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2,2,2-三苯基苯乙酮

2,2,2-三苯基苯乙酮结构式
2,2,2-三苯基苯乙酮结构式
品牌特惠专场
常用名 2,2,2-三苯基苯乙酮 英文名 benzopinacolone
CAS号 466-37-5 分子量 348.436
密度 1.1±0.1 g/cm3 沸点 498.4±14.0 °C at 760 mmHg
分子式 C26H20O 熔点 182-184 °C(lit.)
MSDS 中文版 美版 闪点 216.3±15.1 °C

Reactions of Acenaphthenequinone and Aceanthrenequinone with Arenes in Superacid.

Appl. Catal. A Gen. 336(1-2) , 128-132, (2008)

The hydroxyalkylation reactions of aceanthrenequinone (6) and acenapthenequinone (7) with a series of arenes have been studied. In reactions with the Br__nsted superacid CF(3)SO(3)H (triflic acid), the condensation products are formed in good yields (58-99%, ...

Chiral synthesis via organoboranes. 15. Selective reductions. 42. Asymmetric reduction of representative prochiral ketones with potassium 9-O-(1, 2: 5, 6-di-O-isopropylidene-. alpha.-D-glucofuranosyl)-9-boratabicyclo [3.3. 1] nonane. Brown HC, etal.

J. Org. Chem. 53(6) , 1231-38, (1988)