高氯酸镁
一般危化品
高氯酸镁结构式
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常用名 | 高氯酸镁 | 英文名 | Magnesium perchlorate |
|---|---|---|---|---|
| CAS号 | 10034-81-8 | 分子量 | 223.20600 | |
| 密度 | 2,21 g/cm3 | 沸点 | N/A | |
| 分子式 | Cl2MgO8 | 熔点 | 251 °C | |
| MSDS | 中文版 美版 | 闪点 | N/A | |
| 符号 |
GHS03, GHS07 |
信号词 | Danger |
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Notable effects of the metal salts on the formation and decay reactions of α-tocopheroxyl radical in acetonitrile solution. The complex formation between α-tocopheroxyl and metal cations.
J. Phys. Chem. B 115(32) , 9880-8, (2011) The measurement of the UV-vis absorption spectrum of α-tocopheroxyl (α-Toc(•)) radical was performed by reacting aroxyl (ArO(•)) radical with α-tocopherol (α-TocH) in acetonitrile solution including four kinds of alkali and alkaline earth metal salts (MX or M... |
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Electrocatalytic reduction of CO2 with palladium bis-N-heterocyclic carbene pincer complexes.
Inorg. Chem. 53(24) , 12962-72, (2014) A series of pyridine- and lutidine-linked bis-N-heterocyclic carbene (NHC) palladium pincer complexes were electrochemically characterized and screened for CO2 reduction capability with 2,2,2-trifluoroethanol, acetic acid, or 2,2,2-trifluoroacetic acid (TFA) ... |
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Transformation of D-(-)-ribose into a natural product-like scaffold via a Lewis acid catalyzed intramolecular hetero-Diels-Alder reaction.
Nucleosides Nucleotides Nucleic Acids 26(6-7) , 701-4, (2007) Starting from D-(-)-ribose, a tricyclic natural product-like scaffold suitable for combinatorial derivatization was synthesized via an intramolecular hetero-Diels-Alder reaction. Lithium perchlorate was found to enhance the reaction rate and, at the same time... |
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Ligand exchange dynamics in aqueous solution studied with 2DIR spectroscopy.
J. Phys. Chem. B 114(19) , 6693-702, (2010) We have used time-resolved multidimensional vibrational spectroscopy, generally termed 2DIR spectroscopy, to study the equilibrium dynamics of ligand exchange in an aqueous solution containing 3.4 M Mg(ClO(4))(2) and 1.2 M NaSCN. The sensitivity of the CN str... |
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Ultrafast two-dimensional infrared spectroscopy resolves the conformational change of an Evans auxiliary induced by Mg(ClO4)2.
J. Org. Chem. 77(24) , 11091-5, (2012) Structure determination of reactive species is a key step in understanding reaction mechanisms. We demonstrate the application of polarization-dependent two-dimensional infrared spectroscopy (P2D-IR) as a powerful tool combining structure resolution with ultr... |
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Biological implications of magnesium salts at the molecular level.
Magnes. Res. 9(4) , 259-62, (1996) The interaction of Mg2+ cations in biological systems is studied by using nucleic acid bases as the biological system. Magnesium salts, such as, MgCl2 6H2O, MgSO4. 7H2O and Mg(ClO4). XH2O have been employed in order to compare their complexation with cytosine... |
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Unusual and unexpected reactivity of t-butyl dicarbonate (Boc2O) with alcohols in the presence of magnesium perchlorate. A new and general route to t-butyl ethers.
Org. Lett. 7(3) , 427-30, (2005) [reaction: see text] A new mild method for protecting alcohols as t-butyl ethers is reported. The reaction proceeds with Mg(ClO4)2 and Boc2O and shows general applicability. The deprotection of t-butyl ethers has also been revisited. Preliminary results indic... |
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An extremely efficient three-component reaction of aldehydes/ketones, amines, and phosphites (Kabachnik-Fields reaction) for the synthesis of alpha-aminophosphonates catalyzed by magnesium perchlorate.
J. Org. Chem. 72(4) , 1263, (2007) Commercially available magnesium perchlorate is reported as an extremely efficient catalyst for the synthesis of alpha-aminophosphonates. A three-component reaction (3-CR) of an amine, an aldehyde or a ketone, and a di-/trialkyl phosphite (Kabachnik-Fields re... |
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Synthesis and photoinduced electron transfer of phthalocyanine-perylenebisimide pentameric arrays.
J. Org. Chem. 74(16) , 5871-80, (2009) Zinc phthalocyanine-perylenebisimide pentameric arrays, ZnPc(PDI)(4) 1 and 2, have been synthesized. ZnPc(PDI)(4) 1 has no substituents in the PDI bay positions, while ZnPc(PDI)(4) 2 presents four phenoxy groups in the bay positions of each perylene. In both ... |
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[The experimental effect of growth stimulants on protein assimilation].
Vopr. Pitan. (3) , 58-60, (1990) In experiments on rats it was established that the compound CAM-300 in a dose of 2 mg/kg did not induce body mass growth, protein biological value increase or pepsinogen concentration change in the gastric mucosa. Fenobolin stimulation of growth in the experi... |