4-(二甲基氨基)苯硼酸

4-(二甲基氨基)苯硼酸结构式
4-(二甲基氨基)苯硼酸结构式
品牌特惠专场
常用名 4-(二甲基氨基)苯硼酸 英文名 4-(Dimethylamino)phenylboronic acid
CAS号 28611-39-4 分子量 164.997
密度 1.1±0.1 g/cm3 沸点 329.9±44.0 °C at 760 mmHg
分子式 C8H12BNO2 熔点 227 °C(lit.)
MSDS 中文版 美版 闪点 153.3±28.4 °C
符号 GHS07
GHS07
信号词 Warning

Synthesis and photophysical investigation of a series of push-pull arylvinyldiazine chromophores.

J. Org. Chem. 8th ed., 77 , 4087-4096, (2012)

A new series of push-pull arylvinyldiazines has been efficiently prepared by aldol condensation between the appropriate methyldiazine and aromatic aldehyde. The optical absorption and emission properties of these chromophores were studied in different solvent...

Nickel-catalyzed Suzuki-Miyaura reaction of aryl fluorides.

J. Am. Chem. Soc. 48th ed., 133 , 19505-19511, (2011)

Two protocols for the nickel-catalyzed cross-coupling of aryl fluorides with aryl boronic esters have been developed. The first employs metal fluoride cocatalysts, such as ZrF(4) and TiF(4), which enable Suzuki-Miyaura reactions of aryl fluorides bearing elec...

Dramatic Effect of the Gelling Cation on the Catalytic Performances of Alginate-Supported Palladium Nanoparticles for the Suzuki-Miyaura Reaction Chtchigrovsky, M.; et al.

Chem. Mater. 8th ed., 24 , 1505-1510, (2012)

Organic dyes incorporating the cyclopentadithiophene moiety for efficient dye-sensitized solar cells Cheng, X.; et al.

Dyes and Pigments 3rd ed., 92 , 1292-1299, (2012)

Rapid access to 4-substituted-pyrones and 2(5H)-furanones via a palladium-catalyzed C-OH bond activation Hu, Y.; et al.

Tetrahedron 38th ed., 67 , 7258-7262, (2011)

Chiral allene-containing phosphines in asymmetric catalysis.

J. Am. Chem. Soc. 45th ed., 133 , 18066-18069, (2011)

We demonstrate that allenes, chiral 1,2-dienes, appended with basic functionality can serve as ligands for transition metals. We describe an allene-containing bisphosphine that, when coordinated to Rh(I), promotes the asymmetric addition of arylboronic acids ...

ortho-Phenylene oligomers with terminal push-pull substitution.

Org. Biomol. Chem. 17th ed., 10 , 3398-3405, (2012)

ortho-Phenylenes are an emerging class of helical oligomers and polymers. We have synthesized a series of push-pull-substituted o-phenylene oligomers (dimethylamino/nitro) up to the octamer. Conformational analysis of the hexamer using a combination of low-te...