五氟吡啶结构式
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常用名 | 五氟吡啶 | 英文名 | Pentafluoropyridine |
|---|---|---|---|---|
| CAS号 | 700-16-3 | 分子量 | 169.052 | |
| 密度 | 1.6±0.1 g/cm3 | 沸点 | 100.1±35.0 °C at 760 mmHg | |
| 分子式 | C5F5N | 熔点 | -42 | |
| MSDS | 中文版 美版 | 闪点 | 23.9±0.0 °C | |
| 符号 |
GHS02, GHS07 |
信号词 | Warning |
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Solid phase analytical derivatization of anthropogenic and natural phenolic estrogen mimics with pentafluoropyridine for gas chromatography-mass spectrometry.
J. Chromatogr. A. 1218(51) , 9135-41, (2011) A simple, low cost, fast and sensitive method is reported for the determination of the four endocrine disrupting chemicals (EDCs) 4-tert-butylphenol, 4-tert-octylphenol, bisphenol A and 17β-estradiol using pentafluoropyridine as the derivatizing reagent. Thes... |
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Photochemical Reactions of Fluorinated Pyridines at Half-Sandwich Rhodium Complexes: Competing Pathways of Reaction.
Organometallics 33(1) , 45-52, (2014) Irradiation of CpRh(PMe3)(C2H4) (1; Cp = _(5)-C5H5) in the presence of pentafluoropyridine in hexane solution at low temperature yields an isolable _(2)-C,C-coordinated pentafluoropyridine complex, CpRh(PMe3)(_(2)-C,C-C5NF4) (2). The molecular structure of 2 ... |
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Palladium-catalyzed coupling reaction of perfluoroarenes with diarylzinc compounds.
Chemistry 20(7) , 2040-8, (2014) This report describes the first Pd(0)-catalyzed cross-coupling of hexafluorobenzene (C6F6) with diarylzinc compounds to give a variety of pentafluorophenyl arenes. This reaction could be applied to other perfluoroarenes, such as octafluorotoluene, pentafluoro... |
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Selective C-F/C-H bond activation of fluoroarenes by cobalt complex supported with phosphine ligands.
Dalton Trans. 42(16) , 5740-8, (2013) The reactions of pentafluoropyridine C5NF5, hexafluorobenzene C6F6, and perfluoronaphthalene C10F8 with cobalt(0) complex, Co(PMe3)4, were investigated. The Co(I) complexes (4-C5NF4)Co(PMe3)3 (1), (C6F5)Co(PMe3)3 (2), (C10F7)Co(PMe3)3 (3), (4-C5NF4)Co(PMe3)4 ... |