硝基乙酸甲酯结构式
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常用名 | 硝基乙酸甲酯 | 英文名 | Methyl nitroacetate |
|---|---|---|---|---|
| CAS号 | 2483-57-0 | 分子量 | 119.076 | |
| 密度 | 1.3±0.1 g/cm3 | 沸点 | 196.5±0.0 °C at 760 mmHg | |
| 分子式 | C3H5NO4 | 熔点 | N/A | |
| MSDS | 中文版 美版 | 闪点 | 105.0±0.0 °C | |
| 符号 |
GHS07 |
信号词 | Warning |
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Experimental and theoretical studies of Diels-Alder reaction between methyl (Z)-2-nitro-3-(4-nitrophenyl)-2-propenoate and cyclopentadiene. Jasinski R, et al.
Monatsh. Chem 144(3) , 327-35, (2013)
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Catalytic intermolecular allylic C-H alkylation.
J. Am. Chem. Soc. 130 , 14090-14091, (2008) The first electrophilic Pd(II)-catalyzed allylic C H alkylation is reported, providing a novel method for formation of sp3-sp3 C C bonds directly from C H bonds. A wide range of aromatic and heteroaromatic linear (E)-alpha-nitro-arylpentenoates are obtained a... |
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Expedient synthesis of cyclopropane alpha-amino acids by the catalytic asymmetric cyclopropanation of alkenes using iodonium ylides derived from methyl nitroacetate.
J. Am. Chem. Soc. 127(51) , 18014-5, (2005) A highly enantioselective (up to 97.5% ee) and diastereoselective (95:5 dr trans/cis) Cu(I)-catalyzed cyclopropanation of alkenes using phenyliodonium ylide generated in situ from iodosobenzene and methyl nitroacetate is reported. The cyclopropanation took pl... |
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[Experimental establishment of the maximum permissible concentration of the methyl and ethyl esters of nitroacetic acid].
Gig. Tr. Prof. Zabol. (7) , 49-51, (1980)
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