4,7-菲咯啉
4,7-菲咯啉结构式
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常用名 | 4,7-菲咯啉 | 英文名 | 4,7-phenanthroline |
|---|---|---|---|---|
| CAS号 | 230-07-9 | 分子量 | 180.20500 | |
| 密度 | 1.25g/cm3 | 沸点 | 365.1ºC at 760mmHg | |
| 分子式 | C12H8N2 | 熔点 | 172-174ºC(lit.) | |
| MSDS | N/A | 闪点 | 164.8ºC | |
| 符号 |
GHS05, GHS07 |
信号词 | Danger |
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Cold-spray ionization mass spectrometric detection of a coordination oligomer.
Anal. Sci. 28(7) , 635-7, (2012) Coordination polymer (CP) formation is an unexplored area in weak-interaction chemistry due to the difficulty of monitoring the coordination process. By using cold-spray ionization mass spectrometry (CSI-MS), several kinds of coordination compounds were detec... |
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Mononucleotide recognition by cyclic trinuclear palladium(II) complexes containing 4,7-phenanthroline N,N bridges.
Dalton Trans. (10) , 1563-6, (2004) Reaction of [(dach)Pd(NO3)2] entities (dach = (R,R)-1,2-diaminocyclohexane, (S,S)-1,2-diaminocyclohexane) and 4,7-phenanthroline (phen) providing, respectively, 90 and 120 degrees bond angles, leads to the formation of two novel positively charged homochiral ... |
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Reactions of phthalazine, quinazoline, 4,7-phenanthroline and 2,3'-bipyridine with ruthenium carbonyl.
Dalton Trans. 41(24) , 7249-57, (2012) The reactions of [Ru(3)(CO)(12)] with four aromatic diazines have been studied in THF at reflux temperature. With phthalazine (L(1)), the compound [Ru(3)(μ-κ(2)N(2)N(3)-L(1))(μ-CO)(3)(CO)(7)] (1), which contains an intact phthalazine ligand in an axial positi... |
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Cyclic tetranuclear half-sandwich ruthenium(II) complexes with 4,7-phenanthroline and hydroxo bridges: crystal structure, solution behaviour and binding to nucleosides.
J. Inorg. Biochem. 102(5-6) , 1025-32, (2008) The reaction between [(eta(6)-p-cymene)Ru(H2O)3]X2 and 4,7-phenanthroline (phen) leads to the formation of the rectangular tetranuclear complexes [(eta(6)-p-cymene)4Ru4(mu-4,7-phen-N4,N7)(2)(mu-OH)4]X4 (X=NO3, 1a; SO3CF3, 1b) which have been structurally char... |
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Investigation of the regulation of transcriptional changes inAncylostoma caninumlarvae following serum activation, with a focus on the insulin-like signalling pathway
Vet. Parasitol. 159(2) , 139-48, (2009) The exit from dauer in the free-living nematode Caenorhabditis elegans is under the control of a single amphidial neuron (ASJ) of the insulin-like signalling pathway. Mutations of this pathway have the ability to suppress entry into the dauer stage. It has be... |
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Regulation of glucose transport in the NIH 3T3 L1 preadipocyte cell line by TCDD.
Environ. Health Perspect. 102(5) , 454-8, (1994) This study examined the changes in cellular glucose uptake induced by 2,3,7,8 tetrachlorodibenzo-p-dioxin (TCDD) as measured by quantification of intracellular radioactivity in the NIH 3T3 L1 preadipocyte cell line after a 30-minute incubation with the non-me... |
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Protective action of dehydroascorbic acid on the Ah receptor-dependent and receptor-independent induction of lipid peroxidation in adipose tissue of male guinea pig caused by TCDD administration.
J. Biochem. Toxicol. 11(6) , 269-78, (1996) The effect of 2,3,7,8-tetrachlorodibenzo-p-dioxin (TCDD) on lipid peroxidation, 3H-Me-glucose (3H-Me-glu), and 14C-dehydroascorbic acid (14C-DHA) uptakes were studied in adipose tissue of male guinea pig. Under in vitro test conditions, using isolated adipose... |
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Cyclic [2]pseudorotaxane tetramers consisting of two rigid rods threaded through two bis-macrocycles: copper(I)-templated synthesis and X-ray structure studies.
J. Am. Chem. Soc. 130(33) , 11013-22, (2008) Variously substituted coordinating rigid rods have been synthesized which incorporate a central 4,7-phenanthroline nucleus attached to two 2-pyridyl groups via its 3 and 8 positions, so as to yield bis-bidentate chelates, the two-coordinating axes of the chel... |
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Transfer RNA-pseudouridine synthetase Pus1 of Saccharomyces cerevisiae contains one atom of zinc essential for its native conformation and tRNA recognition.
Biochemistry 37(20) , 7268-76, (1998) RNA:pseudouridine synthetase (Pus1) from Saccharomyces cerevisiae is a multisite specific enzyme that catalyzes the formation of pseudouridine at positions 34 and 36 of intron-containing precursor tRNAIle and at positions 27 and/or 28 of several yeast tRNAs. ... |
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Differential inhibition of the yeast bc1 complex by phenanthrolines and ferroin. Implications for structure and catalytic mechanism.
J. Biol. Chem. 272(27) , 16753-60, (1997) o-Phenanthroline and m-phenanthroline both inhibit the electron transfer activity of lauryl maltoside-solubilized yeast bc1 complex progressively with time. Pre-steady-state kinetics indicate that these compounds bind to the complex on the intermembrane space... |