正丁基锂结构式
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常用名 | 正丁基锂 | 英文名 | n-Butyllithium |
|---|---|---|---|---|
| CAS号 | 109-72-8 | 分子量 | 64.055 | |
| 密度 | 0.68 g/mL at 20 °C | 沸点 | 60-80 ºC | |
| 分子式 | C4H9Li | 熔点 | -95 °C | |
| MSDS | 中文版 | 闪点 | -21 ºC | |
| 符号 |
GHS02, GHS05, GHS07, GHS08, GHS09 |
信号词 | Danger |
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Layered titanium diboride: towards exfoliation and electrochemical applications.
Nanoscale 7 , 12527-34, (2015) Layered transition metal diborides (TMDB), amongst other refractory metal borides, are commonly employed for material fabrication such as wear- and corrosion-resistant coatings due to their impressive chemical stability and thermal conductivity. In spite of t... |
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Effects of cyano-substituents on the molecular packing structures of conjugated polymers for bulk-heterojunction solar cells.
ACS Appl. Mater. Interfaces 6(18) , 15774-82, (2014) The molecular packing structures of two conjugated polymers based on alkoxy naphthalene, one with cyano-substituents and one without, have been investigated to determine the effects of electron-withdrawing cyano-groups on the performance of bulk-heterojunctio... |
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Design, synthesis and structure-activity relationship studies of novel and diverse cyclooxygenase-2 inhibitors as anti-inflammatory drugs.
J. Enzyme Inhib. Med. Chem. 29(6) , 846-67, (2014) Because of the pivotal role of cyclooxygenase (COX) in the inflammatory processes, non-steroidal anti-inflammatory drugs (NSAIDs) that suppress COX activities have been used clinically for the treatment of inflammatory diseases/syndromes; however, traditional... |
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Atomically controlled substitutional boron-doping of graphene nanoribbons.
Nat. Commun. 6 , 8098, (2015) Boron is a unique element in terms of electron deficiency and Lewis acidity. Incorporation of boron atoms into an aromatic carbon framework offers a wide variety of functionality. However, the intrinsic instability of organoboron compounds against moisture an... |
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Synthetic (+)-terrein suppresses interleukin-6/soluble interleukin-6 receptor induced-secretion of vascular endothelial growth factor in human gingival fibroblasts.
Bioorg. Med. Chem. 22(19) , 5338-44, (2014) Interleukin (IL)-6 is a proinflammatory cytokine that performs a wide variety of biological functions, including important roles in the progression of chronic inflammatory diseases such as periodontal disease. (+)-Terrein, a secondary bioactive fungal metabol... |
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Predator lipids induce paralytic shellfish toxins in bloom-forming algae.
Proc. Natl. Acad. Sci. U. S. A. 112 , 6395-400, (2015) Interactions among microscopic planktonic organisms underpin the functioning of open ocean ecosystems. With few exceptions, these organisms lack advanced eyes and thus rely largely on chemical sensing to perceive their surroundings. However, few of the signal... |
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Deposition of wafer-scale single-component and binary nanocrystal superlattice thin films via dip-coating.
Adv. Mater. 27 , 2846-51, (2015) Single-component and binary nanocrystal superlattices are assembled over wafer-scale areas using the dip-coating method. A series of measurements are performed to confirm superlattice assembly. This study demonstrates the versatility of dip-coating in deposit... |
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Europium bis(dimethylsilyl)amides including mixed-valent Eu3[N(SiHMe2)2]6[μ-N(SiHMe2)2]2.
Dalton Trans. 43(46) , 17324-32, (2014) Trivalent Eu[N(SiHMe2)2]3(THF)2 can easily be synthesized by applying a routine salt metathesis protocol (EuCl3(THF)2 and 3 equiv. of Li[N(SiHMe2)2] in n-hexane) which crystallizes isotypically to its analogues of the rare-earth metal series (space group P21/... |
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Polymeric micelles for pH-responsive delivery of cisplatin.
J. Drug Target. 22(7) , 629-37, (2014) Methoxy poly(ethylene oxide)-block-poly-(α-carboxylate-ε-caprolactone) (PEO-b-PCCL) was used to develop pH-responsive polymeric micelles for the delivery of cisplatin (CDDP). Micelles were prepared through complexation of CDDP with the pendant carboxyl groups... |
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Synthesis of Amphiphilic Ru(II) Heteroleptic Complexes Based on Benzo[1,2-b:4,5-b']dithiophene: Relevance of the Half-Sandwich Complex Intermediate and Solvent Compatibility.
Chemistry 21 , 16252-65, (2015) The detailed synthesis and characterization of four ruthenium(II) complexes [RuLL'(NCS)2 ] is reported, in which L represents a 2,2'-bipyridine ligand functionalized at the 4,4' positions with benzo[1,2-b:4,5-b']dithiophene derivatives (BDT) and L' is 2,2'-bi... |