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2-溴丙酸

一般危化品
2-溴丙酸结构式
2-溴丙酸结构式
常用名 2-溴丙酸 英文名 2-Bromopropionic Acid
CAS号 598-72-1 分子量 152.975
密度 1.8±0.1 g/cm3 沸点 202.6±13.0 °C at 760 mmHg
分子式 C3H5BrO2 熔点 25.7°C
MSDS 中文版 美版 闪点 100.0±0.0 °C
符号 GHS05 GHS07
GHS05, GHS07
信号词 Danger

Design and synthesis of digitally encoded polymers that can be decoded and erased.

Nat. Commun. 6 , 7237, (2015)

Biopolymers such as DNA store information in their chains using controlled sequences of monomers. Here we describe a non-natural information-containing macromolecule that can store and retrieve digital information. Monodisperse sequence-encoded poly(alkoxyami...

A novel hyperbranched poly(acrylic acid) for improved resin-modified glass-ionomer restoratives.

Dent. Mater. 27(5) , 478-86, (2011)

The objective of this study was to synthesize and characterize novel hyperbranched poly(acrylic acid)s via atom-transfer radical polymerization (ATRP) technique and tether the photo-curable methacrylate onto the poly(acrylic acid), use these polymers to formu...

Use of structure-activity relationships for probing biochemical mechanisms: glutathione transferase zeta conjugation of haloacids.

Adv. Exp. Med. Biol. 500 , 23-31, (2001)

Catalysis of the hydrolysis of ethyl mandelate and esterification of alpha-bromopropionic acid by lipase in microemulsions.

Chin. J. Biotechnol. 9(1) , 33-9, (1993)

Candida cyclindracea lipase (CCL) was added to "sodium dodecyl sulfonate (AS)/n-butanol/n-octane/n-octane" water-in-oil microemulsion to catalyze the hydrolysis of ethyl mandelate and the esterification of alpha-bromopropionic acid with n-butanol, respectivel...

Superparamagnetic nanoparticle-supported enzymatic resolution of racemic carboxylates.

Chem. Commun. (Camb.) (35) , 4432-4, (2005)

Candida rugosa lipase immobilized on maghemite nanoparticles demonstrated high stereoselectivity in kinetic resolution of racemic carboxylates and improved long-term stability over its parent free enzyme, allowing the supported enzyme to be repeatedly used fo...

A transition-state analysis of the enzyme catalysis in the affinity labelling of horse-liver alcohol dehydrogenase by bromoacids.

Eur. J. Biochem. 126(2) , 247-52, (1982)

The effect of temperature on the inactivation of liver alcohol dehydrogenase and on the alkylation of a model thiol free in solution by bromoacetate, 2-bromopropionate, 3-bromopropionate and 2-bromo-3-(5-imidazolyl)-propionate has been studied and the thermod...

Reductive dehalogenation of halocarboxylic acids by the phototrophic genera Rhodospirillum and Rhodopseudomonas.

Appl. Environ. Microbiol. 63(8) , 3333-5, (1997)

Type strains of the purple nonsulfur species Rhodospirillum rubrum, Rhodospirillum photometricum, and Rhodopseudomonas palustris grew phototrophically on a number of two- and three-carbon halocarboxylic acids in the presence of CO2, by reductive dehalogenatio...

The absence of cerebellar granule cell necrosis in the mouse following L-2-chloropropionic acid administration.

Arch. Toxicol. 74(9) , 547-54, (2000)

Oral administration of L-2-chloropropionic acid (L-CPA) to rats either as a single dose (750 mg/kg) or daily doses (250 mg/kg per day for 3 days) produces selective necrosis to the granule cell layer of the cerebellum. As part of a study to understand the mec...

Isolation, characterization and identification of a Paracoccus sp. 2-haloacid-degrading bacterium from the marine sponge Hymeniacidon perlevis.

J. Basic Microbiol. 51(3) , 318-24, (2011)

A 2-haloacid dehalogenase-producing bacterium, designated DEH99, was isolated from the marine sponge Hymeniacidon perlevis using a modified enrichment medium and a pH indicator method. DEH99 could degrade only half of the racemic mixture 2-chloropropionic aci...

Synthesis and chromatographic properties of S-(1-carboxyethyl)-L-cysteine and S-(1-carboxypropyl)-L-cysteine.

Ital. J. Biochem. 36(1) , 1-7, (1987)

Details are reported for the synthesis of S-(1-carboxyethyl)-L-cysteine (1-CEC) and S-(1-carboxypropyl)-L-cysteine (1-CPC) from cysteine and 2-bromopropionic acid or 2-bromobutyric acid, respectively. Some analytical data and the behaviour of these two compou...