1-溴-2,4,6-三-叔丁基苯
1-溴-2,4,6-三-叔丁基苯结构式
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常用名 | 1-溴-2,4,6-三-叔丁基苯 | 英文名 | Benzene,2-bromo-1,3,5-tris(1,1-dimethylethyl)- |
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| CAS号 | 3975-77-7 | 分子量 | 325.32700 | |
| 密度 | 1.064g/cm3 | 沸点 | 299.7ºC at 760mmHg | |
| 分子式 | C18H29Br | 熔点 | 168-173ºC(lit.) | |
| MSDS | 中文版 美版 | 闪点 | 123.7ºC | |
| 符号 |
GHS07 |
信号词 | Warning |
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A new biarylphosphine ligand for the Pd-catalyzed synthesis of diaryl ethers under mild conditions.
Org. Lett. 14(1) , 170-3, (2012) A new bulky biarylphosphine ligand (L8) has been developed that allows the Pd-catalyzed C-O cross-coupling of a wide range of aryl halides and phenols under milder conditions than previously possible. A direct correlation between the size of the ligand substi... |
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Palladium(0)-catalyzed intermolecular amination of unactivated C(sp³)-H bonds.
Angew. Chem. Int. Ed. Engl. 50(37) , 8647-51, (2011)
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Rationalizing oligomerization in dimethylindium(III) chalcogenolates (Me2InER') (E = O, S, Se): a structural and computational study.
Dalton Trans. 39(16) , 3833-41, (2010) The effect on oligomerization of increased steric bulk in dimethylindium(III) chalcogenolates (Me(2)InER') (E = O, S, Se) has been examined. The facile reaction of Me(3)In with a series of phenols, thiophenols and selenophenols afforded the compounds [Me(2)In... |
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The first Cu-and amine-free Sonogashira-type cross-coupling in the C-6-alkynylation of protected 2'-deoxyadenosine. Ngassa FN, et al.
Tetrahedron 65(21) , 4085-4091, (2009)
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