentation reaction of alpha-amino acids or alpha-amino alcohols; furthermore, we succeeded in developing a... |
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Aziridinium from N,N-dibenzyl serine methyl ester: synthesis of enantiomerically pure beta-amino and alpha,beta-diamino esters.
Org. Lett. 8(10) , 2183-6, (2006) [reaction: see text] Reaction of N,N-dibenzyl-O-methylsulfonyl serine methyl ester with a variety of heteronucleophiles (sodium azide, sodium phthalimide, amines, thiols) and carbanions (sodium malonate) gave, via an aziridinium intermediate, the correspondin... |
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Contribution of the anomeric effect to the solution and crystal structure of [1S,2S,6S,7s]-1,6-diaza-4,9-dioxa-2,7-dimethoxycarbonylbicyclo[4.4.1]undecane, a condensation product of L-serine methyl ester with formaldehyde.
Carbohydr. Res. 330(1) , 43-51, (2001) The reaction of L-serine methyl ester hydrochloride (1) with paraformaldehyde (2) in dichloromethane in the presence of triethylamine afforded a novel compound: [lS,2S,6S,7S]-1,6-diaza-4,9-dioxa-2,7-dimethoxycarbonylbicyclo[4.4.1]undecane (4) as a 2:3 adduct ... |
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Theoretical evidence for pyramidalized bicyclic serine enolates in highly diastereoselective alkylations.
Chemistry 13(17) , 4840-8, (2007) A new chiral serine equivalent and its enantiomer have been synthesized from (S)- and (R)-N-Boc-serine methyl esters (Boc: tert-butyloxycarbonyl). The use of these compounds as chiral building blocks has been demonstrated in the synthesis of alpha-alkyl alpha... |
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Selective inhibition of divergent seryl-tRNA synthetases by serine analogues.
FEBS Lett. 579(20) , 4344-8, (2005) Seryl-tRNA synthetases (SerRSs) fall into two distinct evolutionary groups of enzymes, bacterial and methanogenic. These two types of SerRSs display only minimal sequence similarity, primarily within the class II conserved motifs, and possess distinct modes o... |